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We use DFT to study the effect of molecular adsorbates on the conductance of metallic carbon nanotubes. The five molecules considered (NO2, NH2, H, COOH, OH) lead to similar scattering of the electrons. The adsorption of a single molecule…

Mesoscale and Nanoscale Physics · Physics 2008-10-02 Juan Maria Garcia-Lastra , Kristian S. Thygesen , Mikkel Strange , Angel Rubio

We report the transmission over a wide frequency range (far infrared - visible) of pristine and hole-doped, free-standing carbon nanotube films at temperatures between 50 K and 300 K. Optical constants are estimated by Kramers-Kronig…

Materials Science · Physics 2013-05-29 F. Borondics , K. Kamaras , M. Nikolou , D. B. Tanner , Z. H. Chen , A. G. Rinzler

Carbon nanotubes (CNTs) are a promising material for high-performance electronics beyond silicon. But unlike silicon, the nature of the transport band gap in CNTs is not fully understood. The transport gap in CNTs is predicted to be…

In this article, we show that it is possible to differentiate between water adsorbed on the outside of a single-walled carbon nanotube and that confined inside. To this aim, we measured the electronic transport of a carbon nanotube based…

Recent advances in nanotechnology have provided new materials which have the potential to surpass copper and aluminum alloys in electrical conductivity, weight and ampacity [2-6]. Among these carbon nanotubes (CNTs) stand out due to their…

Applied Physics · Physics 2020-08-28 Farhad Daneshvar , Hung-Jue Sue

Carbon nanotubes are the focus of considerable research efforts due to their fascinating physical properties. They provide an excellent model system for the study of one dimensional materials and molecular electronics. The chirality of…

Controlling doping is essential for a successful integration of semiconductor materials into device technologies. However, the assessment of doping levels and the distribution of charge carriers in carbon nanotubes or other nanoscale…

We have performed experiments on single-wall carbon nanotube (SWNT) networks and compared with density-functional theory (DFT) calculations to identify the microscopic origin of the observed sensitivity of the network conductivity to…

Mesoscale and Nanoscale Physics · Physics 2010-01-15 D. J. Mowbray , C. Morgan , K. S. Thygesen

We study the conductance of carbon nanotube wires in the presence of disorder, in the limit of phase coherent transport. For this purpose, we have developed a simple numerical procedure to compute transmission through carbon nanotubes and…

Condensed Matter · Physics 2009-10-31 M. P. Anantram , T. R. Govindan

We show that the presence of electrically insulating graphite oxide (GO) within a single wall carbon nanotube network strongly enhances electrical conductivity, whereas reduced graphite oxide, even though electrically conductive, suppresses…

Multiwalled carbon nanotubes are shown to be ballistic conductors at room temperature, with mean free paths of the order of tens of microns. These experiments follow and extend the original experiments by Frank et al (Science, 280 1744…

Materials Science · Physics 2007-05-23 Philippe Poncharal , Claire Berger , Yan Yi , Z. L. Wang , Walt A. de Heer

Electronic states and transport properties of double-wall carbon nanotubes without impurities are studied in a systematic manner. It is revealed that scattering in the bulk is negligible and the number of channels determines the average…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Seiji Uryu

Using first-principles calculations, we investigate the electronic structures and binding properties of nicotine and caffeine adsorbed on single-walled carbon nanotubes to determine whether CNTs are appropriate for filtering or sensing…

Mesoscale and Nanoscale Physics · Physics 2013-07-10 Hyung-June Lee , Gunn Kim , Young-Kyun Kwon

Semiconducting single-walled carbon nanotubes are studied in the diffusive transport regime. The peak mobility is found to scale with the square of the nanotube diameter and inversely with temperature. The maximum conductance, corrected for…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Xinjian Zhou , Ji-Yong Park , Shaoming Huang , Jie Liu , Paul L. McEuen

The electrical conductivity of metallic carbon nanotubes (CNTs) quickly saturates with respect to bias voltage due to scattering from a large population of optical phonons. Decay of these dominant scatterers in pristine CNTs is too slow to…

Materials Science · Physics 2017-04-05 Andrij Vasylenko , Jamie Wynn , Paulo Medeiros , Andrew J. Morris , Jeremy Sloan , David Quigley

We predict new forms of carbon consisting of one and two dimensional networks of interlinked single wall carbon nanotubes, some of which are energetically more stable than van der Waals packing of the nanotubes on a hexagonal lattice. These…

Materials Science · Physics 2009-10-31 T. Yildirim , O. Gulseren , C. Kilic , S. Ciraci

Using a scattering technique based on a parametrized linear combination of atomic orbitals Hamiltonian, we calculate the ballistic quantum conductance of multi-wall carbon nanotubes. We find that inter-wall interactions not only block some…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 S. Sanvito , Y. -K. Kwon , D. Tománek , C. J. Lambert

We investigate the nitrogen substitutional impurity in semiconducting zigzag and metallic armchair single-wall carbon nanotubes using ab initio density functional theory. At low concentrations (less than 1 atomic %), the defect state in a…

Materials Science · Physics 2007-05-23 Andriy H. Nevidomskyy , Gábor Csányi , Michael C. Payne

Addressing the optical properties of a single nanoparticle in the infrared is particularly challenging, thus alternative methods for characterizing the conductance spectrum of nanoparticles in this spectral range need to be developed. Here…

Mesoscale and Nanoscale Physics · Physics 2017-10-17 Hongyue Wang , Emmanuel Lhuillier , Qian Yu , Alexandre Zimmers , Benoit Dubertret , Christian Ulysse , Hervé Aubin

In-situ Raman experiments together with transport measurements have been carried out on carbon nanotubes as a function of gate voltage. In metallic tubes, a large increase in the Raman frequency of the $G^-$ band, accompanied by a…

Mesoscale and Nanoscale Physics · Physics 2009-09-29 Anindya Das , A. K. Sood , A. Govindaraj , A. Marco Saitta , Michele Lazzeri , Francesco Mauri , C. N. R Rao