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Ferroelectric solid solutions usually exhibit giant dielectric response and high piezoelectricity in the vicinity of the morphotropic phase boundary (MPB), where the structural phase transitions between the rhombohedral and the tetragonal…

Materials Science · Physics 2024-07-02 Yubai Shi , Yifan Shan , Hongyu Wu , Zhicheng Zhong , Ri He , Run-Wei Li

The structure and properties of the ferromagnet Tb_{1-x}Dy_xFe_2 (Terfenol-D) are explored through the morphotropic phase boundary (MPB) separating ferroic phases of differing symmetry. Our synchrotron data support a first order structural…

Many ferroelectric solid solutions exhibit enhanced electro-mechanical properties at the morphotropic boundary separating two phases with different orientations of polarization. The mechanism of properties enhancement is associated with…

Materials Science · Physics 2015-05-19 Dragan Damjanovic

The symmetric studies on the structure-property relationship of the unpoled and poled states of 0.67BiFeO3-0.33BaTiO3 (0.67BF-0.33BT) were conducted to understand the origin of the morphotropic phase boundary (MPB) in BF-BT. A typical…

Materials Science · Physics 2020-03-24 Yongxing Wei , Jiahao Shen , Chenxing Bai , Changqing Jin , Weitong Zhu , Ye Tian , Gang Xu

Morphotropic phase boundaries (MPBs) show substantial piezoelectric and dielectric responses, which have practical applications. The predicted existence of MPB in HfO2-ZrO2 solid solution thin film has provided a new way to increase the…

Materials Science · Physics 2021-07-28 Alireza Kashir , Hyunsang Hwang

Relaxor ferroelectrics have been a focus of intense attention due to their anomalous dielectric characteristics, diffuse phase transitions, and strong piezoelectricity. Understanding the structure and dynamics of relaxors has been one of…

Materials Science · Physics 2013-12-09 Hiroyuki Takenaka , Ilya Grinberg , Andrew M. Rappe

The realization of a spontaneous macroscopic ferroelectric order in fluids of anisotropic mesogens is a topic of both fundamental and technological interest. Recently, we demonstrated that a system of dipolar achiral disklike ellipsoids can…

Soft Condensed Matter · Physics 2016-01-06 Tushar Kanti Bose , Jayashree Saha

We show results of Monte Carlo simulations of an array of monodispersed magnetic monodomain particles, in a square lattice with dipolar interactions and perpendicular uniaxial anisotropy. We first show the equilibrium phase diagram of the…

Materials Science · Physics 2008-10-17 Daniel A Stariolo , Orlando V. Billoni

We investigate the microstructural evolution in a ferroelectric to antiferroelectric phase transition at the morphotropic phase boundary in the Bi(1-x)SmxFeO3 system. Continuous Sm3+ substitution on the A-site induces short-range…

We examine a simple model for Pb(In$_{1/2}$Nb$_{1/2}$)O$_3$ (PIN), which includes both long-range dipole-dipole interaction and random local anisotropy. A improved algorithm optimized for long-range interaction has been applied for…

Disordered Systems and Neural Networks · Physics 2010-02-11 Yusuke Tomita , Takeo Kato , Kazuma Hirota

Recently, based on the phase-field modeling, it was predicted that Hf1-xZrxO2 (HZO) exhibits the morphotropic phase boundary (MPB) in its compositional phase diagram. Here, we investigate the effect of structural changes between tetragonal…

Materials Science · Physics 2021-05-05 Alireza Kashir , Hyunsang Hwang

In this work, we address the issue of peaking of piezoelectric response at a particular composition in the morphotropic phase boundary (MPB) region of (Pb0.940Sr0.06)(ZrxTi1-x)O3 (PSZT) piezoelectric ceramics. We present results of…

A mechanically coupled phase-field model is proposed for the first time to simulate the peculiar behavior of relaxor ferroelectrics. Based on the random field theory for relaxors, local random fields are introduced to characterize the…

Materials Science · Physics 2016-10-23 Shuai Wang , Min Yi , Bai-Xiang Xu

The structural evolution of the strain-driven morphotropic phase boundary (MPB) in BiFeO3 films has been investigated using synchrotron x-ray diffractometry in conjunction with scanning probe microscopy. Our results demonstrate the…

Relaxor ferroelectrics are applied in electronic devices such as actuators and sonars. Morphotrophic phase boundaries (MPBs) with monoclinic structures are known for their high piezoelectricity and electromechanical coupling factors in…

We discuss theoretically a frustrated Heisenberg antiferromagnet in magnetic field close to the saturation one. It is demonstrated that a small biaxial anisotropy and/or the magnetic dipolar interaction produce a delicate balance between…

Strongly Correlated Electrons · Physics 2021-02-24 O. I. Utesov , A. V. Syromyatnikov

The radiofrequency dielectric response of the lead-free Ba(Zr$_{0.5}$Ti$_{0.5}$)O$_3$ relaxor ferroelectric is simulated using a coarse-grained Hamiltonian. This concept, taken from Real-Space Renormalization Group theories, allows…

Materials Science · Physics 2016-09-28 Gregory Geneste , L. Bellaiche , Jean-Michel Kiat

Relaxor ferroelectrics are complex oxide materials which are rather unique to study the effects of compositional disorder on phase transitions. Here, we study the effects of quenched cubic random electric fields on the lattice instabilities…

Materials Science · Physics 2017-06-14 J. R. Arce-Gamboa , G. G. Guzmán-Verri

Monte Carlo simulations based on a first-principles-derived Hamiltonian are conducted to study the properties of PZT alloys compositionally modulated along the [100] pseudocubic direction near the morphotropic phase boundary (MPB). It is…

Materials Science · Physics 2009-11-10 Ningdong Huang , Zhirong Liu , Zhongqing Wu , Jian Wu , Wenhui Duan , Binglin Gu , Xiaowen Zhang

Freestanding ferroelectric oxide membranes emerge as a promising platform for exploring the interplay between topological polar ordering and dipolar interactions that are continuously tunable by strain. Our investigations combining density…

Materials Science · Physics 2024-07-31 Yihao Hu , Jiyuan Yang , Shi Liu
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