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The primary attribute of interest of surface nanobubbles is their unusual stability and a number of theories trying to explain this have been put forward. Interestingly, the dissolution of nanobubbles is a topic that did not receive a lot…

A model for gas nanobubbles is proposed in which their remarkable stability is explained as due to the presence of a qualitatively different form of water covering the nanobubble surface layer which leads to a reduction of the diffusion…

Mesoscale and Nanoscale Physics · Physics 2014-10-15 Siddhartha Sen , Kumar S. Gupta

Electrolysis of water is employed to produce surface nanobubbles on highly orientated pyrolytic graphite (HOPG) surfaces. Hydrogen (oxygen) nanobubbles are formed when the HOPG surface acts as negative (positive) electrode. Coverage and…

We apply specular and off-specular neutron reflection at the hydrophobic silicon/water interface to check for evidence of nanoscopic air bubbles whose presence is claimed after an ad hoc procedure of solvent exchange. Nanobubbles and/or a…

Soft Condensed Matter · Physics 2017-10-13 Philipp Gutfreund , Marco Maccarini , Andrew Dennison , Max Wolff

It has been recently shown that nanobubbles exhibit a remarkable and unexpected stability. The lifetime of nanobubbles, formed either within liquids or on hydrophobic surfaces, can exceed by more than 10 orders of magnitude the theoretical…

Soft Condensed Matter · Physics 2019-05-14 Caroline Desgranges , Jerome Delhommelle

Water electrolysis in a microsystem is observed and analyzed on a short-time scale ~10 us. Very unusual properties of the process are stressed. An extremely high current density is observed because the process is not limited by the…

Soft Condensed Matter · Physics 2013-07-18 Vitaly B. Svetovoy , Remco G. P. Sanders , Miko C. Elwenspoek

Nanobubbles are observed with optical microscopy using the total internal reflection fluorescence (TIRF) excitation. We report on TIRF visualization using Rhodamine 6G at 5$\mu\,$M concentration which results to strongly contrasted…

Fluid Dynamics · Physics 2012-04-13 Chon U Chan , Claus-Dieter Ohl

Hydrogen can be stored in containers or in materials. In materials it can exist in molecular or atomic forms. The atomic form can further exist as multiple phases. Molecular hydrogen can be adsorbed on the surface or can be present inside…

A surprising phenomenon is presented: a bubble, produced from water electrolysis, is immobilized in the liquid (as if the Archimedes' buoyant force were annihilated). This is achieved using a nanoelectrode (1 nm to 1 $\mu$m of curvature…

Soft Condensed Matter · Physics 2017-02-07 Z Hammadi , L Lapena , R Morin , J Olives

We present a probabilistic approach to water-water hydrogen bonding that allows one to obtain an analytic expression for the number of bonds per water molecule as a function of both its distance to a hydrophobic particle and hydrophobe…

Soft Condensed Matter · Physics 2013-03-20 Yuri S. Djikaev , Eli Ruckenstein

Prior studies on the effects of surface chemistry of detonation nanodiamonds (DNDs) on Hydrogen Bonds (HBs) of water have not unambiguously distinguished among three broad categories of HBs: water-site HBs (HB$^{(s)}$), water-water HBs in…

Computational Physics · Physics 2021-03-03 Farshad Saberi-Movahed , Donald W Brenner

Protein nanoparticles have been proven to be highly effective stabilizers of water-in-water emulsions obtained from a number of different types of aqueous two-phase systems (ATPS). The stabilizing efficiency of such particles is attributed…

Soft Condensed Matter · Physics 2025-02-14 Andrzej Balis , Georgi Gochev , Domenico Truzzolillo , Dawid Lupa , Liliana Szyk-Warszynska , Jan Zawala

Nonadiabatic corrections in molecules composed of a few atoms are considered. It is demonstrated that a systematic perturbative expansion around the adiabatic solution is possible, with the expansion parameter being the electron-nucleus…

Chemical Physics · Physics 2009-11-13 Krzysztof Pachucki , Jacek Komasa

Since air-water and water-air interfaces are equally refractive, cloud droplets and microbubbles dispersed in bodies of water reflect sunlight in much the same way. The lifetime of sunlight-reflecting microbubbles, and hence the scale on…

Atmospheric and Oceanic Physics · Physics 2010-10-29 Russell Seitz

The compartmentalization of chemical reactions within droplets has advantages in low costs, reduced consumption of reagents and increased throughput. Reactions in small droplets have also been shown to greatly accelerate the rate of many…

Soft Condensed Matter · Physics 2020-07-27 Brendan P. Dyett , Xuehua Zhang

Nanopores are both a tool to study single-molecule biophysics and nanoscale ion transport, but also a promising material for desalination or osmotic power generation. Understanding the physics underlying ion transport through nano-sized…

Soft Condensed Matter · Physics 2021-04-02 Sanjin Marion , Michal Macha , Sebastian J. Davis , Andrey Chernev , Aleksandra Radenovic

The solvation of charged, nanometer-sized spherical solutes in water, and the effective, solvent-induced force between two such solutes are investigated by constant temperature and pressure Molecular Dynamics simulations of model solutes…

Soft Condensed Matter · Physics 2009-11-10 J. Dzubiella , J. -P. Hansen

Sound driven gas bubbles in water can emit light pulses (sonoluminescence). Experiments show a strong dependence on the type of gas dissolved in water. Air is found to be one of the most friendly gases towards this phenomenon. Recently,…

chao-dyn · Physics 2009-10-28 Michael Brenner , Sascha Hilgenfeldt , Detlef Lohse , ;

The existence of surface nanobubbles has been previously suggested using various experimental techniques, including attenuated total reflection spectroscopy, quartz crystal microbalance, neutron reflectometry, and x-ray reflectivity, but…

In this paper we elaborate on the idea [Lohse et al., Phys. Rev. Lett. 78, 1359-1362 (1997)] that (single) sonoluminescing air bubbles rectify argon. The reason for the rectification is that nitrogen and oxygen dissociate and their reaction…

chao-dyn · Physics 2009-10-30 Detlef Lohse , Sascha Hilgenfeldt
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