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The structural, elastic and electronic properties of two-dimensional (2D) titanium carbide/nitride based pristine (Tin+1Cn/Tin+1Nn) and functionalized MXenes (Tin+1CnT2/Tin+1NnT2, T stands for the terminal groups: -F, -O and -OH, n = 1, 2,…

Materials Science · Physics 2018-07-06 Ning Zhang , Yu Hong , Sanaz Yazdanparast , Mohsen Asle Zaeem

MXenes, a new class of two dimensional materials with several novel properties, are usually prepared from their MAX phases by etching out the A element using strong chemical reagents. This results in passivation of the surfaces of MXene…

Materials Science · Physics 2019-07-24 Krishnakanta Mondal , Prasenjit Ghosh

MXenes are an emerging class of 2D materials of interest in applications ranging from energy storage to electromagnetic shielding. MXenes are synthesized by selective etching of layered bulk MAX phases into sheets of 2D MXenes. Their…

Materials Science · Physics 2023-07-27 Kat Nykiel , Alejandro Strachan

As emerging atomically ultrathin metal compounds, MXenes show great promise for catalysts and nanoelectronics applications due to the abundant surface terminations and high metallic conductivity. However, the tendency of the interlayer…

Materials Science · Physics 2022-10-18 Qiye Guan , Hejin Yan , Yongqing Cai

The two-dimensional transition metal carbide/nitride family (MXenes) has garnered significant attention due to their highly customizable surface functional groups. Leveraging modern material science techniques, the customizability of MXenes…

Mesoscale and Nanoscale Physics · Physics 2023-10-31 Jiamin Liu , Guo Li , Xinxu Zhang , Jiahao Wei , Hui Jia , Yulong Wu , Changlong Liu , Yonghui Li

MXenes are a family two-dimensional transition metal carbide and nitride materials, which often exhibit very good metallic conductivity and are thus of great interest for applications in, e.g., flexible electronics, electrocatalysis, and…

Materials Science · Physics 2021-07-14 Mohammad Bagheri , Rina Ibragimova , Hannu-Pekka Komsa

Transition metal carbides/nitrides (MXenes) are a newly developing class of two-dimensional (2D) materials with technically robust properties that can be finely tuned by planar surface functionalization. Herein, the critical role of oxygen…

Materials Science · Physics 2020-08-17 Hongzhi Yu , Ke Xu , Zhisen Zhang , Jian Weng , Jianyang Wu

3D titanium carbonitrides TiCxNy possess excellent physical, chemical, and mechanical properties, attractive for various industrial applications. Most recently, the uncommon nano-sized layers of 2D-like titanium carbonitrides were…

Materials Science · Physics 2015-06-15 A. N. Enyashin , A. L. Ivanovskii

Recent chemical exfoliation of layered MAX phase compounds to novel two-dimensional transition metal carbides and nitrides, so called MXenes, has brought new opportunity to materials science and technology. This review highlights the…

Materials Science · Physics 2017-05-09 Mohammad Khazaei , Ahmad Ranjbar , Masao Arai , Taizo Sasaki , Seiji Yunoki

MXenes, a family of layered transition metal carbides and nitrides, have shown great promise for use in emerging electrochemical energy storage devices, including batteries and supercapacitors. MXene surfaces are terminated by mixed -O, -F…

Materials Science · Physics 2018-07-05 Nuala M. Caffrey

Density functional theory simulations with conventional (PBE) and hybrid (HSE06) functionals were performed to investigate the structural and electronic properties of MXene monolayers, \ce{Ti_{n+1}C_n} and \ce{Ti_{n+1}N_n} ($n$ = 1--9) with…

Materials Science · Physics 2013-07-04 Yu Xie , P. R. C. Kent

The chemical bonding in the carbide core and the surface chemistry in a new group of transition-metal carbides Tin+1Cn-Tx (n=1,2) called MXenes have been investigated by surface-sensitive valence band X-ray photoelectron spectroscopy.…

Materials Science · Physics 2018-03-21 Martin Magnuson , Joseph Halim , Lars-Åke Näslund

The class of two-dimensional carbides and nitrides known as MXenes exhibit remarkable electronic properties. Tailoring these properties, however, requires an in-depth understanding of the band structure and Fermi-surface topology. Surface…

Materials Science · Physics 2025-03-12 Martin Magnuson , Per Eklund , Craig Polley

Two-dimensional transition metal carbides and nitrides (MXenes) are a perspective group of materials with a broad palette of applications. Surface terminations are a product of the MXene preparation, and post-processing can also lead to…

Materials Science · Physics 2024-07-18 Barbora Vénosová , František Karlický

MXenes are 2D transition metal carbides with high potential for overcoming limitations of conventional two-dimensional electronics. In this context, various MXenes have shown magnetic properties suitable for applications in spintronics, yet…

Materials Science · Physics 2020-01-08 Shuo Li , Junjie He , Petr Nachtigall , Lukáš Grajciar , Federico Brivio

Titanium carbide and nitride MXenes are two-dimensional inorganic materials that exhibit noteworthy physical and chemical properties. These materials are considered for a variety of technological applications, ranging from energy harvesting…

Materials Science · Physics 2025-07-31 Luis F. V. Thomazini , Alexandre F. Fonseca

Ti$_3$C$_2$T$_X$ nano-sheets (MXenes) are an emerging class of two-dimensional materials with outstanding potential to be employed in energy storage, catalysis, and triboelectric applications, on length scales ranging from the nano- to…

Applied Physics · Physics 2021-10-06 A. Rodriguez , M. S. Jaman , O. Acikgoz , B. Wang , J. Yu , P. G. Grutzmacher , A. Rosenkranz , M. Z. Baykara

Hybrid materials of MXenes (2D carbides and nitrides) and transition-metal oxides (TMOs) have shown great promise in electrical energy storage and 2D heterostructures have been proposed as the next-generation electrode materials to expand…

Materials Science · Physics 2021-07-21 Lihua Xu , Tao Wu , Paul R. C. Kent , De-en Jiang

MXenes are a family of 2D transition metal carbides and nitrides with remarkable properties and great potential for energy storage and catalysis applications. However, their oxidation behavior is not yet fully understood, and there are…

Transition-metal dichalcogenides (TMDs) are promising for two-dimensional (2D) semiconducting devices and novel phenomena. For 2D applications, their work function, ionization energy, and electron affinity are required as a function of…

Materials Science · Physics 2021-03-16 Han-gyu Kim , Hyoung Joon Choi
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