Related papers: HD depletion in starless cores
We use spectra and maps of NH2D, ND2H, and ND3, obtained with the CSO, IRAM 30m and Arecibo telescopes, to study deuteration processes in dense cores. The data include the first detection of the hyperfine structure of ND2H. The emission of…
We present constraints on the deuterium to hydrogen ratio (D/H) in the metal-poor gas cloud at redshift $z=0.701$ towards QSO 1718+4807. We use new Keck spectra in addition to Hubble Space Telescope (HST) and International Ultraviolet…
We present the modeling results of deuterium fractionation of water ice, H2, and the primary deuterium isotopologues of H3+ adopting physical conditions associated with the star and planet formation process. We calculated the deuterium…
The mechanisms responsible for chemical depletion across diverse astrophysical environments are not yet fully understood. In this paper, we investigate chemical depletion in post-AGB/post-RGB binary stars hosting second-generation…
We present a theoretical study of the deuterated species detectability in various types of extragalactic star-forming regions based on our predictions of chemical abundances. This work is motivated by the past and current attempts at…
We report a detection in the interstellar medium of an infrared transition within the electronic ground state of the deuterated hydrogen molecule, HD. Through a deep integration with the Short-Wavelength-Spectrometer on ISO, the pure…
The desorption of molecular species from ice mantles back into the gas phase in molecular clouds results from a variety of very poorly understood processes. We have investigated three mechanisms; desorption resulting from H_2 formation on…
Aims. The purpose of this study is to examine the prediction that the deuterated H3+ ion, H2D+, can be found exclusively in the coldest regions of molecular cloud cores. This is also a feasibility study for the detection of the ground-state…
Context. Deuterium in H-bearing species is enhanced during the early stages of star formation, however, only a small number of high spatial resolution deuteration studies exist towards protostellar objects, leaving the small-scale…
Deuterated ions are abundant in cold (T=10 K), dense (n=10^5 cm^-3) regions, in which CO is frozen out onto dust grains. In such environments, the deuterium fractionation of such ions can exceed the elemental abundance ratio of D/H by a…
From mapping observations of H2CO, HDCO, and D2CO, we have determined how the degree of deuterium fractionation changes over the central 3'x3' region of rho Oph A. The multi-transition data of the various H2CO isotopologues, as well as from…
In the interstellar cold gas, the chemistry of formaldehyde (H$_2$CO) can be essential to explain the formation of complex organic molecules. On this matter, the massive and energetic protostellar object G331 is still unexplored and, hence,…
Finding tracers of the innermost regions of prestellar cores is important for understanding their chemical and dynamical evolution before the onset of gravitational collapse. While classical molecular tracers, such as CO and CS, have been…
We have studied the chemistry of nitrogen--bearing species during the initial stages of protostellar collapse, with a view to explaining the observed longevity of N2H+ and NH3 and the high levels of deuteration of these species. We followed…
Deuterium enrichment of interstellar methanol is reproduced experimentally for the first time via grain-surface H-D substitution in solid methanol at an atomic D/H ratio of 0.1. Although previous gas-grain models successfully reproduce the…
$H_2$ is the most abundant interstellar species. Its deuterated forms ($HD$ and $D_2$) are also significantly abundant. Huge abundances of these molecules could be explained by considering the chemistry occurring on the interstellar dust.…
We aim to investigate the chemistry and gas phase abundance of HNCO and the variation of the HNCO/CS abundance ratio as a diagnostic of the physics and chemistry in regions of massive star formation. A numerical-chemical model has been…
(Abridged) We present evidence that low-mass starless cores, the simplest units of star formation, are systematically differentiated in their chemical composition. Molecules including CO and CS almost vanish near the core centers, where the…
Hot cores and their precursors contain an integrated record of the physics of the collapse process in the chemistry of the ices deposited during that collapse. In this paper, we present results from a new model of the chemistry near high…
We determine the ortho/para ratios of NH2D and NHD2 in two dense, starless cores, where their formation is supposed to be dominated by gas-phase reactions, which, in turn, is predicted to result in deviations from the statistical spin…