Related papers: Counter-ions at single charged wall: Sum rules
We study thermal equilibrium of classical pointlike counterions confined between symmetrically charged walls at distance $d$. At very large couplings when the counterion system is in its crystal phase, a harmonic expansion of particle…
We consider a one-dimensional classical Wigner jellium, not necessarily charge neutral, for which the electrons are allowed to exist beyond the support of the background charge. The model can be seen as a one-dimensional Coulomb gas in…
We discuss a sum rule satisfied by the correlation function of two particles with small relative momenta. The sum rule, which results from the completeness condition of the quantum states of the two particles, is first derived and then we…
Electric double layers (EDL) with counterions only, say electrons with the elementary charge $-e$, in thermal equilibrium at the inverse temperature $\beta$ are considered. In particular, we study the effect of the surface charge modulation…
The one-component Coulomb gas on the sphere, consisting on $N$ unit charges interacting via a logarithmic potential, and in the presence of two external charges each of strength proportional to $N$, is considered. There are two spherical…
The model under consideration is an asymmetric two-dimensional Coulomb gas of positively (q_1=+1) and negatively (q_2=-1/2) charged pointlike particles, interacting via a logarithmic potential. This continuous system is stable against…
We prove that at all positive temperatures in the bulk of a classical two-dimensional one-component plasma (also called Coulomb or log-gas, or jellium) the variance of the number of particles in large disks grows (strictly) more slowly than…
This paper concerns the equilibrium bulk charge and current density correlation functions in quantum media, conductors and dielectrics, fully coupled to the radiation (the retarded regime). A sequence of static and time-dependent sum rules,…
An exact solution is given for a two-dimensional model of a Coulomb gas, more general than the previously solved ones. The system is made of a uniformly charged background, positive particles, and negative particles, on the surface of a…
The recently derived sum rules for the scattering phase shifts of the Overhauser geminals (being 2-body-wave functions which parametrize the pair density together with an appropriately chosen occupancy) are generalized to integral equations…
Screening of a strongly charged macroion by multivalent counterions is considered. It is shown that counterions form a strongly correlated liquid at the surface of the macroion. Cohesive energy of this liquid leads to additional attraction…
We study a one dimensional Coulomb system, where two charged colloids are neutralized by a collection of point counterions, with global neutrality. Temperature being given, two situations are addressed: the colloids are either kept at fixed…
Coulomb law is one of the fundamental laws in Physics. It describes the magnitude of the electrostatic force between two electric charges. Counterintuitively the repulsion force between two equal electric charges in a vacuum, stated by the…
A sufficiently damped iteration of the Kohn-Sham equations with the exact functional is proven to always converge to the true ground-state density, regardless of the initial density or the strength of electron correlation, for finite…
The eigenvalue absorption for a many-particle Hamiltonian depending on a parameter is analyzed in the framework of non--relativistic quantum mechanics. The long--range part of pair potentials is assumed to be pure Coulomb and no restriction…
We investigate the equilibrium of a fluid in contact with a solid boundary through a density-functional theory. Depending on the conditions, the fluid can be in one phase, gas or liquid, or two phases, while the wall induces an external…
We study the ground-state structures of identical classical point charges with Coulomb interactions, confined between two symmetric parallel charged walls. For the well understood homogeneous dielectric case with no electrostatic images,…
Strong coupling phenomena, such as the like charged macroions attraction, opposite charged macroions repulsion, charge renormalization or charge inversion, are known to be mediated by multivalent counterions. Most theories treat the…
We develop a general formalism to investigate the effect of quenched fixed charge disorder on effective electrostatic interactions between charged surfaces in a one-component (counterion-only) Coulomb fluid. Analytical results are…
How do charge and density fluctuations compete in ionic fluids near gas-liquid criticality when quantum mechanical effects play a role ? To gain some insight, long-range $\Phi^{{\mathcal{L}}}_{\pm \pm} / r^{d+\sigma}$ interactions (with…