Related papers: HD depletion in starless cores
We present column density measurements of the HD molecule in the interstellar gas toward 17 Galactic stars. The values for the seven most heavily reddened sightlines, with E(B-V) = 0.38-0.72, are derived from observations with the Far…
We use the deuteration of $c$-$\mathrm{C_{3}H_{2}}$ to probe the physical parameters of starless and protostellar cores, related to their evolutionary states, and compare it to the $\mathrm{N_{2}H^{+}}$-deuteration in order to study…
To investigate how the abundance of N2H+ varies as massive clumps evolve, here we present a multi-wavelength study toward six molecular clouds. All of these clouds contain several massive clumps in different evolutionary stages of star…
Dust and associated depletion of heavy elements from the gas phase can modify the thermal properties of HII regions from the dust-free case, with significant consequences for the emergent optical spectrum. We present the results of…
Physical conditions in dense and cold regions of interstellar clouds favour the formation of ice mantles on the surfaces of interstellar grains. It is predicted that most of the gaseous species heavier than H2 or He will adsorb onto the…
The predictions of Galactic chemical evolution models for D and $^3$He are described in connection with those on the other Galactic quantities for which observational constraints are available. Models in agreement with the largest set of…
We present a chemical abundance analysis on the basis of high signal-to- noise and high resolution spectra for 12 stars of our newly defined sample. The selection criterion for the stars of this sample was their position in the `RV Tauri'…
CH2D+, the singly deuterated counterpart of CH3+, offers an alternative way to mediate formation of deuterated species at temperatures of several tens of K, as compared to the release of deuterated species from grains. We report a…
We use a sample of 47 homogeneous and high sensitivity CO images taken from the Nobeyama and BIMA surveys to demonstrate that, contrary to common belief, a significant number (~40%) of HI-deficient nearby spiral galaxies are also depleted…
We use high resolution spectra obtained with FUSE and STIS to obtain interstellar column densities of H I, D I, O I, S II, Fe II and P II toward the QSO HE 0226-4110 ( l = 253.4 deg , b = -65.77 deg). We obtain D/H = 21(+8, -6) ppm.…
The HDO/H2O ratio in interstellar gas is often used to draw conclusions on the origin of water in star-forming regions and on Earth. In cold cores and in the outer regions of protoplanetary disks, gas-phase water comes from photodesorption…
Context: Dark cloud chemical models usually predict large amounts of O2, often above observational limits. Aims: We investigate the reason for this discrepancy from a theoretical point of view, inspired by the studies of Jenkins and Whittet…
We constructed two new models for deuterium and spin-state chemistry for the purpose of modeling the low-temperature environment prevailing in starless and pre-stellar cores. The fundamental difference between the two models is in the…
[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…
Recent observations of the HDO/H$_2$O ratio toward protostars in isolated and clustered environments show an apparent dichotomy, where isolated sources show higher D/H ratios than clustered counterparts. Establishing which physical and…
The massive star-forming region Mon R2 hosts the closest ultra-compact HII region that can be spatially resolved with current single-dish telescopes. We used the IRAM-30m telescope to carry out an unbiased spectral survey toward two…
Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of…
Context: In the centre of pre-stellar cores, the deuterium fractionation is enhanced due to the cold temperatures and high densities. Therefore, the chemistry of deuterated molecules can be used to probe the evolution and the kinematics in…
We quantify if the chemical abundance gradients given by a dynamical model of core collapse including time-dependent changes in density and temperature differ greatly from abundances derived from static models, where the density and…
The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…