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Raman measurements in carbon allotropes are generally associated with the exploration of the vibrational modes. Here, we present a theory of the non-resonant inelastic light scattering accompanied by the excitations of intersubband…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 Oleksiy Kashuba , Vladimir I. Fal'ko

In Raman spectroscopy of graphite and graphene, the $D$ band at $\sim 1355$cm$^{-1}$ is used as the indication of the dirtiness of a sample. However, our analysis suggests that the physics behind the $D$ band is closely related to a very…

Mesoscale and Nanoscale Physics · Physics 2013-02-26 Ken-ichi Sasaki , Yasuhiro Tokura , Tetsuomi Sogawa

It has been long accepted that the second-order Raman bands in carbon nanotubes are enhanced through the double-resonance mechanism. Although separate aspects of this mechanism have been studied for a few second-order Raman bands, including…

Mesoscale and Nanoscale Physics · Physics 2018-08-15 Valentin N. Popov

A theoretical study describing the coherence properties of near-field Raman scattering in two- and one-dimensional systems is presented. The model is applied to the Raman modes of pristine graphene and graphene edges. Our analysis is based…

Mesoscale and Nanoscale Physics · Physics 2014-03-31 Luiz Gustavo Cançado , Ryan Beams , Ado Jorio , Lukas Novotny

By analytically constructing the matrix elements of an electron-phonon interaction for the $D$ band in the Raman spectra of armchair graphene nanoribbons, we show that pseudospin and momentum conservation result in (i) a $D$ band consisting…

Mesoscale and Nanoscale Physics · Physics 2012-03-14 K. Sasaki , K. Kato , Y. Tokura , S. Suzuki , T. Sogawa

A new group-theory method to relate a spectrum of carbon nanotubes with that of a graphene monolayer is elaborated. The spectrum reconstruction is performed using a virtual intermediate planar periodic structure. Selected irreducible…

Materials Science · Physics 2015-06-05 M. V. Avramenko , S. B. Rochal , Yu. I. Yuzyuk

Nanometer-scale graphene objects are attracting much research interest because of newly emerging properties originating from quantum confinement effects. We present Raman spectroscopy studies of graphene nanoribbons (GNRs) which are known…

Materials Science · Physics 2012-01-23 Sunmin Ryu , Janina Maultzsch , Melinda Y. Han , Philip Kim , Louis E. Brus

Non-dispersive, inter-layer interaction induced Raman peaks (I bands) -- in the region of the D band -- have been observed recently for bilayer graphene, when the two layers were rotated with respect to each other. Here, similar…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Bálint Gyimesi , János Koltai , Viktor Zólyomi , Jenő Kürti

We investigate vibration modes and their Raman activity of single-walled carbon nanotubes that are bent within their intrinsic elastic limits. By implementing novel boundary conditions for density-functional based tight-binding, and using…

Materials Science · Physics 2009-11-13 Sami Malola , Hannu Häkkinen , Pekka Koskinen

The tangential G-band in the Raman spectra of a metallic single-wall carbon nanotube shows two peaks: a higher frequency component having the Lorentzian shape and a lower-frequency component of lower intensity with a Breit-Wigner-Fano…

Other Condensed Matter · Physics 2009-11-11 S. M. Bose , S. Gayen , S. N. Behera

The scattering of lattice excitations (phonons) with the photoexcited charge carriers is of a major concern in optoelectronic devices. Here, the resonant Raman scattering will be utilized to study an exciton-phonon interaction in GaN…

We exploit the near field enhancement of nano-antennas to investigate the Raman spectra of otherwise not optically detectable carbon nanotubes (CNTs). We demonstrate that a top-down fabrication approach is particularly promising when…

Mesoscale and Nanoscale Physics · Physics 2015-07-01 Nicola Paradiso , Fatemeh Yaghobian , Christoph Lange , Tobias Korn , Christian Schüller , Rupert Huber , Christoph Strunk

We provide a topological understanding on phonon Hall effect in dielectrics with Raman spinphonon coupling. A general expression for phonon Hall conductivity is obtained in terms of the Berry curvature of band structures. We find a…

Materials Science · Physics 2011-01-28 Lifa Zhang , Jie Ren , Jian-Sheng Wang , Baowen Li

We develop a theoretical framework for probing moir\'e phonon modes using Raman spectroscopy, and illustrate it with the example of twisted bilayer graphene (TBG). These moir\'e phonons arise from interlayer sliding motion in twisted 2D…

Strongly Correlated Electrons · Physics 2025-06-24 Vitor Dantas , Héctor Ochoa , Rafael M. Fernandes , Natalia B. Perkins

Since their discovery, graphene-based systems represent an exceptional playground to explore the emergence of peculiar quantum effects. The present paper focuses on the anomalous appearence of strong infrared phonon resonances in the…

Mesoscale and Nanoscale Physics · Physics 2012-10-04 E. Cappelluti , L. Benfatto , M. Manzardo , A. B. Kuzmenko

The electron-phonon matrix elements relevant to the Raman intensity and Kohn anomaly of the G band are calculated by taking into account the effect of the edge of graphene. The analysis of the pseudospin reveals that the longitudinal…

Mesoscale and Nanoscale Physics · Physics 2010-04-13 K. Sasaki , R. Saito , K. Wakabayashi , T. Enoki

Phonon softening phenomena of the $\Gamma$ point optical modes including the longitudinal optical mode, transverse optical mode and radial breathing mode in "metallic" single wall carbon nanotubes are reviewed from a theoretical point of…

Mesoscale and Nanoscale Physics · Physics 2010-05-13 K. Sasaki , H. Farhat , R. Saito , M. S. Dresselhaus

Raman spectroscopy is an integral part of graphene research. It is used to determine the number and orientation of layers, the quality and types of edge, and the effects of perturbations, such as electric and magnetic fields, strain,…

Materials Science · Physics 2015-06-16 Andrea C. Ferrari , Denis M. Basko

Raman spectroscopy has been the most extensively employed method to study carbon nanotubes at high pressures. This review covers reversible pressure-induced changes of the lattice dynamics and structure of single- and multi-wall carbon…

Condensed Matter · Physics 2009-09-29 I. Loa

Raman spectroscopy plays a key role in studies of graphene and related carbon systems. Graphene is perhaps the most promising material of recent times for many novel applications, including electronics. In this paper, the traditional and…

Materials Science · Physics 2015-12-07 Eric J. Heller , Yuan Yang , Lucas Kocia , Wei Chen , Shiang Fang , Mario Borunda , Efthimios Kaxiras
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