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We consider deflection of polarizable molecules by inhomogeneous optical fields, and analyze the role of molecular orientation and rotation in the scattering process. It is shown that molecular rotation induces spectacular rainbow-like…

Quantum Physics · Physics 2015-05-19 E. Gershnabel , I. Sh. Averbukh

We provide a theory of the deflection of polar and non-polar rotating molecules by inhomogeneous static electric field. Rainbow-like features in the angular distribution of the scattered molecules are analyzed in detail. Furthermore, we…

Chemical Physics · Physics 2015-05-20 E. Gershnabel , I. Sh. Averbukh

The lack of a direct map between control fields and desired control objectives poses a significant challenge in applying quantum control theory to quantum technologies. Here, we propose an analytical framework to precisely control a limited…

Quantum Physics · Physics 2025-03-05 Qian-Qian Hong , Daoyi Dong , Niels E. Henriksen , Franco Nori , Jun He , Chuan-Cun Shu

Ultracold polar molecules trapped on an optical lattice is a many-body system that, under appropriate conditions, may support collective excitations reminiscent of excitons in solid state crystals. Here, we discuss the rotational…

Atomic Physics · Physics 2017-08-23 Marina Litinskaya , Roman V. Krems

We consider deflection of rotating symmetric molecules by inhomogeneous optical and static electric fields, compare results with the case of linear molecules, and find new singularities in the distribution of the scattering angle.…

Chemical Physics · Physics 2015-05-28 Erez Gershnabel , Ilya Sh. Averbukh

Molecules have vibrational, rotational, spin-orbit and hyperfine degrees of freedom or quantum states, each of which responds in a unique fashion to external electromagnetic radiation. The control over superpositions of these quantum states…

Quantum Physics · Physics 2024-04-29 Svetlana Kotochigova , Qingze Guan , Eite Tiesinga , Vito Scarola , Brian DeMarco , Bryce Gadway

We present an analysis of two experimental approaches to controlling the directionality of molecular rotation with ultrashort laser pulses. The two methods are based on the molecular interaction with either a pair of pulses (a "double kick"…

Optics · Physics 2015-06-11 C. Bloomquist , S. Zhdanovich , A. A. Milner , V. Milner

The rotational response of quantum condensed fluids is strikingly distinct from rotating classical fluids, especially notable for the excitation and ordering of quantized vortex ensembles. Although widely studied in conservative systems,…

Since the external regions of the envelopes of rapidly rotating early-type stars are unstable to convection, a coupling may exist between the convection and the internal rotation. We explore what can be learned from spectroscopic and…

Solar and Stellar Astrophysics · Physics 2015-05-20 J. Zorec , Y. Fremat , A. Domiciano de Souza , O. Delaa , P. Stee , D. Mourard , L. Cidale , C. Martayan , C. Georgy , S. Ekstrom

We propose an approach to probe coherent spin-state dynamics of molecules using circularly polarized hard x-ray pulses. For the dynamically aligned nitric oxide molecules in a coherent superposition spin-orbit coupled electronic state that…

Optics · Physics 2024-01-02 Xiaoyu Mi , Ming Zhang , Zheng Li

Semiclassical catastrophes in the dynamics of a quantum rotor (molecule) driven by a strong time-varying field are considered. We show that for strong enough fields, a sharp peak in the rotor angular distribution can be achieved via…

Quantum Physics · Physics 2007-05-23 I. Sh. Averbukh , R. Arvieu , M. Leibscher

We propose and computationally study a method for simultaneously orienting the angular momentum of asymmetric top molecules along: 1) a laboratory-fixed direction; 2) the molecular intermediate moment of inertia axis; 3) the laser field…

Quantum Physics · Physics 2022-11-21 Emil J. Zak

Optical control over elementary molecular vibration establishes fundamental capabilities for exploiting the broad range of optical linear and nonlinear phenomena. However, experimental demonstration of the coherently driven molecular…

Optics · Physics 2015-09-01 Biqin Dong , Xiangfan Chen , Fan Zhou , Chen Wang , Hao F. Zhang , Cheng Sun

We consider deflection of polarizable molecules by inhomogeneous optical fields, and analyze the role of molecular orientation and rotation in the scattering process. It is shown that molecular rotation induces spectacular rainbow-like…

Atomic Physics · Physics 2015-05-14 E. Gershnabel , I. Sh. Averbukh

A new mechanism is described, analyzed and visualized, for the dissipation of suprathermal rotation energy of molecules in magnetic fields, a necessary condition for their alignment. It relies upon the Lorentz force perturbing the motion of…

Astrophysics of Galaxies · Physics 2016-02-17 Renaud Papoular

Vibrational dynamics in conventional molecules usually takes place on a timescale of picoseconds or shorter. A striking exception are ultralong-range Rydberg molecules, for which dynamics is dramatically slowed down as a consequence of the…

Single molecule rotational correlation functions are analyzed for several reorientation geometries. Even for the simplest model of isotropic rotational diffusion our findings predict non-exponential correlation functions to be observed by…

Other Condensed Matter · Physics 2016-08-16 G. Hinze , G. Diezemann , Th. Basché

The extraordinary success in laser cooling, trapping, and coherent manipulation of atoms has energized the efforts in extending this exquisite control to molecules. Not only are molecules ubiquitous in nature, but the control of their…

Atomic Physics · Physics 2022-04-27 D. Mitra , K. H. Leung , T. Zelevinsky

Distintictive features of supersolids show up in their rotational properties. We calculate the moment of inertia of a harmonically trapped dipolar Bose-Einstein condensed gas as a function of the tunable scattering length parameter,…

Quantum Gases · Physics 2020-02-05 S. M. Roccuzzo , A. Gallemí , A. Recati , S. Stringari

We consider the coherent control of ultracold molecule-molecule scattering, impacted by a dense set of rovibrational resonances. To characterize the resonance spectrum, a rudimentary model based on multichannel quantum defect theory has…

Atomic Physics · Physics 2023-01-18 Adrien Devolder , Timur V. Tscherbul , Paul Brumer