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Metal-organic frameworks (MOFs) are a highly tunable class of crystalline materials where metal atoms or clusters are connected by organic linkers. They offer a versatile platform for exploring quantum phenomena such as entangled magnetism,…

Strongly Correlated Electrons · Physics 2025-12-25 Natalia Drichko , V. Sara Thoi , N. Peter Armitage

Finding new two-dimensional (2D) materials with novel quantum properties is highly desirable for technological innovations. In this work, we studied a series of metal-organic frameworks (MOFs) with different metal cores and discovered…

Materials Science · Physics 2020-11-17 Jie Li , Ruqian Wu

Perovskite metal-organic frameworks (MOFs) have recently emerged as potential candidates for multiferroicity. However, the compounds synthesized so far possess only weak ferromagnetism and low polarization. Additionally, the very low…

Materials Science · Physics 2018-01-24 Paresh Chandra Rout , Varadharajan Srinivasan

Through rational chemical design, and thanks to the hybrid nature of metal-organic frameworks (MOFs), it is possible to prepare molecule-based 2D magnetic materials stable at ambient conditions. Here, we illustrate the versatility of this…

Magnetic metal-organic frameworks (MMOFs), where magnetic metal nodes are connected into a crystal structure by organic linkers, have a potential to host exotic magnetic states. We present a study of bulk magnetic properties of four…

Ferromagnetism (FM) is the cornerstone of permanent magnets, data storage and other technologies that directly impact our everyday life by their implementation in standard applications and devices. When downscaling bulk materials into their…

Multiferroicity and magnetodielectric coupling in metal-organic-frameworks (MOFs) is rare and so far restricted mainly to formate-based systems with perovskite structure. In the course of this work we designed a tetragonal framework…

Materials Science · Physics 2017-10-31 Tathamay Basu , A. Jesche , B. Bredenkotter , M. Grzywa , D. Denysenko , D. Volkmer , A. Loidl , S. Krohns

Metal-organic frameworks (MOFs) combine high porosity with structural fragility, raising important questions about their mechanical stability. We develop a rigidity-based framework in which spring networks parameterized by UFF4MOF are used…

Materials Science · Physics 2026-03-06 Christopher M. Owen , Michael J. Lawler

Organic and molecule-based magnets are not easily attainable, because to introduce stable paramagnetic centers to pure organic systems is challenging. Crystalline covalent organic frameworks (COFs) with high designability and chemical…

Chemical Physics · Physics 2020-06-09 Hongde Yu , Dong Wang

Metal-organic frameworks (MOFs) are an important class of materials that present intriguing opportunities in the fields of sensing, gas storage, catalysis, and optoelectronics. Very recently, two-dimensional (2D) MOFs have been proposed as…

Materials Science · Physics 2018-10-15 Avijit Kumar , Kaustuv Banerjee , Adam S. Foster , Peter Liljeroth

Metal-organic frameworks (MOFs) symbolize the particular class of hybrid crystalline, nano-porous materials made of either discrete metal ions or clusters with organic linkers. Past studies on MOFs-based materials largely focused on…

Materials Science · Physics 2022-06-28 Ranjeev Kumar Parashar , Priyajit Jash , Prakash Chandra Mondal

Using density functional theory (DFT), we investigate mechanical properties of a few 2D metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) having Dirac and flat bands. These porous materials have become a subject of…

Materials Science · Physics 2023-03-15 Priyadarshini Kapri , Takuto Kawakami , Mikito Koshino

The potential to utilize metal-organic frameworks as a replacement for rare earth materials as well as in technological applications has prompted increased interested in this material class. The simulation of organic materials, including…

Materials Science · Physics 2026-05-01 Alexander C. Tyner , Avinash Pathapati , Alexander V. Balatsky

A combination of variable-temperature neutron scattering, reverse Monte Carlo analysis and direct Monte Carlo simulation is used to characterise the emergence of magnetic order in the metal--organic framework (MOF) Tb(HCOO)$_3$ over the…

Disordered Systems and Neural Networks · Physics 2016-12-21 Daniel R. Harcombe , Philip G. Welch , Pascal Manuel , Paul J. Saines , Andrew L. Goodwin

The magnetoresistance (MR) of a material is typically insensitive to reversing the applied field direction and varies quadratically with magnetic field in the low-field limit. Quantum effects [1], unusual topological band structures [2],…

Two-dimensional (2D) metal-organic frameworks (MOFs) in a kagome lattice can exhibit strong electron-electron interactions, which can lead to tunable quantum phases including many exotic magnetic phases. While technological developments of…

Strongly Correlated Electrons · Physics 2022-11-10 Bernard Field , Agustin Schiffrin , Nikhil V. Medhekar

We investigate the magnetism of the Co$^{II}_4$(OH)$_2$(C$_1$$_0$H$_1$$_6$O$_4$)$_3$ metal-organic framework which displays complex inorganic chains separated from each other by distances of 1 to 2 nm, and which orders at ~5.4 K. The…

We combine infrared spectroscopy, nano-indentation measurements, and \emph{ab initio} simulations to study the evolution of structural, elastic, thermal, and electronic responses of the metal organic framework MOF-74-Zn when loaded with…

Materials Science · Physics 2014-12-23 Pieremanuele Canepa , Kui Tan , Yingjie Du , Hongbing Lu , Yves J. Chabal , T. Thonhauser

Metal-organic frameworks (MOFs) are a specific class of hybrid, crystalline, nano-porous materials made of metal-ion-based nodes and organic linkers. Most of the studies on MOFs largely focused on porosity, chemical and structural…

Materials Science · Physics 2024-01-17 Ranjeev Kumar Parashar , Priyajit Jash , Michael Zharnikov , Prakash Chandra Mondal

Metal--organic frameworks (MOFs) are a family of chemically diverse materials, with applications in a wide range of fields covering engineering, physics, chemistry, biology and medicine. Research so far has focused almost entirely on…

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