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Effective potentials of the relativistic m\alpha^6 order correction for the ground state of the Coulomb two-center problem are calculated. They can be used to evaluate the relativistic contribution of that order to the energies of hydrogen…

Atomic Physics · Physics 2007-11-26 V. I. Korobov , Ts. Tsogbayar

We develop a numerical method to calculate the Bethe logarithm for resonant states. We use the Complex Coordinate Rotation (CCR) formalism to describe resonances as time-independent Schr\"odinger solutions. To get a proper expression for…

Atomic Physics · Physics 2014-02-11 Vladimir I. Korobov

We report a calculation of relativistic corrections of order $m\alpha^7$ to the Bethe logarithm for the $2^3S$ and $2^3P$ states of helium-like ions. The calculation is required for improving the accuracy of theoretical energies of…

Atomic Physics · Physics 2022-08-30 Vladimir A. Yerokhin , Vojtěch Patkóš , Krzysztof Pachucki

We consider a general procedure to evaluate the Bethe logarithm for a general few-body atomic or molecular system. As benchmarks we use calculation for the ground states of a helium atom and H_2^+ molecular ion. The obtained values are:…

Atomic Physics · Physics 2014-02-11 V. I. Korobov

We calculate the two-loop Bethe logarithm correction to atomic energy levels in hydrogen-like systems. The two-loop Bethe logarithm is a low-energy quantum electrodynamic (QED) effect involving multiple summations over virtual excited…

High Energy Physics - Phenomenology · Physics 2007-05-23 Krzysztof Pachucki , Ulrich D. Jentschura

With this work we start a project of calculating the QED contribution of order $\alpha^7m$ to the $2^3P$-$2^3S$ transition energy in helium, aiming for an accurate determination of the nuclear charge radius $r_E$ from measurements of the…

Atomic Physics · Physics 2021-02-16 Vladimir A. Yerokhin , Vojtěch Patkóš , Krzysztof Pachucki

The Bethe logarithm for a large set of states of the helium atom is calculated with a precision of 12-14 significant digits. The numerical data is obtained for the case of infinite mass of a nucleus. Then we study the mass dependence and…

Atomic Physics · Physics 2019-07-31 Vladimir I. Korobov

We calculate the one- and two-loop corrections of order alpha(Zalpha)^6 and alpha^2(Zalpha)^6 respectively, to the Lamb shift in hydrogen-like systems using the formalism of nonrelativistic quantum electrodynamics. We obtain general results…

Atomic Physics · Physics 2009-11-11 Ulrich D. Jentschura , Andrzej Czarnecki , Krzysztof Pachucki

A general computational scheme for the (non-relativistic) Bethe logarithm is developed opening the route to `routine' evaluation of the leading-order quantum electrodynamics correction (QED) relevant for spectroscopic applications for small…

Chemical Physics · Physics 2023-01-10 Dávid Ferenc , Edit Mátyus

The relativistic second-order corrections at orders $m\alpha^6$ and $m\alpha^6(m/M)$ in hydrogen molecular ions are calculated. Convergence of numerical results is studied, which allows estimating the relative numerical uncertainty to be…

Atomic Physics · Physics 2025-06-30 Vladimir I. Korobov , Jean-Philippe Karr , Zhen-Xiang Zhong

In this article we propose a simple approach for the precision calculation of Bethe logarithm. The leading contributions are obtained using specific operators, while the remaining terms are eliminated by adjusting the parameter $\lambda$.…

Accurate results for nonrelativistic energy, relativistic, QED, and finite nuclear mass corrections are obtained for $2^1S_{1/2}$, $3^1S_{1/2}$ and $2^1P_{1/2}$ states of the Li atom and Be$^+$ ion. Our computational approach uses the…

Atomic Physics · Physics 2009-11-13 Mariusz Puchalski , Krzysztof Pachucki

In this work we develop and implement a method for calculation of the Bethe logarithm for many-electron atoms. This quantity is required to evaluate the leading-order quantum electrodynamics correction to the energy and properties of atomic…

Atomic Physics · Physics 2023-11-21 Michał Lesiuk , Jakub Lang

We investigate relativistic and quantum electrodynamic effects for highly-excited bound states in hydrogenlike systems (Rydberg states). In particular, hydrogenic one-loop Bethe logarithms are calculated for all circular states (l = n-1) in…

Atomic Physics · Physics 2016-09-08 U. D. Jentschura , E. -O. Le Bigot , J. Evers , P. J. Mohr , C. H. Keitel

We present improved theoretical calculations of transition frequencies for the fundamental transitions $(L\!=\!0,v\!=\!1)\to(L'\!=\!0,v'\!=\!0)$ in the hydrogen molecular ions H$_2^+$ and HD$^+$ with a relative uncertainty $4\cdot10^{-11}$…

Atomic Physics · Physics 2017-02-20 V. I. Korobov , L. Hilico , J. -P. Karr

High-precision variational calculations of the operators for the relativistic corrections in the leading $m\alpha^4$ order are presented. The ro-vibrational states in the range of the total orbital angular momentum $L\!=\!0\!-\!4$ and…

Atomic Physics · Physics 2019-01-09 D. T. Aznabayev , A. K. Bekbaev , V. I. Korobov

We present a precise fully relativistic numerical solution of the two-center Coulomb problem. The special case of unit nuclear charges is relevant for the accurate description of the ${\rm H}_2^+$ molecular ion and its isotopologues,…

Quantum Physics · Physics 2022-05-11 O. Kullie , S. Schiller

The major goal of the high-precision studies of ro-vibrational states in the hydrogen molecular ions is to provide an alternative way for improving the electron-to-proton mass ratio, or the atomic mass of electron. By now the complete set…

Atomic Physics · Physics 2008-04-16 V. I. Korobov

We recalculate the leading relativistic corrections for the ground electronic state of the hydrogen molecule using variational method with explicitly correlated functions which satisfy the interelectronic cusp condition. The new…

Chemical Physics · Physics 2017-05-31 Mariusz Puchalski , Jacek Komasa , Krzysztof Pachucki

The simplest, algebraic quantum-electrodynamical corrections, due to the double-negative energy subspace and instantaneous interactions, are computed to the no-pair energy of two-spin-1/2-fermion systems. Numerical results are reported for…

Chemical Physics · Physics 2025-12-09 Péter Jeszenszki , Edit Mátyus
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