Related papers: How to reduce the crack density in drying colloida…
-- A scientific hurdle in manufacturing solid films by drying colloidal layers is preventing them from fracturing. This paper examines how the drying rate of colloidal liquids influences the particle packing at the nanoscale in correlation…
Drying of colloidal dispersion and their consolidation into a particulate deposit is a common phenomenon. This process involves various physical processes such as diffusion of liquid molecules into the ambient atmosphere and advection of…
Drying a droplet of colloidal dispersion can result in complex pattern formation due to both development and deformation of a skin at the drop surface. The present study focus on the drying process of droplets of colloidal dispersions in a…
When colloidal suspensions dry, stresses build up and cracks often occur - a phenomenon undesirable for important industries such as paint and ceramics. We demonstrate an effective method which can completely eliminate cracking during…
Charged colloidal dispersions make up the basis of a broad range of industrial and commercial products, from paints to coatings and additives in cosmetics. During drying, an initially liquid dispersion of such particles is slowly…
We report an experimental study on the drying of silica colloidal dispersions. Here we focus on a surface instability occurring in a drying paste phase before crack formation which affects the final film quality. Observations at macroscopic…
During drying of colloidal suspensions, colloidal particles can form concentrated particle layers beneath the receding free surface. The drying rate can gradually decrease with the growth of the particle layers. We construct a model to…
Consolidation of colloidal gels results in enormous stresses that are usually released in the formation of undesirable cracks. The capacity of a gel network to crack during drying depends on the existence and significance of a pressure…
We report an experimental study of the crack pattern formed during the drying of a colloidal suspension. A horizontal fiber, which provides a one dimensional, boundary-free substrate, is coated by a film of micronic thickness. The geometry…
We study the stress developed during the drying of a colloidal drop of silica nanoparticles. In particular, we use the wrinkling instability of a thin floating sheet to measure the net stress applied by the deposit on the substrate and we…
Drying complex fluids is a common phenomenon where a liquid phase transforms into a dense or porous solid. This transformation involves several physical processes, such as the diffusion of liquid molecules into the surrounding atmosphere…
We investigate the initiation of cracks in vertically freestanding water-saturated colloidal pillars constructed using a direct-write technique. Paradoxically, the cracks form during drying at the free end, far from the substrate, where the…
When a colloidal gel dries through evaporation, cracks are usually formed, which often reveal underlying processes at work during desiccation. Desiccating colloid droplets of few hundred $\mu l$ size show interesting effects of pattern…
The fracture mechanics was widely employed to explain the crack propagation in the deposition produced by drying colloidal suspension. However, more complex than conventional fracture, those cracks periodically distribute and make up a…
Attractive colloidal particles can form a disordered elastic solid or gel when quenched into a two-phase region, if the volume fraction is sufficiently large. When the interactions are comparable to thermal energies the stress-bearing…
In simulations and experiments, we study the drying of films containing mixtures of large and small colloidal particles in water. During drying, the mixture stratifies into a layer of the larger particles at the bottom with a layer of the…
The invasion of air into porous systems in drying processes is often localized in soft materials, such as colloidal suspensions and granular pastes, and it typically develops in the form of cracks before ordinary drying begins. To…
Substrate wettability alteration induced control over crack formation process in thin colloidal films has been addressed in the present study. Colloidal nanosuspension (53nm, mean particle diameter) droplets have been subjected to natural…
Cohesive granular materials, like wet sand, retain their shape before yielding under stress. This solid-like behavior is associated with elasticity. As the loading increases, the material typically flows. However, cohesive materials can…
Drying suspensions often leave behind complex patterns of particulates, as might be seen in the coffee stains on a table. Here we consider the dynamics of periodic band or uniform solid film formation on a vertical plate suspended partially…