Related papers: Determination of photodissociation and radiative a…
When the atoms of a dimer remain most of the time very far apart, in so-called long-range molecular states, their mutual interaction is ruled by plain atomic properties. The high-resolution spectroscopic study of some molecular excited…
The reported ''dissociation times'' for the Br$_{2}$ C ($^{1}\Pi_{u}$ $1_{u}$) state by various measurement methods differ widely across the literature (30 to 340 fs). We consider this issue by investigating attosecond extreme ultraviolet…
Photoionization and recombination cross sections and rate coefficients are calculated for Li-like Fe XXIV and He-like Fe XXV using the Breit-Pauli R-matrix (BPRM) method. A complete set of total and level-specific parameters is obtained to…
The charge transfer in low energy (0.25 to 150 eV/amu) H($nl$) + He$^+(1s)$ collisions is investigated using a quasi-molecular approach for the $n=2,3$ as well as the first two $n=4$ singlet states. The diabatic potential energy curves of…
Cross sections are presented for dissociative recombination and electron-impact vibrational excitation of the ArH+ molecular ion at electron energies appropriate for the interstellar environment. The R-matrix method is employed to determine…
We demonstrate that a near-dissociation photoassociation resonance can be used to create a deeply bound molecular sample of ultracold NaCs. To probe the resulting vibrational distribution of the sample, we use a new technique that can be…
The breakup cross sections in the reaction $^6$He+$^{12}$C are calculated at about 40 MeV/nucleon using the high-energy approximation (HEA) and with the help of microscopic optical potentials (OP) of interaction with the target nucleus…
The photoionization spectrum of an atom in a magnetic field is calculated by combining R-matrix propagation with local adiabatic basis expansions. This approach considerably increases the speed and the energy range over which calculations…
The total single-photon ionisation cross section was calculated for helium atoms in their ground state. Using a full configuration-interaction approach the photoionisation cross section was extracted from the complex-scaled resolvent. In…
The latest molecular data - potential energy curves and Rydberg$/$valence interactions - characterizing the super-excited electronic states of CO are reviewed, in order to provide inputs for the study of their fragmentation dynamics.…
The global potential energy surfaces of the first six singlet electronic states of CO$_2$, 1---3$^1/!A'$ and 1---3$^1/!A"$ are constructed using high level ab initio calculations. In linear molecule, they correspond to…
In this work we discuss the rotational structure of Rydberg molecules. We calculate the complete wave function in a laboratory fixed frame and derive the transition matrix elements for the pho- toassociation of free ground state atoms. We…
Various differential cross sections of high-energy photon splitting in the electric fields of heavy atoms are calculated exactly in the parameter \al. The consideration is based on the quasiclassical approach applicable for small angles…
Photon initiated chemistry, \textit{i.e.} the interaction of light with chemical species, is a key factor in the evolution of the atmosphere of exoplanets. For planets orbiting stars in UV-rich environments, photodissociation induced by…
Adiabatic potential energy curves of the $^1\Sigma^+$ and $^1\Pi$ states of the LiH molecule have been calculated. They correlate asymptotically to atomic states, like 2s+1s, 2p+1s, 3s+1s, 3p+1s, 3d+1s, 4s+1s, 4p+1s and 4d+1s. Very good…
We present spectroscopic measurements of seven vibrational levels $v=29-35$ of the $A(1^1\Sigma_u^+)$ excited state of Li$_2$ molecules by the photoassociation of a degenerate Fermi gas of $^6$Li atoms. The absolute uncertainty of our…
We have observed short-range photoassociation of LiRb to the two lowest vibrational states of the $d\,^3\Pi$ potential. These $d\,^3\Pi$ molecules then spontaneously decay to vibrational levels of the $a^3\,\Sigma^+$ state with generation…
Resonant vibrational and rotation-vibration excitation cross sections for electron-CO scattering are calculated in the 0-10 eV energy range for all 81 vibrational states of CO, assuming that the excitation occur via the 2{\Pi} shape…
We report the first observation of photoassociation to the 2(1)Sigma(g)(+) state of 85Rb2 . We have observed two vibrational levels (v'=98, 99) below the 5s1/2+5p1/2 atomic limit and eleven vibrational levels (v'=102-112) above it. The…
It has been known that electronic conical intersections in a molecular system can also be created by laser light even in diatomics. The direct consequence of these light-induced degeneracies is the appearance of a strong mixing between the…