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We study the performance scaling of three quantum algorithms for combinatorial optimization: measurement-feedback coherent Ising machines (MFB-CIM), discrete adiabatic quantum computation (DAQC), and the D\"urr-Hoyer algorithm for quantum…

We propose an unconstrained optimization method based on the well-known primal-dual hybrid gradient (PDHG) algorithm. We first formulate the optimality condition of the unconstrained optimization problem as a saddle point problem. We then…

Optimization and Control · Mathematics 2024-08-29 X. Zuo , S. Osher , W. Li

An effective means for analyzing the impact of novel operating schemes on power systems is time domain simulation, for example for investigating optimization-based curtailment of renewables to alleviate voltage violations. Traditionally,…

Optimization and Control · Mathematics 2016-07-27 Sandro Merkli , Alexander Domahidi , Juan Jerez , Manfred Morari , Roy S. Smith

We propose a framework to learn the time-dependent Hartree-Fock (TDHF) inter-electronic potential of a molecule from its electron density dynamics. Though the entire TDHF Hamiltonian, including the inter-electronic potential, can be…

Chemical Physics · Physics 2024-12-05 Harish S. Bhat , Prachi Gupta , Christine M. Isborn

We present a fully numerical framework for the optimization of molecule-specific quantum chemical basis functions within the quantics tensor train format using a finite-difference scheme. The optimization is driven by solving the…

Chemical Physics · Physics 2025-06-12 Paul Haubenwallner , Matthias Heller

In this paper, through a very intuitive vanilla proximal method perspective, we derive accelerated high-order optimization algorithms for minimizing a convex function that has H\"{o}lder continuous derivatives. In this general convex…

Optimization and Control · Mathematics 2019-10-01 Chaobing Song , Yong Jiang , Yi Ma

Nonequispaced discrete Fourier transformation (NDFT) is widely applied in all aspects of computational science and engineering. The computational efficiency and accuracy of NDFT has always been a critical issue in hindering its…

Mathematical Software · Computer Science 2020-08-06 Sheng-Chun Yang , Yong-Lei Wang

First-order optimization algorithms can be considered as a discretization of ordinary differential equations (ODEs) \cite{su2014differential}. In this perspective, studying the properties of the corresponding trajectories may lead to…

Optimization and Control · Mathematics 2022-06-22 Jean-François Aujol , Charles Dossal , Văn Hào Hoàng , Hippolyte Labarrière , Aude Rondepierre

We present unrestricted Hartree Fock method coupled with configuration interaction (CI) method (URHF-CI) suitable for the calculation of ground and excited states of large number of electrons localized by complex gate potentials in…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Ramin M. Abolfath , Pawel Hawrylak

The general procedure underlying Hartree-Fock and Kohn-Sham density functional theory calculations consists in optimizing orbitals for a self-consistent solution of the Roothaan-Hall equations in an iterative process. It is often ignored…

Chemical Physics · Physics 2017-03-16 Alain C. Vaucher , Markus Reiher

In many data classification problems, there is no linear relationship between an explanatory and the dependent variables. Instead, there may be ranges of the input variable for which the observed outcome is signficantly more or less likely.…

Machine Learning · Computer Science 2016-04-13 Mallory Sheth , Roy Welsch , Natasha Markuzon

In two-sided matching market, when the regional constraints are present, the deferred acceptance (DA) algorithm suffers from undesirable inefficiency due to the artificial allocation of the regional caps among hospitals. We show that, given…

Theoretical Economics · Economics 2025-04-25 Elizabeth Nanami Aoi

We propose a simple iterative algorithm to construct the optimal multi-configuration approximation of an $N$-fermion wave function. That is, $M\geq N $ single-particle orbitals are sought iteratively so that the projection of the given wave…

Quantum Physics · Physics 2014-01-10 J. M. Zhang , Marcus Kollar

We develop a new approximation theory for linear and quadratic interpolation models, suitable for use in convex-constrained derivative-free optimization (DFO). Most existing model-based DFO methods for constrained problems assume the…

Optimization and Control · Mathematics 2024-03-25 Lindon Roberts

The Hartree-Fock equation is a fundamental equation in many-electron problems. It is of practical importance in quantum chemistry to find solutions to the Hartree-Fock equation. The self-consistent field (SCF) method is a standard numerical…

Analysis of PDEs · Mathematics 2023-11-17 Sohei Ashida

Practical applicability of quantum optimisation on near term devices is constrained by limited qubit counts and hardware noise, which restricts the scalability of quantum optimisation algorithms for combinatorial problems. The simulation of…

Quantum Physics · Physics 2026-05-01 Namasi G Sankar , Georgios Miliotis , Simon Caton

An optimization algorithm for nonsmooth nonconvex constrained optimization problems with upper-C2 objective functions is proposed and analyzed. Upper-C2 is a weakly concave property that exists in difference of convex (DC) functions and…

Optimization and Control · Mathematics 2022-04-21 Jingyi Wang , Cosmin G. Petra

Existing algorithms to solve alternating-current optimal power flow (AC-OPF) often exploit linear approximations to simplify system models and accelerate computations. In this paper, we improve a recent hierarchical OPF algorithm, which…

Optimization and Control · Mathematics 2023-02-09 Heng Liang , Xinyang Zhou , Changhong Zhao

Quantum Annealing (QA) and QAOA are promising quantum optimisation algorithms used for finding approximate solutions to combinatorial problems on near-term NISQ systems. Many NP-hard problems can be reformulated as Quadratic Unconstrained…

Quantum Physics · Physics 2025-10-06 Namasi G Sankar , Georgios Miliotis , Simon Caton

The massive integration of distributed energy resources changes the operational demands of the electric power distribution system, motivating optimization-based approaches. The added computational complexities of the resulting optimal power…

Optimization and Control · Mathematics 2023-07-04 Yunqi Luo , Rabayet Sadnan , Bala Krishnamoorthy , Anamika Dubey