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We suggest an explanation of the recently observed discrepancy between the experimental and theoretical results on ionization of atoms, encapsulated into the fullerenes by photons with the energies of about 80-190eV. On the ground of…

Atomic Physics · Physics 2015-06-19 M. Ya. Amusia , L. V. Chernysheva , E. G. Drukarev

We analyze the role of shake-off and of the final state interactions in inelastic processes in the fullerene shell which follow ionization of the caged atom. We demonstrate that in the broad interval of the photon energies the process is…

Atomic Physics · Physics 2013-02-21 M. Ya. Amusia , E. G. Drukarev

We present the main features of the electronic structure of the heavy atoms that is best of all seen in photoionization. We acknowledge how important was and still is investigation of the interaction between low- and high frequency lasers…

Atomic Physics · Physics 2015-06-03 M. Ya. Amusia

The photoionization of a two-shell endohedral A@CN1@CN2 is considered. Formulas are presented for cross-sections and angular anisotropy parameters, both dipole and non-dipole. The effect of the fullerenes shell upon photoelectron from atom…

Atomic and Molecular Clusters · Physics 2013-05-29 M. Ya. Amusia , L. V. Chernysheva , E. Z. Liverts

We calculate the photoionization cross-section of a molecular endohedral. We limit ourselves to two-atomic molecules. The consideration is much more complex than for atomic endohedrals because the system even for almost spherical fullerenes…

Atomic and Molecular Clusters · Physics 2019-09-04 M. Ya. Amusia , L. V. Chernysheva , S. K. Semenov

We have calculated photoionization cross-section of endohedral atoms A@CN. We took into account the polarizability of the fullerene electron shell CN that modifies the incoming photon beam and the one-electron wave functions of the caged…

Atomic and Molecular Clusters · Physics 2019-03-27 M. Ya. Amusia , L. V. Chernysheva

We study the interconnection between the results of two qualitatively different approximate calculations of photoionization cross sections, $\sigma_{n\ell}$, for neutral atoms ($A$) or their cations ($A^+$), centrally confined inside a…

Atomic Physics · Physics 2024-09-19 V. K. Dolmatov , L. V. Chernysheva , V. G. Yarzhemsky

We discuss the complicated resonance structure of the endohedral atom photoionization cross section. Very strong enhancement and interference patterns in the photoionization cross-section of the valent and subvalent subshells of noble gas…

Atomic Physics · Physics 2008-06-03 M. Ya. Amusia , L. V. Chernysheva

We demonstrate the prominent modification of the outer shell photoionization cross-section in noble gas (NG) endohedral atoms NG@F under the action of the fullerene F electron shell. This shell leads to two important effects, namely to…

Atomic and Molecular Clusters · Physics 2009-11-13 M. Ya. Amusia , A. S. Baltenkov , L. V. Chernysheva

We demonstrate strong interference patterns in the photoionization cross-section of the subvalent subshells of noble gas (NG) endohedral atoms NG@F. This interference is a result of common action of three factors: the effect of neighboring…

Atomic and Molecular Clusters · Physics 2007-10-25 M. Ya. Amusia , A. S. Baltenkov , L. V. Chernysheva

We discuss the influence of a single or double fullerenes shell upon photoionization and vacancy decay of an atom, stuffed inside the fullerenes construction. The main manifestations of this influence are additional structures in the…

Atomic Physics · Physics 2009-06-23 M. Ya. Amusia

We concentrate here on photon absorption as well as electron and positron scattering upon endohedrals that consist of a fullerenes shell and an inner atom A. The aim is to understand the effect of fullerene electron shell in formation of…

Atomic and Molecular Clusters · Physics 2018-02-12 M. Ya. Amusia , A. F. Ioffe

We demonstrate the role played by the fullerene shell in the photoionization and vacancy decay of endohedral atoms A@C60. It is shown, partly in the frame of a rather simple model that describes the fullerene shell, partly using only the…

Chemical Physics · Physics 2007-05-23 M. Ya. Amusia

We have demonstrated that the polarization of the fullerene shell considerably alters the polarization potential of an atom, stuffed inside a fullerene. This essentially affects the electron elastic scattering phases as well as…

Atomic and Molecular Clusters · Physics 2016-06-22 M. Ya. Amusia , L. V. Chernysheva

The ionization of an atom by a high-frequency intense laser pulse, where the energy of a single-photon is sufficient to ionize the system, is investigated from first principles. It is shown that as a consequence of an AC Stark effect in the…

Atomic Physics · Physics 2012-06-26 Philipp V Demekhin , Lorenz S Cederbaum

Using $He@C_{60}$ as an example, we demonstrate that static potential of the fullerene core essentially alters the cross section of the two-electron ionization differential in one-electron energy $d\sigma ^{++}(\omega )/d\epsilon $. We…

Atomic Physics · Physics 2009-11-11 M. Ya. Amusia , E. Z. Liverts , V. B. Mandelzweig

In this Letter, we investigate the variation of endohedral A@CN potential due to addition at the center of it a positive charge, for example, in the process of atom A photoionization. Using a reasonable model to describe the fullerenes…

Atomic and Molecular Clusters · Physics 2019-10-29 M. Ya. Amusia , A. S. Baltenkov , L. V. Chernysheva

The interactions between atoms and molecules may be described by a potential energy function of the nuclear coordinates. Non-bonded interactions are dominated by repulsive forces at short range and attractive dispersion forces at long…

Photoionization calculations of the endofullerene molecule Cl@$C_{60}$ with an open-shell chlorine atom are performed in the time-dependent local density approximation (TDLDA) based on a spherical jellium model. Cross sections for…

Atomic and Molecular Clusters · Physics 2021-06-08 Dakota Shields , Ruma De , Mohamed El-Amine Madjet , Steven T. Manson , Himadri S. Chakraborty

In this Letter, we investigate the time delay of photoelectrons by fullerenes shell in endohedrals. We present general formulas in the frame of the random phase approximation with exchange (RPAE) applied to endohedrals A@CN that consist of…

Atomic and Molecular Clusters · Physics 2020-10-28 M. Ya. Amusia , L. V. Chernysheva
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