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Unlike the ferropnictide superconductors, which crystallize in a tetragonal crystal structure, binary FeAs forms in an orthorhombic crystal structure, where the local atomic environment resembles a highly distorted variant of the FeAs4…

Other Condensed Matter · Physics 2015-03-17 J. R. Jeffries , N. P. Butch , H. Cynn , S. R. Saha , K. Kirshenbaum , S. T. Weir , Y. K. Vohra , J. Paglione

Conventional magnetism occurs in systems which contain transition metals or rare earth ions with partially filled $d$ or $f$ shells. It is theoretically predicted that compounds of groups IA and IIA with IV and V, in some structural phases,…

Materials Science · Physics 2017-03-28 Seyed Mojtaba Rezaei Sani , Omid Khakpour

We report on doping dependencies of structural parameters and superconducting transition temperatures in the solid solution (Ba1-xKx)Fe2As2. As the main effect of doping on the crystal structure, we find linear decreasing As-Fe-As bond…

Superconductivity · Physics 2008-09-26 Marianne Rotter , Michael Pangerl , Marcus Tegel , Dirk Johrendt

The chromium arsenides BaCr2As2 and BaCrFeAs2 with ThCr2Si2 type structure (space group I4/mmm; also adopted by '122' iron arsenide superconductors) have been suggested as mother compounds for possible new superconductors. DFT-based…

Magnetization, susceptibility, specific heat, resistivity, neutron and x-ray diffraction have been used to characterize the properties of single crystalline CaFe2-xNixAs2 as a function of Ni doping for x varying from 0 to 0.1. The combined…

The measurements of the magnetic susceptibility, magnetization, electrical resistivity and magnetoresistance have been performed for the Fe intercalated compound Fe0.5TiS2. According to X-ray diffraction measurements the Fe0.5TiS2 compound…

The ternary-arsenide compound BaCo2As2 was previously proposed to be in proximity to a quantum-critical point where long-range ferromagnetic (FM) order is suppressed by quantum fluctuations. Here we report the effect of Ir substitution for…

Strongly Correlated Electrons · Physics 2020-07-02 Santanu Pakhira , N. S. Sangeetha , V. Smetana , A. -V. Mudring , D. C. Johnston

Resistivity, specific heat and magnetic susceptibility measurements performed on SrFe2As2 samples evidence a behavior very similar to that observed in LaFeAsO and BaFe2As2 with the difference that the formation of the SDW and the lattice…

Superconductivity · Physics 2008-09-06 C. Krellner , N. Caroca-Canales , A. Jesche , H. Rosner , A. Ormeci , C. Geibel

Here we report the successful synthesis of a spin- & charge-decoupled diluted magnetic semiconductor (Ca,Na)(Zn,Mn)2As2, crystallizing into the hexagonal CaAl2Si2 structure. The compound shows a ferromagnetic transition with a Curie…

We report the synthesis and characterization of bulk form diluted magnetic semiconductors Ba(Zn1-2xMnxCox)2As2 (0 <= x <= 0.15) with a crystal structure identical to that of 122-type Fe-based superconductors. Mn and Co co-doping into the…

Strongly Correlated Electrons · Physics 2014-03-18 Huiyuan Man , Cui Ding , Shengli Guo , Guoxiang Zhi , Xin Gong , Quan Wang , Hangdong Wang , Bin Chen , F. L. Ning

The compound BaMn2As2 with the tetragonal ThCr2Si2 structure is a local-moment antiferromagnetic insulator with a Neel temperature TN = 625 K and a large ordered moment mu = 3.9 mu_B/Mn. We demonstrate that this compound can be driven…

We examine the magnetic and electrical transport properties of the hexagonal EuIn2As2 compound, combining experimental and theoretical results. This compound is predicted to be an axion-insulator from an electronic point of view and an…

We have performed the first-principles electronic structure calculation for the novel superconductor Ca4Al2O6Fe2As2 which has the smallest a lattice parameter and the largest As height from the Fe plane among the Fe-As superconductors. We…

Superconductivity · Physics 2010-12-13 Takashi Miyake , Taichi Kosugi , Shoji Ishibashi , Kiyoyuki Terakura

Recent discoveries of intrinsic two-dimensional (2D) ferromagnetism in insulating/semiconducting van der Waals (vdW) crystals open up new possibilities for studying fundamental 2D magnetism and devices employing localized spins. However, a…

Among Transition-Metal Dichalcogenides, mono and few-layers thick VSe2 has gained much recent attention following claims of intrinsic room-temperature ferromagnetism in this system, which have nonetheless proved controversial. Here, we…

In this study we present a detailed ab initio analysis of the magnetic properties of VSe2 . Ab initio calculations in the so-called 1T structure yield a ferromagnetic phase as most stable, with a magnetic moment of about 0.6 {\mu} B /V.…

Materials Science · Physics 2018-09-20 Adolfo O. Fumega , Victor Pardo

Two-dimensional materials and their heterostructures have opened up new possibilities for magnetism at the nanoscale. In this study, we utilize first-principles simulations to investigate the structural, electronic, and magnetic properties…

Materials Science · Physics 2022-10-11 Diem Thi-Xuan Dang , Ranjan Kumar Barik , Manh-Huong Phan , Lilia M. Woods

Due to the similarity to BaFe2As2 and SrFe2As2 the RFe2Si2 (R=La, Y and Lu) system has been proposed as a potential candidate for a new superconducting family containing Fe-Si layers as a structural unit. Various R(Fe1-xMx)2Si2 M=Ni, Mn and…

Superconductivity · Physics 2015-06-17 I. Felner , B. Lv , C. W. Chu

We report on the hitherto unknown compound CeZn2-dGe2 (d approx 0.41). We find this compound to crystallize in a defect version of the well-known CaBe2Ge2 structure type. The phase forms in a Zn/In flux and with Zn-deficiency on one of its…

Strongly Correlated Electrons · Physics 2022-03-14 Robin Lefèvre , Fabian O von Rohr

Fermi-surface topology governs the relationship between magnetism and superconductivity in iron-based materials. Using low-temperature transport, angle-resolved photoemission, and x-ray diffraction we show unambiguous evidence of large…

Strongly Correlated Electrons · Physics 2014-05-09 K. Gofryk , B. Saparov , T. Durakiewicz , A. Chikina , S. Danzenbächer , D. V. Vyalikh , M. J. Graf , A. S. Sefat