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In this work, electronic structure of several doped TiO$_2$ anatase systems is computed using DFT+$U$. Effective masses of charge carriers are also computed to quantify how the dopant atoms perturb the bands of the host anatase material.…

Materials Science · Physics 2022-08-19 Abhishek Raghav , Kenta Hongo , Ryo Maezono , Emila Panda

Oxide based diluted magnetic semiconductor (DMS) materials have been a subject of increasing interest due to reports of room temperature ferromagnetism in several systems and their potential use in the development of spintronic devices.…

Materials Science · Physics 2012-12-06 A. J. Silvestre , L. C. J. Pereira , M. R. Nunes , O. C. Monteiro

We present theoretical study of relative stability as well as of the magnetic and electronic properties of AgF2 and CuF2, in two related structural forms: orthorhombic (ambient pressure form of AgF2) and monoclinic (ambient pressure form of…

Materials Science · Physics 2024-03-28 Daniel Jezierski , Wojciech Grochala

Combining LSDA+$U$ and an analysis of superexchange interactions beyond DFT, we describe the magnetic ground states in rutile and anatase Cr-doped TiO$_2$. In parallel, we correct our LSDA+$U$ ground state through GW corrections…

Strongly Correlated Electrons · Physics 2015-06-15 F. Da Pieve , S. Di Matteo , T. Rangel , M. Giantomassi , D. Lamoen , G. -M. Rignanese , X. Gonze

Emergency of superconductivity at the instabilities of antiferromagnetism (AFM), spin/charge density waves has been widely recognized in unconventional superconductors. In copper-oxide superconductors, spin fluctuations play a predominant…

Superconductivity · Physics 2015-10-27 Heshan Yu , Ge He , Ziquan Lin , Jie Yuan , Beiyi Zhu , Yi-feng Yang , Tao Xiang , Feo. V. Kusmartsev , Liang Li , Junfeng Wang , Kui Jin

Study and comparison of over 30 examples of electron doped BaFe2As2 for transition metal (TM) = Co, Ni, Cu, and (Co/Cu mixtures) have lead to an understanding that the suppression of the structural/antiferromagnetic phase transition to low…

Superconductivity · Physics 2009-08-04 P. C. Canfield , S. L. Bud'ko , N. Ni , J. Q. Yan , A. Kracher

The ferroelectric trends of rutile (TiO$_2$) in bulk and at the (110) surface are investigated by means of ab initio density functional theory. We discuss the underlying mechanism of the incipient ferroelectric behavior of rutile in terms…

Materials Science · Physics 2015-06-12 Anna Grünebohm , Peter Entel , Claude Ederer

We report a classical interatomic force field for TiO$_2$, which has been parameterized using density functional theory forces, energies, and stresses in the rutile crystal structure. The reliability of this new classical potential is…

The potential applications of dilute magnetic oxides (DMOs) in magneto-optic and spintronic devices have attracted significant attention, although understanding their magnetic behavior is complex due to intricate interactions of intrinsic…

Materials Science · Physics 2025-02-13 Hemant Arora , Atul Bandyopadhyay , Arup Samanta

We report here the observation of ferromagnetism (FM) at 300 K in mixtures of TiO2 and Co3O4 powders despite the antiferromagnetic and diamagnetic character of both oxides respectively. The ferromagnetic behavior is found in the early…

We have investigated the magnetization properties and flux dynamics of superconducting Cu$_x$TiSe$_2$ single crystals within wide range of copper concentrations. We find that the superconducting anisotropy is low and independent on copper…

Superconductivity · Physics 2013-10-08 P. Husanikova , J. Fedor , J. Derer , J. Soltys , V. Cambel , M. Iavarone , S. J. May , G. Karapetrov

Titanium dioxide is one of the most widely investigated oxides. This is due to its broad range of applications, from catalysis to photocatalysis to photovoltaics. Despite this large interest, many of its bulk properties have been sparsely…

Materials Science · Physics 2010-03-12 L. Chiodo , J. M. García-Lastra , D. J. Mowbray , A. Iacomino , A. Rubio

We investigate magnetic properties of CrTe$_2$ within the density functional theory (DFT) approach in ferromagnetic phase and combination of DFT and dynamical mean field theory (DFT+DMFT) approach in paramagnetic phase. We show that few…

Strongly Correlated Electrons · Physics 2026-03-03 A. A. Katanin , E. M. Agapov

Density functional calculations are performed to investigate the room temperature ferromagnetism in GaN:Cu nanowires (NWs). Our results indicate that two Cu dopants are most stable when they are near each other. Compared to bulk GaN:Cu, we…

Materials Science · Physics 2008-07-08 H. J. Xiang , Su-Huai Wei

Density functional theory calculations indicate that the incorporation of V into Ti lattice positions of rutile TiO2 leads to magnetic V4+ species, but the extension and sign of the coupling between dopant moments confirm that ferromagnetic…

Materials Science · Physics 2015-05-28 Ricardo Grau-Crespo , Udo Schwingenschlögl

We calculate the nature of magnetic interactions in transition-metal doped ZnO using the local spin density approximation and LSDA+\textit{U} method of density functional theory. We investigate the following four cases: (i) single…

Materials Science · Physics 2009-11-11 Priya Gopal , Nicola A. Spaldin

Titanium dioxide, TiO$_2$, has multiple applications in catalysis, energy conversion and memristive devices because of its electronic structure. Most of these applications utilize the naturally existing phases: rutile, anatase and brookite.…

Materials Science · Physics 2016-11-28 Ye Luo , Anouar Benali , Luke Shulenburger , Jaron T. Krogel , Olle Heinonen , Paul R. C. Kent

Density functional theory (DFT) and DFT corrected for on-site Coulomb interactions (DFT+U) calculations are presented on Aluminium doping in bulk TiO$_2$ and the anatase (101) surface. Particular attention is paid to the mobility of oxygen…

Materials Science · Physics 2014-03-24 Conn O'Rourke , David R. Bowler

The electronic properties of pentavalent-ion (Nb$^{5+}$, Ta$^{5+}$, and I$^{5+}$) doped anatase and rutile TiO$_2$ are studied using spin-polarized GGA+\emph{U} calculations. Our calculated results indicate that these two phases of TiO$_2$…

Materials Science · Physics 2015-05-13 Kesong Yang , Ying Dai , Baibiao Huang , Yuan Ping Feng

We revisit the most widely investigated and controversial oxide diluted magnetic semiconductor (DMS), Co:TiO2, with a new high temperature film growth, and show that the corresponding material is not only an intrinsic DMS ferromagnet, but…