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In order to develop a better understanding of electrochemical $\mathrm{O_2}$ reduction in non-aqueous solvents, we apply two-photon photoelectron spectroscopy to probe the dynamics of $\mathrm{O_2}$ reduction at a DMSO/Cu(111) model battery…

Materials Science · Physics 2023-01-12 Angelika Demling , Sarah B. King , Philip Shushkov , Julia Stähler

When two reservoirs of a distinct salinity are connected by channels or pores, a fluid flow termed diffusio-osmotic is generated. This article investigates the flow emerging in an uniformly charged long slit whose thickness exceeds the…

Fluid Dynamics · Physics 2026-04-27 Elena F. Silkina , Evgeny S. Asmolov , Olga I. Vinogradova

Two-dimensional (2D) nanomaterials exhibit unique properties that are promising for diverse applications, including those relevant to concentration-gradient-driven transport of electrolyte solutions through porous membranes made from these…

Soft Condensed Matter · Physics 2025-02-21 Holly C. M. Baldock , David M. Huang

A quantitative relationship between the diffusion coefficient $D$ of a tagged particle in a liquid and the entropy $S$ of that liquid has long been sought, as it would allow entropy to be inferred directly from diffusion measurements and…

Statistical Mechanics · Physics 2025-09-25 Nayana Venkatareddy , Mohd Moid , Prabal K. Maiti , Biman Bagchi

We develop and verify a phase-sensitive second harmonic generation spectroscopic scheme that allows for direct determination of the absolute surface charge density and surface potential of a water interface without need of prior interfacial…

Chemical Physics · Physics 2019-08-27 Laetitia Dalstein , Kuo-Yang Chiang , Yu-Chieh Wen

The strongly correlated electron fluids in high temperature cuprate superconductors demonstrate an anomalous linear temperature ($T$) dependent resistivity behavior, which persists to a wide temperature range without exhibiting saturation.…

Superconductivity · Physics 2017-08-01 Tao Hu , Yinshang Liu , Hong Xiao , Gang Mu , Yi-feng Yang

The calculation of the solvation properties of a single water molecule in liquid water is carried out in two ways. In the first, the water molecule is placed in a cavity and the solvent is treated as a dielectric continuum. This model is…

chem-ph · Physics 2008-02-03 Steven W. Rick , B. J. Berne

Biological water is an ionic solution containing both monovalent and divalent ions. However, the effects of divalent ions on the dynamics of biological water remain largely unknown. Here, we investigate how the transport dynamics of water…

Soft Condensed Matter · Physics 2026-05-26 Minho Lee , Jinwon Park , Ji-Hyun Kim , Minhaeng Cho , Jaeyoung Sung

The dependence of DNA assemblies conductance on relative humidity is investigated theoretically. Following earlier suggestions, we consider the ionic conductivity through the layers of water adsorbed by DNA molecules. The increase in…

Chemical Physics · Physics 2015-05-14 J. M. Leveritt , S. Tesar , C. Dibaya , R. Shrestha , A. L. Burin

In nematic liquid crystals light is strongly scattered from director fluctuations. We are interested in the limit where the incoming light wave is scattered many times. Then, the light transport can be described by a diffusion equation for…

Soft Condensed Matter · Physics 2008-02-03 Holger Stark

In electrochemical systems, an understanding of the underlying transport processes is required to aid in their better design. This includes knowledge of possible near-electrode convective mixing that can enhance measured currents. Here, for…

Fluid Dynamics · Physics 2021-09-15 Nakul Pande , Jeffery A. Wood , Guido Mul , Detlef Lohse , Bastian T. Mei , Dominik Krug

We present a minimal model to analyze the capacitive response of a biological membrane subjected to a step voltage via blocking electrodes. Through a perturbative analysis of the underlying electrolyte transport equations, we show that the…

Soft Condensed Matter · Physics 2025-03-07 Jafar Farhadi , Joshua B. Fernandes , Karthik Shekhar , Kranthi K. Mandadapu

Energy dissipation in water is very fast and more efficient than in many other liquids. This behavior is commonly attributed to the intermolecular interactions associated with hydrogen bonding. Here, we investigate the dynamic energy flow…

A system in equilibrium keeps ``exploring" nearby states in the phase space and consequently, fluctuations can contain information, that the mean value does not. However, such measurements involve a fairly complex interplay of effects…

Mesoscale and Nanoscale Physics · Physics 2024-02-22 Bikash C. Barik , Himadri Chakraborti , Aditya K. Jain , Buddhadeb Pal , H. E. Beere , D. A. Ritchie , K. Das Gupta

We investigate the variation of the oscillation frequency of the Mg$^{2+}$ and O$^{2-}$ ions in the magnesium oxide lattice due to the interactions of the surface with water monolayers by means of Low Energy Electron Diffraction. Our key…

Heterostructures of 2D materials offer a fertile ground to study ion transport and charge storage. Here we employ ab initio molecular dynamics to examine the proton-transfer/diffusion and redox behavior in a water layer confined in the…

Chemical Physics · Physics 2022-01-12 Lihua Xu , De-en Jiang

We consider the problem of Coulomb drag resistance in bilayers of electron liquids with spontaneously broken time-reversal symmetry. In the hydrodynamic regime, the viscosity tensor of such fluids has a nonvanishing odd component. In this…

Mesoscale and Nanoscale Physics · Physics 2025-07-14 Dmitry Zverevich , Dmitri B. Gutman , Alex Levchenko

Dielectric spectra of human blood reveal a rich variety of dynamic processes. Achieving a better characterization and understanding of these processes not only is of academic interest but also of high relevance for medical applications as,…

Biological Physics · Physics 2015-03-13 M. Wolf , R. Gulich , P. Lunkenheimer , A. Loidl

The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem…

Soft Condensed Matter · Physics 2009-11-10 Martin Z. Bazant , Katsuyo Thornton , Armand Ajdari

The structure and dynamics of aqueous solvation of ethanol and ethylene are studied by DFT-based Car-Parrinello molecular dynamics. We did not find an enhancement of the structure of the hydrogen bonded network of hydrating water molecules.…

Chemical Physics · Physics 2009-11-07 Titus S. van Erp , Evert Jan Meijer
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