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Although RNAs play many cellular functions little is known about the dynamics and thermodynamics of these molecules. In principle, all-atom molecular dynamics simulations can investigate these issues, but with current computer facilities,…

Biomolecules · Quantitative Biology 2013-01-22 Tristan Cragnolini , Philippe Derreumaux , Samuela Pasquali

We use mesoscopic non-equilibrium thermodynamics theory to describe RNA unfolding under tension. The theory introduces reaction coordinates, characterizing a continuum of states for each bond in the molecule. The unfolding considered is so…

Statistical Mechanics · Physics 2007-09-18 J. M. Rubi , D. Bedeaux , S. Kjelstrup

RNA pseudoknots are a kind of minimal RNA tertiary structural motifs, and their three-dimensional (3D) structures and stability play essential roles in a variety of biological functions. Therefore, to predict 3D structures and stability of…

Biological Physics · Physics 2019-05-21 Ya-Zhou Shi , Lei Jin , Chen-Jie Feng , Ya-Lan Tan , Zhi-Jie Tan

The kinetic folding of RNA sequences into secondary structures is modeled as a complex adaptive system, the components of which are possible RNA structural rearrangements (SRs) and their associated bases and base pairs. RNA bases and base…

Biomolecules · Quantitative Biology 2007-05-23 Wilfred Ndifon

Recent single-molecule pulling experiments have shown how it is possible to manipulate RNA molecules using optical tweezers force microscopy. We investigate a minimal model for the experimental setup which includes a RNA molecule connected…

Statistical Mechanics · Physics 2009-11-10 Maria Manosas , Felix Ritort

The structure of the self-cleaving hairpin ribozyme is well characterized, and its folding has been examined in bulk and by single-molecule fluorescence, establishing the importance of cations, especially magnesium in the stability of the…

Biomolecules · Quantitative Biology 2007-05-23 Lucas G. Nivon , Eugene I. Shakhnovich

In this paper, we explore the feasibility of using coarse-grained models to simulate the self-assembly of DNA nanostructures. We introduce a simple model of DNA where each nucleotide is represented by two interaction sites corresponding to…

Soft Condensed Matter · Physics 2009-10-07 Thomas E. Ouldridge , Iain G. Johnston , Ard A. Louis , Jonathan P. K. Doye

We introduce an extended version of oxDNA, a coarse-grained model of DNA designed to capture the thermodynamic, structural and mechanical properties of single- and double-stranded DNA. By including explicit major and minor grooves, and by…

DNA is an astonishing material that can be used as a molecular building block to construct periodic arrays and devices with nanoscale accuracy and precision. Here, we present simple bead-spring model of DNA nanostars having three, four and…

Soft Condensed Matter · Physics 2021-10-22 Supriyo Naskar , Dhiraj Bhatia , Shiang-Tai Lin , Prabal K. Maiti

We explore in detail the structural, mechanical and thermodynamic properties of a coarse-grained model of DNA similar to that introduced in Thomas E. Ouldridge, Ard A. Louis, Jonathan P.K. Doye, Phys. Rev. Lett. 104 178101 (2010). Effective…

Biomolecules · Quantitative Biology 2013-06-25 Thomas E. Ouldridge , Ard A. Louis , Jonathan P. K. Doye

We study the behaviour of double-stranded RNA under twist and tension using oxRNA, a recently developed coarse-grained model of RNA. Introducing explicit salt-dependence into the model allows us to directly compare our results to data from…

Biomolecules · Quantitative Biology 2016-01-19 Christian Matek , Petr Šulc , Ferdinando Randisi , Jonathan P. K. Doye , Ard A. Louis

RNA function crucially depends on its structure. Thermodynamic models currently used for secondary structure prediction rely on computing the partition function of folding ensembles, and can thus estimate minimum free-energy structures and…

Biomolecules · Quantitative Biology 2022-07-26 Nicola Calonaci , Alisha Jones , Francesca Cuturello , Michael Sattler , Giovanni Bussi

Detecting conformational transitions in molecular systems is key to understanding biological processes. Here, we investigate the force variance in single-molecule pulling experiments as an indicator of molecular folding transitions. We…

Statistical Mechanics · Physics 2023-09-13 Marc Rico , Felix Ritort

Detailed thermodynamic analysis of complex systems with multiple stable configurational states allows for insight into the cooperativity of each individual transition. In this work we derive a heat capacity decomposition comprising…

Statistical Mechanics · Physics 2022-11-15 Christopher C. Walker , Theodore L. Fobe , Michael R. Shirts

We introduce a coarse-grained model of DNA with bases modeled as rigid-body ellipsoids to capture their anisotropic stereochemistry. Interaction potentials are all physicochemical and generated from all-atom simulation/parameterization with…

Soft Condensed Matter · Physics 2015-05-14 Alex Morriss-Andrews , Joerg Rottler , Steven S. Plotkin

In structure-based models of proteins, one often assumes that folding is accomplished when all contacts are established. This assumption may frequently lead to a conceptual problem that folding takes place in a temperature region of very…

Biomolecules · Quantitative Biology 2016-05-23 Karol Wołek , Marek Cieplak

Nowadays different experimental techniques, such as single molecule or relaxation experiments, can provide dynamic properties of biomolecular systems, but the amount of detail obtainable with these methods is often limited in terms of time…

Computational Physics · Physics 2017-04-19 Giovanni Pinamonti , Jianbo Zhao , David E. Condon , Fabian Paul , Frank Noé , Douglas H. Turner , Giovanni Bussi

The objective of the present study was to develop an understanding of short single-stranded DNA (ssDNA) to assist the development of new DNA-based biosensors. A ssDNA model containing twelve bases was constructed from the 130-145 codon…

Biological Physics · Physics 2012-07-30 Subhasish Chatterjee , Bonnie Gersten , Siddarth Thakur , Alexander Burin

Urea titration of RNA by urea is an effective approach to investigate the forces stabilizing this biologically important molecule. We used all atom molecular dynamics simulations using two urea force fields and two RNA constructs to…

Biomolecules · Quantitative Biology 2017-01-24 U. Deva Priyakumar , Changbong Hyeon , D. Thirumalai , Alexander D. MacKerell

The highly charged RNA molecules, with each phosphate carrying a single negative charge, cannot fold into well-defined architectures with tertiary interactions, in the absence of ions. For ribozymes, divalent cations are known to be more…

Biomolecules · Quantitative Biology 2019-07-24 Naoto Hori , Natalia A. Denesyuk , D. Thirumalai