Related papers: Prospects for high-resolution microwave spectrosco…
The methanol molecule CH3OH has a complex microwave spectrum with a large number of very strong lines. This spectrum includes purely rotational transitions as well as transitions with contributions of the internal degree of freedom…
Full-dimensional (12D) vibrational states of the methanol molecule (CH$_3$OH) have been computed using the GENIUSH-Smolyak approach and the potential energy surface from Qu and Bowman (2013). All vibrational energies are converged better…
Recently, methanol was identified as a sensitive target system to probe variations of the proton-to-electron mass ratio $\mu$ [Jansen \emph{et al.} Phys. Rev. Lett. \textbf{106}, 100801 (2011)]. The high sensitivity of methanol originates…
We report on the using of torsion-rotational transitions in the CH3OH and (13)CH3OH molecules to evaluate possible variations of the physical constant mu=m_e/m_p - the electron-to-proton mass ratio - from spectral observations of emission…
Torsion-rotation transitions in molecules exhibiting hindered internal rotation possess enhanced sensitivities to a variation of the proton-to-electron mass ratio. This enhancement occurs due to a cancellation of energies associated with…
Methanol is observed in a wide range of astrophysical sources throughout the universe, and comprehensive databases of the millimeter and THz spectra of CH3OH and its principal isotopologues represent important tools for the astronomical…
Numerical calculations of the sensitivity coefficients, Q_mu, of microwave molecular transitions in the ground torsion-rotation state of deuterated methanol (CH3OD, CD3OH, and CD3OD) to small variations in the fundamental physical constant…
We present results on simultaneous observations of Class~I methanol masers at 25, 36, and 44 GHz towards 22 Galactic targets carried out with the Effelsberg 100-m telescope. The study investigates relations between the hyperfine (HF)…
Methanol is an abundant molecule in space. The column density of CH$_3^{18}$OH is in some star-forming regions so high that the search for CH$_3^{17}$OH is promising. But only very few transition frequencies of CH$_3^{17}$OH with a…
Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…
We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main…
We have started a measurement campaign of numerous methanol isotopologs in low-lying torsional states in order to provide extensive line lists for radio astronomical observations from an adequate spectroscopic model and to investigate how…
Observations of Serpens have been performed at the JCMT using Harp-B. Maps over a 4.5'x5.4' region were made in a frequency window around 338 GHz, covering the 7-6 transitions of methanol. Emission is extended over each source, following…
Deuterated molecules have been detected and studied toward Orion BN/KL in the past decades, mostly with single-dish telescopes. However, high angular resolution data are critical not only for interpreting the spatial distribution of the…
The abundance of deuterated molecules in a star-forming region is sensitive to the environment in which they are formed. Deuteration fractions therefore provide a powerful tool for studying the physical and chemical evolution of a…
Observations of the frequencies of different rotational transitions of the methanol molecule have provided the most sensitive probe to date for changes in the proton-to-electron mass ratio, over space and time. Using methanol absorption…
Using the Haystack Observatory 37-m radio telescope we have undertaken a search for emission in the 2(0)-3(1)E rotational transition of methanol in its first torsionally excited state (v_t=1) at 44.9 GHz. We examined seven galactic sources…
Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the…
The deuteration of molecules forming in the ices such as methanol (CH$_3$OH) is sensitive to the physical conditions during their formation in dense cold clouds and can be probed through observations of deuterated methanol in hot cores.…
The possibility of using astrophysical observations of rotational transitions in the methanol molecule to measure, or constrain temporal and spatial variations in the proton-to-electron mass ratio (mu) has recently been investigated by…