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Iridates abound with interesting magnetic behaviours because of their strong spin-orbit coupling. Sr$_3$NiIrO$_6$ brings together the spin-orbital entanglement of the Ir$^{4+}$ ion with a 3$d$ Ni cation and a one-dimensional crystal…

Materials Science · Physics 2018-10-19 Turan Birol , Kristjan Haule , David Vanderbilt

It is well known that the kinetic exchange interaction between single-occupied magnetic orbitals (s-s) is always antiferromagnetic, while between single- and double-occupied orbitals (s-d) is always ferromagnetic and much weaker. Here we…

Materials Science · Physics 2016-04-22 Naoya Iwahara , Liviu F. Chibotaru

Pronounced anisotropy of magnetic properties and complex magnetic order of a new oxi-halide compound Co7(TeO3)4Br6 has been investigated by powder and single crystal neutron diffraction, magnetization and ac susceptibility techniques.…

Materials Science · Physics 2013-05-29 M. Prester , I. Zivkovic , O. Zaharko , D. Pajic , P. Tregenna-Piggott , H. Berger

Evidence for multiple magnetic transitions and unconventional spin exchange interactions in the ilmenite insulator MnTiO3 is provided via neutron scattering. On cooling, while G-type antiferromagnetic (AFM) order sets in first at 63 K with…

Strongly Correlated Electrons · Physics 2026-03-09 Srimal Rathnayaka , Luke Daemen , Despina Louca

Strong Coulomb repulsion and spin-orbit coupling are known to give rise to exotic physical phenomena in transition metal oxides. Initial attempts to investigate systems where both of these fundamental interactions are comparably strong,…

The copper fluoride Cu$_2$F$_5$ is a compound with 2D-magnetic exchange interactions between the Cu ions in the $S=1$ and $S=\frac{1}{2}$ spin-states. Using ab-initio calculations, we predict that the existence of 5% vacancies in the…

Strongly Correlated Electrons · Physics 2023-03-28 Dmitry M. Korotin , Dmitry Y. Novoselov , Vladimir I. Anisimov

The phenomena of exchange anisotropy is well known in terms of static magnetization properties such as enhanced coercivity and magnetization loop shifts. These effects are primarily associated with effective anisotropies introduced into the…

Materials Science · Physics 2007-05-23 R. L. Stamps , K. Usadel

The ability to tune exchange (magnetic) interactions between 3d transition metals in perovskite structures has proven to be a powerful route to discovery of novel properties. Here we demonstrate that the introduction of 3d-5d exchange…

Strongly Correlated Electrons · Physics 2015-04-13 L. S. I. Veiga , G. Fabbris , M. van Veenendaal , N. M. Souza-Neto , H. L. Feng , K. Yamaura , D. Haskel

Using density functional theory plus Hubbard-U (DFT+U) approach, we find that quasi one-dementation(1D) 3d transition metal(TM) zigzag nanowire can be constructed by TM adsorbed on the surface of graphyne sheet. The results show that the TM…

Materials Science · Physics 2013-05-22 Junjie He , Pan Zhou , N. Jiao , S. Y. Ma , K. W. Zhang , R. Z. Wang , L. Z. Sun

Using a combination of linear response theory and constrained orbital hybridization approach, we study the mechanism of magnetic exchange interaction of iron-based superconductor. We reproduce the observed highly anisotropic exchange…

Superconductivity · Physics 2015-06-05 Xiangang Wan , Jinming Dong , Xi Dai

We report our investigation of the electronic and magnetic excitations of Sr$_3$NiIrO$_6$ by resonant inelastic x-ray scattering at the Ir L$_3$ edge. The intra-$t_{2g}$ electronic transitions are analyzed using an atomic model, including…

Strongly Correlated Electrons · Physics 2016-06-08 E. Lefrançois , A. -M. Pradipto , M. Moretti Sala , L. C. Chapon , V. Simonet , S. Picozzi , P. Lejay , S. Petit , R. Ballou

Anisotropic magnetic properties of a layered kagome-like system Cu3Bi(SeO3)2O2Br have been studied by bulk magnetization and magnetic susceptibility measurements as well as powder and single-crystal neutron diffraction. At T_N = 27.4 K the…

Strongly Correlated Electrons · Physics 2012-10-16 M. Pregelj , O. Zaharko , A. Günther , A. Loidl , V. Tsurkan , S. Guerrero

The realization of unconventional quantum phases in frustrated and spin-orbit coupled materials remains at the forefront of quantum materials research. Here we report the synthesis and discovery of NiIrO3, the first honeycomb iridate with…

Magnetic systems exhibiting exchange bias effect are being considered as materials for applications in data storage devices, sensors and biomedicine. As the size of new mag- netic devices is being continuously reduced, the influence of…

The magnetic anisotropy af a rectangular Cu-O-Cu bond is investigated in second order of the spin-orbit interaction. Such a bond is characteristic for cuprates having edge sharing CuO_2 chains, and exists also in the Cu_3O_4 plane or in…

Strongly Correlated Electrons · Physics 2009-10-31 V. Yu. Yushankhai , R. Hayn

Exchange bias effect is an important attribute in several device applications. Traditionally, it is discussed as a form of exchange anisotropy at the interface between the ferromagnetic/antiferromagnetic layers of two distinct systems. We…

Strongly Correlated Electrons · Physics 2015-05-13 Prasanna D. Kulkarni , S. Venkatesh , A. Thamizhavel , V. C. Rakhecha , S. Ramakrishnan , A. K. Grover

Ac and dc magnetization and heat-capacity (C) measurements performed on the pseudo-one-dimensional compound Sr$_3$CuIrO$_6$ reveal a competition between antiferromagnetic (AF) and ferromagnetic (F) exchange couplings, as evidenced by…

Strongly Correlated Electrons · Physics 2009-11-07 Asad Niazi , E. V. Sampathkumaran , P. L. Paulose , D. Eckert , A. Handstein , K. -H. Müller

Magnetic anisotropy and magnetic exchange interactions are crucial parameters that characterize the hybrid metal-organic interface, key component of an organic spintronic device. We show that the incorporation of 4$f$ RE atoms to hybrid…

In 5d transition metal oxides, novel properties arise from the interplay of electron correlations and spin--orbit interactions. Na4IrO4, where 5d transition-metal Ir atom occupies the center of the square-planar coordination environment, is…

Materials Science · Physics 2017-12-01 Di Wang , Feng Tang , Yongping Du , Xiangang Wan

The origin of magnetic anisotropy in magnetic compounds is a longstanding issue in solid state physics and nonmagnetic ligand ions are considered to contribute little to magnetic anisotropy. Here, we introduce the concept of ligand driven…

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