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A first principles analysis of an open system thermodynamical Carnot cycle is provided, and the results are compared to those proposed by Gibbs for open systems. The Kelvin-Clausius statement concerning heat transfer for reversible cycles…

General Mathematics · Mathematics 2007-05-23 Christopher G. Jesudason

Recent studies have pointed out the intrinsic dependence of figures of merit of thermodynamic relevance -- such as work, heat and entropy production -- on the amount of quantum coherences that is made available to a system. However, whether…

Quantum Physics · Physics 2023-02-03 G. Zicari , B. Çakmak , Özgür E. Müstecaplıoğlu , M. Paternostro

We discuss the thermodynamics of closed quantum systems driven out of equilibrium by a change in a control parameter and undergoing a unitary process. We compare the work actually done on the system with the one that would be performed…

Quantum Physics · Physics 2015-01-20 F. Plastina , A. Alecce , T. J. G. Apollaro , G. Falcone , G. Francica , F. Galve , N. Lo Gullo , R. Zambrini

Passivity is a fundamental concept in thermodynamics that demands a quantum system's energy cannot be lowered by any reversible, unitary process acting on the system. In the limit of many such systems, passivity leads in turn to the concept…

Quantum Physics · Physics 2017-12-14 Carlo Sparaciari , David Jennings , Jonathan Oppenheim

The Principle of Unattainability rules out the attainment of absolute zero temperature by any finite physical means, no matter how idealised they could be. Nevertheless, we clarify that the Third Law of Thermodynamics, as defined by…

Quantum Physics · Physics 2019-08-26 Tien D. Kieu

The thermodynamics of small quantum many-body systems strongly coupled to a heat bath at low temperatures with non-Markovian behavior are new challenges for quantum thermodynamics, as traditional thermodynamics is built on large systems…

Quantum Physics · Physics 2019-04-23 Jen-Tsung Hsiang , B. L. Hu

We investigate the thermodynamic properties of a single inertial probe driven into a nonequilibrium steady-state by random collisions with self-propelled active walkers. The probe and walkers are confined within a gravitational harmonic…

Statistical Mechanics · Physics 2026-01-13 Dima Boriskovsky , Rémi Goerlich , Benjamin Lindner , Yael Roichman

It is shown that the proof of [1] that the specific heat of the system of classical point particles interacting with each other via uniform gravitational potential energy may be negative is incorrect.

General Physics · Physics 2017-05-03 Ikhtier H. Umirzakov

We consider blocks of quantum spins in a chain at thermal equilibrium, focusing on their properties from a thermodynamical perspective. Whereas in classical systems the temperature behaves as an intensive magnitude, a deviation from this…

Quantum Physics · Physics 2015-05-13 A. Garcia-Saez , A. Ferraro , A. Acin

Thermal operations are an operational model of non-equilibrium quantum thermodynamics. In the absence of coherence between energy levels, exact state transition conditions under thermal operations are known in terms of a mathematical…

Quantum Physics · Physics 2015-08-11 Varun Narasimhachar , Gilad Gour

The thermodynamics of quantum systems coupled to periodically modulated heat baths and work reservoirs is developed. By identifying affinities and fluxes, the first and second law are formulated consistently. In the linear response regime,…

Statistical Mechanics · Physics 2016-06-29 Kay Brandner , Udo Seifert

A large class of isolated quantum system in a pure state can equilibrate and serve as a heat bath. We show that once the equilibrium is reached, any of its subsystems that is much smaller than the isolated system is thermalized such that…

Statistical Mechanics · Physics 2014-06-13 Quntao Zhuang , Biao Wu

The theory of superstatistics is a generalization of Boltzmann-Gibbs statistical mechanics which admits temperature fluctuations, and generates non-canonical ensembles from the distribution function of these fluctuations. Recently, some…

Statistical Mechanics · Physics 2025-04-29 Constanza Farías , Sergio Davis

We review our approach to the second law of thermodynamics, viewed as a theorem asserting the growth of the mean (Gibbs-von Neumann) entropy of quantum spin systems undergoing automorphic (unitary) adiabatic transformations. Non-automorphic…

Mathematical Physics · Physics 2022-08-16 Walter F. Wreszinski

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

Using the scaling relation of the ground state quantum fidelity, we propose the most generic scaling relations of the irreversible work (the residual energy) of a closed quantum system at absolute zero temperature when one of the parameters…

Statistical Mechanics · Physics 2015-09-02 Shraddha Sharma , Amit Dutta

We review the general aspects of the concept of temperature in equilibrium and non-equilibrium statistical mechanics. Although temperature is an old and well-established notion, it still presents controversial facets. After a short…

Statistical Mechanics · Physics 2017-11-13 A. Puglisi , A. Sarracino , A. Vulpiani

Thermodynamics of quantum coherence has attracted growing attention recently, where the thermodynamic advantage of quantum superposition is characterized in terms of quantum thermodynamics. We investigate thermodynamic effects of quantum…

Statistical Mechanics · Physics 2017-10-25 Yûto Murashita , Zongping Gong , Yuto Ashida , Masahito Ueda

The connection between gravity and thermodynamics is explored. Examining a perfect fluid in gravitational equilibrium we find that the entropy is extremal only if Einstein's equations are satisfied. Conversely, one can derive part of…

General Relativity and Quantum Cosmology · Physics 2007-05-23 J. Oppenheim

The existence of fluctuations of temperature has been a somewhat controversial topic in thermodynamics but nowadays it is recognized that they must be taken into account in small, finite systems. Although for nonequilibrium steady states…

Statistical Mechanics · Physics 2022-01-05 Sergio Davis