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We report the coupled effects of macroion charge discretization and counterion valence in the primitive model for spherical colloids. Instead of considering a uniformly charged surface, as it is traditionally done, we consider a more…

Soft Condensed Matter · Physics 2009-11-07 Rene Messina

The electric field dielectric polarization-based separations mechanism represents a novel method for separating solutions at small length scales. An electric field gradient with a maximum strength of $\mathrm{0.4~MV/m}$ applied across a…

Chemical Physics · Physics 2023-11-29 Gaurav Anand , Samira Safaripour , Craig Snoeyink

Monte-Carlo simulations and small-angle x-ray scattering experiments were used to determine the phase diagram of aqueous dispersions of titratable nano-colloids with a moderate size polydispersity over a broad range of monovalent salt…

The relaxation of atomic polarization in buffer-gas-free, paraffin-coated cesium vapor cells is studied using a variation on Franzen's technique of ``relaxation in the dark'' [Franzen, Phys. Rev. {\bf 115}, 850 (1959)]. In the present…

We study electrostatic mechanisms of destabilization of highly asymmetric electrolytes. For this purpose, we perform primitive model Monte Carlo simulations of charged macroions immersed in multivalent salt solution. At low salt…

Soft Condensed Matter · Physics 2007-06-20 Vladimir Lobaskin , Khawla Qamhieh

Wave-particle interaction is a key process in particle diffusion in collisionless plasmas. We look into the interaction of single plasma waves with individual particles and discuss under which circumstances this is a chaotic process,…

Plasma Physics · Physics 2018-02-01 Cedric Schreiner , Rami Vainio , Felix Spanier

To gain some insight into electrochemical activity of dielectric colloids of technical and biomedical interest we investigate a model of dielectric nanosolution whose micro-constitution is dominated by dipolarions -- positively and…

Soft Condensed Matter · Physics 2014-03-27 Sergey Bastrukov , Pik-Yin Lai , Irina Molodtsova

A better understanding of interfacial mechanisms is needed to improve the performances of electrochemical devices. Yet, simulating an electrode surface at fixed electrolyte composition remains a challenge. Here we apply a finite electric…

Materials Science · Physics 2019-11-13 Thomas Dufils , Guillaume Jeanmairet , Benjamin Rotenberg , Michiel Sprik , Mathieu Salanne

The structure of an aqueous solution of sodium chloride at a planar electrode is investigated by integral equation techniques. With the central force water model the aqueous electrolyte is modelled as a mixture of sodium and chloride ions…

chem-ph · Physics 2009-10-28 M. Vossen , F. Forstmann

We present a mechanism for the stabilization of colloids in liquid mixtures without use of surfactants or polymers. When a suitable salt is added to a solvent mixture, the coupling of the colloid's surface chemistry and the preferential…

Soft Condensed Matter · Physics 2015-06-18 Sela Samin , Yoav Tsori

Modern intense ultrafast pulsed lasers generate an electric field of sufficient strength to permit tunnel ionization of the valence electrons in atoms. This process is usually treated as a rapid succession of isolated events, in which the…

Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…

Soft Condensed Matter · Physics 2021-03-03 Michiel Sprik

In a previous paper we proposed a new method based on resummations for studying radiation reaction of an electron in a plane-wave electromagnetic field. In this paper we use this method to study the electron momentum expectation value for a…

High Energy Physics - Phenomenology · Physics 2021-09-22 Greger Torgrimsson

We develop a thermodynamic description of particles held at a fixed surface potential. This system is of particular interest in view of the continuing controversy over the possibility of a fluid-fluid phase separation in aqueous colloidal…

Soft Condensed Matter · Physics 2009-11-10 Yan Levin , Emmanuel Trizac , Lyderic Bocquet

We investigate numerically and on the scaling level the adsorption of a charged colloid on an oppositely charged flexible membrane. We show that the long ranged character of the electrostatic interaction leads to a wrapping reentrance of…

Biological Physics · Physics 2009-11-10 Christian C. Fleck , Roland R. Netz

We investigate the unfolding of single polyelectrolyte (PE) chains collapsed by trivalent salt under the action of alternating-current (AC) electric fields through computer simulations and theoretical scaling. The results show that a…

Soft Condensed Matter · Physics 2011-01-27 Pai-Yi Hsiao , Yu-Fu Wei , Hsueh-Chia Chang

We present a theoretical study of dielectrophoretic (DEP) crossover spectrum of two polarizable particles under the action of a nonuniform AC electric field. For two approaching particles, the mutual polarization interaction yields a change…

Chemical Physics · Physics 2007-05-23 J. P. Huang , Mikko Karttunen , K. W. Yu , L. Dong

We develop an efficient Ewald method of molecular dynamics simulation for calculating the electrostatic interactions among charged and polar particles between parallel metallic plates, where we may apply an electric field with an arbitrary…

Soft Condensed Matter · Physics 2013-10-01 Kyohei Takae , Akira Onuki

Using the previously developed model we revisit the problem of the electric field induced polarization rotation in antiferroelectric crystals of squaric acid. We test an alternative set of the model parameters, according to which the dipole…

Materials Science · Physics 2023-01-05 A. P. Moina

We study the ionic equilibria and interactions of neutral semi-permeable spherical shells immersed in electrolyte solutions, including polyions. Although the shells are uncharged, only one type of ions of the electrolyte can permeate them,…

Soft Condensed Matter · Physics 2012-07-24 Vladimir Lobaskin , Artem N. Bogdanov , Olga I. Vinogradova