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Kohn-Sham (KS) density functional theory (DFT) is a very efficient method for calculating various properties of solids as, for instance, the total energy, the electron density, or the electronic band structure. The KS-DFT method leads to…

Materials Science · Physics 2019-09-20 Fabien Tran , Jan Doumont , Leila Kalantari , Ahmad W. Huran , Miguel A. L. Marques , Peter Blaha

We report Hartree-Fock (HF) based pseudopotentials suitable for plane-wave calculations. Unlike typical effective core potentials, the present pseudopotentials are finite at the origin and exhibit rapid convergence in a plane-wave basis;…

Materials Science · Physics 2008-02-28 W. A. Al-Saidi , E. J. Walter , A. M. Rappe

Accurately modeling the electronic structure of materials is a persistent challenge to high-throughput screening. A promising means of balancing accuracy against computational cost are non-self-consistent calculations with hybrid…

Materials Science · Physics 2020-05-04 Jonathan M. Skelton , David S. D. Gunn , Sebastian Metz , Stephen C. Parker

Density functional theory(DFT) and Hartree-Fock(HF) calculations are reported for the family of transition metal fluorides $\mbox{ScF}_3$, $\mbox{TiF}_4$, $\mbox{VF}_5$, and $\mbox{CrF}_6$. Both HF and the local-density-aproximation (LDA)…

chem-ph · Physics 2016-08-31 Thomas V. Russo , Richard L. Martin , P. Jeffrey Hay

The classification of topological materials is revisited using advanced computational workflows that integrate hybrid density functional theory calculations with exact Hartree-Fock exchange. Unlike previous studies, our workflow optimizes…

Materials Science · Physics 2025-07-16 Hossein Mirhosseini , Luis Elcoro , Andreas Knüpfer , Thomas D. Kühne

Theoretical simulation to phase change materials such as Ge-Sb-Te has suffered from two methodology issues. On the one hand, there is a lack of efficient band gap correction method for density functional theory, which is suitable for these…

Materials Science · Physics 2025-03-19 Shanzhong Xie , Kan-Hao Xue , Shaojie Yuan , Shengxin Yang , Heng Yu , Rongchuan Gu , Ming Xu , Xiangshui Miao

Extending density functional theory (DFT) to an {\it ab initio} orbital functional theory (OFT) requires new methodology for nonlocal exchange and correlation potentials. This paper describes such modifications to a standard Dirac-Slater…

Condensed Matter · Physics 2007-05-23 R. K. Nesbet

We propose an analytical method for the construction of Hartree-Fock phase diagrams for the (fermion) Hubbard model and various generalizations thereof. Such phase diagrams are traditionally constructed numerically, but we argue that, by…

Mathematical Physics · Physics 2025-12-24 Christophe Charlier , Edwin Langmann , Jonatan Lenells

In this article, we discuss how a kind of hybrid computation, which employs symbolic, numeric, classic, and quantum algorithms, allows us to conduct Hartree-Fock electronic structure computation of molecules. In the proposed algorithm, we…

Quantum Physics · Physics 2024-06-19 Ichio Kikuchi , Akihito Kikuchi

Range separated hybrid density functionals are very successful in describing a wide range of molecular and solid state properties accurately. Range separated hybrid functionals are designed from spherically averaged or system averaged…

Materials Science · Physics 2017-12-15 Subrata Jana , Prasanjit Samal

DFT is used throughout nanoscience, especially when modeling spin-dependent properties that are important in spintronics. But standard quantum chemical methods (both CCSD(T) and self-consistent semilocal density functional calculations)…

Chemical Physics · Physics 2017-08-29 Suhwan Song , Min-Cheol Kim , Eunji Sim , Anouar Benali , Olle Heinonen , Kieron Burke

The convergence to the self-consistency in the dynamical-mean-field-theory (DMFT) calculations for models of correlated electron systems can be significantly accelerated by using an appropriate mixing of hybridization functions which are…

Strongly Correlated Electrons · Physics 2009-11-11 Rok Zitko

In the near future, material and drug design may be aided by quantum computer assisted simulations. These have the potential to target chemical systems intractable by the most powerful classical computers. However, the resources offered by…

The time-dependent Hartree-Fock (TDHF) method is an approach to simulate the mean field dynamics of electrons within the assumption that the electrons move independently in their self-consistent average field and within the space of single…

Quantum Physics · Physics 2023-09-06 Sahil Gulania , Stephen K. Gray , Yuri Alexeev , Bo Peng , Niranjan Govind

The ab-initio many-body method suggested in the preceding paper is applied to the 3d transition metals Fe, Co, Ni, and Cu. We use a linearized muffin-tin orbital calculation to determine Bloch functions for the Hartree one-particle…

Condensed Matter · Physics 2007-05-23 I. Schnell , G. Czycholl , R. C. Albers

We propose a practical method to solve the random-phase approximation (RPA) in the self-consistent Hartree-Fock (HF) and density-functional theory. The method is based on numerical evaluation of the residual interactions utilizing finite…

Nuclear Theory · Physics 2010-11-26 Takashi Nakatsukasa , Tsunenori Inakura , Kazuhiro Yabana

We investigate how the fixed-node diffusion Monte Carlo energy of solids depends on single-particle orbitals used in Slater--Jastrow wave functions. We demonstrate that the dependence can be significant, in particular in the case of 3d…

Materials Science · Physics 2010-09-09 Jindrich Kolorenc , Shuming Hu , Lubos Mitas

In a previous contribution (Mol. Phys. {\bf 103}, xxxx, 2005), we established the suitability of density functional theory (DFT) for the calculation of molecular anharmonic force fields. In the present work, we have assessed a wide variety…

Chemical Physics · Physics 2007-05-23 A. Daniel Boese , Wim Klopper , Jan M. L. Martin

The starting point of this paper is the interplay between the construction principle of a sequence and the characters of the compact abelian group that underlies the construction. In case of the Halton sequence in base $\mathbf b=(b_1,…

Number Theory · Mathematics 2013-06-14 Peter Hellekalek

A possibility for fundamental constants to vary in time is suggested by theories unifying gravity with other interactions. In this article we examine proposals to use optical transitions of Sr, Dy, YbII and YbIII for the search of the time…

Atomic Physics · Physics 2009-02-05 V. A. Dzuba , V. V. Flambaum , M. V. Marchenko.
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