Related papers: Anomalous CO2 Ice Toward HOPS-68: A Tracer of Prot…
This paper presents Spitzer-IRS spectroscopy of the CO2 15.2 micron bending mode toward a sample of 50 embedded low-mass stars in nearby star-forming clouds, taken mostly from the ``Cores to Disks (c2d)'' Legacy program. The average…
Sensitive 5-38 um Spitzer Space Telescope (SST) and ground based 3-5 um spectra of the embedded low mass protostars B5 IRS1 and HH46 IRS show deep ice absorption bands superposed on steeply rising mid-infrared continua. The ices likely…
Analyses of infrared signatures of CO$_2$ in water dominated ices in the ISM can give information on the physical state of CO$_2$ in icy grains and on the thermal history of the ices themselves. In many sources, CO$_2$ was found in the…
Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust…
We present observations of the stretching mode of 13CO2 ice along 13 lines of sight in the Galaxy, using the Short Wavelength Spectrometer on board of the Infrared Space Observatory. Remarkable variations are seen in the absorption band…
Aims: Ices in dense star-forming cores contain the bulk of volatile molecules apart from H2 and thus represent a large fraction of dark cloud chemistry budget.To directly constrain the freeze-out profile of CO, the formation route of CO2…
The structure and composition of simple ices can be modified during stellar evolution by protostellar heating. Key to understanding the involved processes are thermal and chemical tracers that can diagnose the history and environment of the…
The composition of protoplanetary disks, and hence the initial conditions of planet formation, may be strongly influenced by the infall and thermal processing of material during the protostellar phase. Composition of dust and ice in…
We present the Spitzer Space Telescope Infrared Spectrograph spectrum of the Orion A protostar HOPS-68. The mid-infrared spectrum reveals crystalline substructure at 11.1, 16.1, 18.8, 23.6, 27.9, and 33.6 microns superimposed on the broad…
The evolution of interstellar ices can be studied with thermal tracers such as the vibrational modes of CO$_2$ ice that show great diversity depending on their local chemical and thermal environment. In this work we present JWST…
We report the first fully sampled maps of the distribution of interstellar CO2 ices, H2O ices and total hydrogen nuclei, as inferred from the 9.7 micron silicate feature, toward the star-forming region Cepheus A East with the IRS instrument…
We present Spitzer IRS spectroscopy of CO2 ice bending mode spectra at 15.2 micrometer toward 19 young stellar objects with luminosity lower than 1 Lsun (3 with luminosity lower than 0.1 Lsun). Ice on dust grain surfaces can encode the…
Carbon dioxide is abundant in ice mantles of dust grains; some is found in the pure crystalline form as inferred from the double peak splitting of the bending profile at about 650 cm$^{-1}$. To study how CO$_2$ segregates into the pure form…
The mobility of atoms, molecules and radicals in icy grain mantles regulate ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore)…
Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2…
JWST has shown that CO2 and CO are common on the surfaces of objects in the Kuiper belt and have apparent surface coverages even higher than that of water ice, though water ice is expected to be significantly more abundant in the bulk…
We present the first Spitzer Infrared Spectrograph observations of the 15.2 micron bending mode of CO2 ice towards field stars behind a quiescent dark cloud. CO2 ice is detected towards 2 field stars (Elias 16, Elias 3) and a single…
We present 5.2-37.2 micron spectroscopy of the edge-on circumstellar disk CRBR 2422.8-3423 obtained using the InfraRed Spectrograph (IRS) of the Spitzer Space Telescope. The IRS spectrum is combined with ground-based 3-5 micron spectroscopy…
CO$_2$ is an important, stable, and abundant molecule in the Universe, but it is very difficult to detect because it has no observable pure rotational transitions. The unique sensitivity and resolution of the James Webb Space Telescope…
CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…