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Surface enhanced Raman scattering (SERS) process results in a tremendous increase of Raman scattering cross section of molecules adsorbed to plasmonic metals and influenced by numerous physico-chemical factors such as geometry and optical…

Chemical Physics · Physics 2021-02-23 Shimon Rubin , Phuong H. L. Nguyen , Yeshaiahu Fainman

We report on the experimental observation of mirror enhanced directional surface enhanced Raman scattering (SERS) from a self-assembled monolayer of molecules coupled to a nanowire-nanoparticle (NW-NP) junction on a mirror in remote…

Optics · Physics 2021-11-17 Sunny Tiwari , Adarsh B Vasista , Diptabrata Paul , G. V. Pavan Kumar

Here we show how surface-enhanced Raman spectroscopy (SERS) features can be fine-tuned in optically active substrates made of layered materials. To demonstrate this, we used DNA-assisted lithography (DALI) to create substrates with silver…

The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic field on rough metal surfaces are considered. It is…

Optics · Physics 2014-11-17 V. P. Chelibanov , A. M. Polubotko

We present experimental demonstration of a recently predicted path interference phenomenon [Nanophotonics 7, 1687 (2018)]. A SERS process becomes resonant when both incident and the converted frequencies match with two plasmon resonances --…

Surface enhanced Raman spectroscopy (SERS) was used to probe the surface chemistry of chlorine-terminated silicon nanocrystal (Si-NC) surfaces in an air-free environment. SERS effect was observed from the thin films of Ag$_x$O using 514 nm…

Materials Science · Physics 2016-06-28 İlker Doğan , Ryan Gresback , Tomohiro Nozaki , Mauritius C. M. van de Sanden

Surface Enhanced Raman Scattering (SERS) and Surface-Enhanced Fluorescence (SEF) are studied within the framework of modified Spontaneous Emission (SE), and similarities and differences are highlighted. This description sheds new light into…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , P. G. Etchegoin

The surface-enhanced Raman scattering in graphene deposited on AlxGa1-xN/GaN axial heterostructure nanowires was investigated. The intensity of graphene Raman spectra was found not to be correlated with aluminium content. Analysis of…

We study Raman scattering in active media placed in proximity of different types of metal nanostructures, at wavelengths that display either Fabry-Perot or plasmonic resonances, or a combination of both. We use a semi-classical approach to…

Optics · Physics 2015-06-05 M. Scalora , M. A. Vincenti , D. de Ceglia , M. Grande , J. W. Haus

Surface-enhanced Raman spectroscopy is a powerful and versatile sensing method with a detection limit down to the single molecule level. In this article, we demonstrate how topology optimization (TopOpt) can be used for designing surface…

Mesoscale and Nanoscale Physics · Physics 2021-08-25 Ying Pan , Rasmus E. Christiansen , Jerome Michon , Juejun Hu , Steven G. Johnson

Synthesis and characterization of high-quality single-crystal WSe2 films on highly-insulating substrate is presented. We demonstrate for the first time that the presence of gold nanoparticles in the basal plane of a WSe2 film can enhance…

Mesoscale and Nanoscale Physics · Physics 2018-11-21 Bablu Mukherjee , Wei Sun Leong , Yida Li , Hao Gong , Linfeng Sun , Ze Xiang Shen , Ergun Simsek , John T. L. Thong

A new type of excitations by highly focused electron beams in scanning transmission electron microscopes is predicted for nanoparticles. The calculated electron energy loss spectra of metallic (silver) and insulating (SiO(sub2))…

Materials Science · Physics 2011-11-09 M. A. Itskovsky , H. Cohen , T. Maniv

Localized surface plasmons are charge density oscillations confined to metallic nanoparticles. Excitation of localized surface plasmons by an electromagnetic field at an incident wavelength where resonance occurs results in a strong light…

Analysis of PDEs · Mathematics 2015-06-03 Habib Ammari , Pierre Millien , Matias Ruiz , Hai Zhang

Surface enhanced Raman spectroscopy (SERS) is a useful multidisciplinary analytic technique. However, it is still a challenge to produce SERS substrates that are highly sensitive, reproducible, stable, reusable, and scalable. Here, we…

Mesoscale and Nanoscale Physics · Physics 2016-07-14 Qiran Cai , Srikanth Mateti , Wenrong Yang , Rob Jones , Kenji Watanabe , Takashi Taniguchi , Shaoming Huang , Ying Chen , Lu Hua Li

The problem of enhanced molecular emission in close proximity to dielectric and metallic interfaces is of great importance for many physical and biological applications. Here we present an exact treatment of the problem from the view point…

Optics · Physics 2022-11-10 Dentcho A Genov

Raman-based technologies have enabled many ground-breaking scientific discoveries related to surface science, single molecule chemistry and biology. For example, researchers have identified surface bound molecules by their Raman vibrational…

Optics · Physics 2020-03-12 Xiaoqin Shen , Hyungwoo Choi , Dongyu Chen , Wei Zhao , Andrea M. Armani

We present a general framework for inverse design of nanopatterned surfaces that maximize spatially averaged surface-enhanced Raman (SERS) spectra from molecules distributed randomly throughout a material or fluid, building upon a recently…

A tri-layer metamaterial perfect absorber of light, consisting of (Al/ZnS/Al) films with the top aluminium layer patterned as an array of circular disk nanoantennas, is investigated for resonantly enhancing Raman scattering from C-60…

Optics · Physics 2018-11-02 Sriram Guddala , Narayanarao Desai , S. Anantha Ramakrishna

Silver nanoparticles dispersed on the surface of an inverted GaN LED were found to plasmonically enhance the near-bandedge emission. The resonant surface plasmon coupling led to a significant enhancement in the exciton decay rate and the…

Photo-Induced Enhanced Raman Spectroscopy (PIERS) is a new surface enhanced Raman spectroscopy (SERS) modality with an order-of-magnitude Raman signal enhancement of adsorbed analytes over that of typical SERS substrates. Despite the…

Materials Science · Physics 2021-06-01 Junzhi Ye , Rakesh Arul , Michel K. Nieuwoudt , Junzhe Dong , Wei Gao , M. Cather Simpson
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