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We report the high-pressure synthesis (6 GPa, 1200 $^{\circ}$C) and ambient pressure characterization of hexagonal HP-BaCoO$_3$. The material (with the 2H crystal structure) has a short intrachain Co-Co distance of about 2.07…

Materials Science · Physics 2023-12-27 Haozhe Wang , Xianghan Xu , Danrui Ni , David Walker , Jie Li , Robert J. Cava , Weiwei Xie

BaFe2Se3 is a potential superconductor material exhibiting transition at 11 K and ambient pressure. Here we extended the structural and performed electrical resistivity measurements on this compound up to 51 GPa and 20 GPa, respectively, in…

We present an ab initio study of the BFCO solid solution formed by multiferroics BiFeO3 (BFO) and BiCoO3 (BCO). We find that BFCO presents a strongly discontinuous morphotropic transition between BFO-like and BCO-like ferroelectric phases.…

Materials Science · Physics 2011-08-23 Oswaldo Diéguez , Jorge Íñiguez

The prototypical antiferroelectric PbZrO$_3$ has several unsettled questions, such as the nature of the antiferroelectric transition, possible intermediate phase and the microscopic origin of the Pbam ground state. Using first principles,…

Materials Science · Physics 2019-07-24 Bin Xu , Olle Hellman , L. Bellaiche

Understanding the polarization switching mechanisms at play in ferroelectric materials is crucial for their exploitation in electronic devices. The conventional centrosymmetric reference structure-based mechanism which accounts for…

Multiferroic BaMnF$_4$ powder were prepared by hydrothermal method. Hysteretic field dependent magnetization curve at 5 K confirms the weak ferromagnetism aroused from the canted antiferromagnetic spins by magnetoelectric coupling. The…

Materials Science · Physics 2015-12-18 Shuang Zhou , Ji Wang , Xiaofeng Chang , Shuangbao Wang , Bin Qian , Zhida Han , Qingyu Xu , Jun Du , Peng Wang , Shuai Dong

We used first-principles calculations to investigate the existence and origin of the ferroelectric in- stability in the ABF3 fluoro-perovskites. We find that many fluoro-perovskites have a ferroelectric instability in their high symmetry…

Materials Science · Physics 2014-09-03 A. C. Garcia-Castro , N. A. Spaldin , A. H. Romero , E. Bousquet

Magnetic structure evolution of multiferroic hexagonal $YMn_{1-x}Fe_{x}O_{3}$ (${x} = 0, 0.05,$ and $0.1$) has been studied by carrying out detailed temperature-dependent neutron diffraction at zero- and 5T-fields. Thermodynamic data…

Materials Science · Physics 2017-07-26 Sonu Namdeo , S. S. S. Rao , S. D. Kaushik , V. Siruguri , A. M. Awasthi

Local structural measurements have been performed on hexagonal HoMnO3 in order to ascertain the specific changes in bond distances which accompany magnetic ordering transitions. The transition from paramagnetic to the antiferromagetic…

Strongly Correlated Electrons · Physics 2015-05-14 T. A. Tyson , T. Wu , K. H. Ahn , S. Kim , S. -W. Cheong

We report the magnetic field dependent dc magnetization and the pressure-dependent (pmax ~ 16 kbar) ac susceptibilities Xp(T) on both powder and bulk multiferroic BiMnO3 samples, synthesized in different batches under high pressure. A clear…

Strongly Correlated Electrons · Physics 2010-03-11 C. C. Chou , S. Taran , J. L. Her , C. P. Sun , C. L. Huang , H. Sakurai , A. A. Belik , E. Takayama-Muromachi , H. D. Yang

The ferroelectric to paraelectric phase transition of multiferroic CaMnTi$_2$O$_6$ has been investigated at high pressures and ambient temperature by second harmonic generation (SHG), Raman spectroscopy, and powder and single-crystal x-ray…

Atomically engineered oxide heterostructures provide a fertile ground for creating novel states. For example, a two-dimensional electron gas at the interface between two oxide insulators, giant thermoelectric Seebeck coefficient, emergent…

Magnetic and dielectric properties of the hexagonal triangular lattice antiferromagnet 2H-AgFeO2 have been studied by neutron diffraction, magnetic susceptibility, specific heat, pyroelectric current, and dielectric constant measurements.…

Strongly Correlated Electrons · Physics 2019-03-05 Noriki Terada , Dmitry D. Khalyavin , Pascal Manuel , Yoshihiro Tsujimoto , Alexei A. Belik

In this work, we report the effects of calcination temperature on structural, dielectric, semiconducting and optical properties of YFeO3 nanoparticles prepared by a high energy ball milling process. The structural analysis of the X-ray…

Materials Science · Physics 2019-10-08 Chandra Bhal Singh , Dinesh Kumar , Narendra Kumar Verma , Akhilesh Kumar Singh

Ferroelectric films usually have phase states and physical properties very different from those of bulk ferroelectrics. Here we propose free-standing ferroelectric-elastic multilayers as a bridge between these two material systems. Using a…

Materials Science · Physics 2011-10-18 S. Prokhorenko , N. A. Pertsev

Multiferroic oxides, such as BiFeO3, have garnered significant attention due to their coupled ferroelectric, magnetic, and elastic properties, offering exciting opportunities for multifunctional device applications. Controlling phase…

Materials Science · Physics 2025-02-19 Fei Sun , Chao Chen , Deyang Chen , Minghui Qin , Xubing Lu , Xingsen Gao , Christopher T Nelson , Jun-Ming Liu

To understand the collinear-magnetism-driven ferroelectricity in multiferroic Ca3CoMnO6 compound, we have established an elastic diatomic Ising spin-chain model with axial-next-nearest-neighbor interaction to describe its magnetoelectric…

Statistical Mechanics · Physics 2016-03-23 Yan Qi , Qi Yang , Nai-sen Yu , An Du

Controlling the ferroelectricity and magnetism in multiferroic materials has been an important research topic. We report the formation of a highly polarized state in multiferroic DyMnO3 single crystals which develops well above the magnetic…

Materials Science · Physics 2014-09-05 Tao Zou , Zhiling Dun , Huibo Cao , Mengze Zhu , Daniel Coulter , Haidong Zhou , Xianglin Ke

Ba(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (BFN) ceramics are considered to be promising for technological applications owing to their high dielectric constant over a wide range of temperatures. However, there exists considerable discrepancy over the…

Recent studies have reported the existence of an epitaxially-stabilized tetragonal-like ('T-like') monoclinic phase in BiFeO3 thin-films with high levels of compressive strain. While their structural and ferroelectric properties are…