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Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…

Astrophysics of Galaxies · Physics 2025-12-01 Valerio Lattanzi , Miguel Sanz-Novo , Víctor M. Rivilla , Izaskun Jiménez-Serra , Paola Caselli

This chapter presents a review on the latest advances in the computation of physical conditions and chemical abundances of elements present in photoionized gas H II regions and planetary nebulae). The arrival of highly sensitive…

Solar and Stellar Astrophysics · Physics 2020-07-22 Jorge García-Rojas

Studying the composition of dust in the interstellar medium (ISM) is crucial in understanding the cycle of dust in our galaxy. The mid-infrared spectral signature of amorphous silicates, the most abundant dust species in the ISM, is studied…

HCN molecules serve as an important tracer for chemical evolution of elemental nitrogen in the regions of star and planet formation. This is largely explained by the fact that N atoms and N$_2$ molecules are poorly accessible for the…

The neutral interstellar medium (ISM) inside the Local Bubble (LB) has been known to have properties typical of the warm neutral medium (WNM). However, several recent neutral hydrogen (HI) absorption experiments show evidence for the…

Astrophysics · Physics 2009-06-23 Snezana Stanimirovic

We have calculated the radiation field, dust grain temperatures, and far infrared emissivity of numerical models of turbulent molecular clouds. When compared to a uniform cloud of the same mean optical depth, most of the volume inside the…

Astrophysics · Physics 2009-11-10 Thomas Bethell , Ellen Zweibel , Fabian Heitsch , J. S. Mathis

The formation of stars is inextricably linked to the structure of their parental molecular clouds. Here we take a number of nearby giant molecular clouds (GMCs) and analyse their column density and mass distributions. This investigation is…

Astrophysics of Galaxies · Physics 2015-05-18 D. Froebrich , J. Rowles

To date, 204 individual molecular species, comprised of 16 different elements, have been detected in the interstellar and circumstellar medium by astronomical observations. These molecules range in size from two atoms to seventy, and have…

Astrophysics of Galaxies · Physics 2018-12-05 Brett A. McGuire

The interstellar medium (ISM) is ubiquitously turbulent across many physically distinct environments within the Galaxy. Turbulence is key in controlling the structure and dynamics of the ISM, regulating star formation, and transporting…

Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the basis of precise laboratory data, a rich collection of more than 200 familiar and exotic molecules have been identified in the interstellar medium, the…

Astrophysics of Galaxies · Physics 2021-03-18 Michael C. McCarthy , Brett A. McGuire

We report high-sensitivity millimetre observations of several molecular species (13CO, HCN, HNC, CN, HCO+ and N2H+) in a sample of compact planetary nebulae. Some species such as HCO+ and CN are particularly abundant compared to envelopes…

Astrophysics · Physics 2009-11-07 E. Josselin , R. Bachiller

In the central regions of active galaxies, dense molecular medium are exposed to various types of radiation and energy injections, such as UV, X-ray, cosmic ray, and shock dissipation. With the rapid progress of chemical models and…

Astrophysics of Galaxies · Physics 2017-01-11 Kotaro Kohno , Ryo Ando , Akio Taniguchi , Takuma Izumi , Tomoka Tosaki

Dust grains are an important component of the interstellar medium (ISM) of galaxies. We present the first direct measurement of the residence times of interstellar dust in the different ISM phases, and of the transition rates between these…

We use very deep spectra obtained with the Ultraviolet-Visual Echelle Spectrograph at the Very Large Telescope to derive physical conditions and chemical abundances of four H II regions of the Large Magellanic Cloud (LMC) and four H II…

Astrophysics of Galaxies · Physics 2022-11-22 G. Domínguez-Guzmán , M. Rodríguez , J. García-Rojas , C. Esteban , L. Toribio San Cipriano , .

The dynamics and chemistry of protostellar disks are likely to be intricately linked, with dynamical processes altering the chemical composition, and chemistry, in turn, controlling the ionization structure and hence the ability of the…

Astrophysics · Physics 2009-11-11 K. Willacy , W. D. Langer , M. Allen , G. Bryden

In this study, we explore the impact of inhomogeneities in the spatial distribution of interstellar dust on spatial scales of $\le1$ au caused by ion shadowing forces on the optical properties of diffuse interstellar medium (ISM) as well as…

Astrophysics of Galaxies · Physics 2020-05-27 Andrei B. Ostrovskii , S. Yu. Parfenov , A. I. Vasyunin , A. V. Ivlev , V. A. Sokolova

Potential vibrational modes associated with diffuse interstellar bands (DIBs) could be discerned by examining energy differences between correlated DIBs. Consequently, $\approx 10^3$ higher correlated DIB pairs ($r-\sigma_r \ge 0.8$, $\ge…

We present three-dimensional astrochemical simulations and synthetic observations of magnetised, turbulent, self-gravitating molecular clouds. We explore various galactic interstellar medium environments, including cosmic-ray ionization…

Astrophysics of Galaxies · Physics 2021-01-20 Thomas G. Bisbas , Jonathan C. Tan , Kei E. I. Tanaka

This paper assesses the implications of a recent discovery (Jenkins 2009) that atomic oxygen is being depleted from diffuse interstellar gas at a rate that cannot be accounted for by its presence in silicate and metallic oxide particles. To…

Astrophysics of Galaxies · Physics 2014-11-20 D. C. B. Whittet

Context. The abundances of many observed compounds in interstellar molecular clouds still lack an explanation, despite extensive research that includes both gas and solid (dust-grain surface) phase reactions. Aims. We aim to qualitatively…

Astrophysics of Galaxies · Physics 2012-07-12 Juris Kalvans , Ivar Shmeld
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