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We present a detailed first-principles DFT study of the equation of state (EOS), energy-optimized geometries, phase stabilities and electronic properties of bulk crystalline Cu3N, CuN and CuN2 in a set of twenty different structural phases.…

Materials Science · Physics 2018-05-18 Mohammed S. H. Suleiman , Mahlaga P. Molepo , Daniel P. Joubert

The atomic and electronic structures of Pd3N, PdN and PdN2 were investigated using ab initio density-functional theory (DFT). We studied cohesive energy vs. volume equation of states (EOS) for a set of reported and hypothetical structures.…

Materials Science · Physics 2013-10-11 Mohammed S. H. Suleiman , Daniel P. Joubert

In the present work, the atomic and the electronic structures of Au3N, AuN and AuN2 are investigated using first-principles density-functional theory (DFT). We studied cohesive energy vs. volume data for a wide range of possible structures…

Materials Science · Physics 2015-11-24 Mohammed S. H. Suleiman , Daniel P. Joubert

We present a first-principles investigation of structural, electronic and optical properties of bulk crystalline Ag3N, AgN and AgN2 based on density functional theory (DFT) and many-body perturbation theory. The equation of state (EOS),…

Materials Science · Physics 2015-09-15 Mohammed S. H. Suleiman , Daniel P. Joubert

The thermodynamic stabilities of various phases of the nitrides of the platinum metal elements are systematically studied using density functional theory. It is shown that for the nitrides of Rh, Pd, Ir and Pt two new crystal structures, in…

Materials Science · Physics 2010-09-03 Daniel Åberg , Babak Sadigh , Jonathan Crowhurst , Alexander F. Goncharov

The phonon spectrum of cubic BaThO$_3$ with the perovskite structure is calculated from first principles within the density functional theory. The analysis of unstable modes in the phonon spectrum enables to determine the symmetry of all…

Materials Science · Physics 2014-05-13 Alexander I. Lebedev

The full potential linearized augmented plane wave (FLAPW) method was used to study the crystal structure and electronic structure properties of PbFe0.5Nb0.5O3 (PFN). The optimized crystal structure, density of states, band structure and…

Materials Science · Physics 2009-11-10 Yuan Xu Wang , C L Wang , M L Zhao , J L Zhang

Structural and optoelectronic properties of {\alpha}, \{beta}, {\gamma} phases of calcium titanate are studied with the implementation of first-principles quantum-chemical calculations in the framework of DFT. When optimizing the geometry,…

Materials Science · Physics 2022-11-01 D. D. Nematov , A. S. Burhonzoda , F. Shokir

We present a first-principles investigation of structural and elastic properties of experimentally observed phases of bulk SrRuO$_3$ - namely orthorhombic, tetragonal, and cubic - by applying density functional theory (DFT) approximations.…

Materials Science · Physics 2016-10-11 Š. Masys , V. Jonauskas

A systematic search for multicomponent crystal structures is carried out for five different ternary systems of nuclei in a polarizable background of electrons, representative of accreted neutron star crusts and some white dwarfs. Candidate…

High Energy Astrophysical Phenomena · Physics 2016-03-09 T. A. Engstrom , N. C. Yoder , V. H. Crespi

The adsorption profiles and electronic structures of Pt$_n$ (n = 1--4) clusters on stoichiometric, reduced and reconstructed rutile TiO$_2$(110) surfaces were systematically studied using on site d-d Coulomb interaction corrected hybrid…

Strongly Correlated Electrons · Physics 2011-01-06 Veysel Celik , Hatice Unal , Ersen Mete , Sinasi Ellialtioglu

We perform density functional theory calculations using Gaussian atomic-orbital methods within the generalized gradient approximation for the exchange and correlation to study the interactions in the bare and hydrogenated platinum clusters.…

Atomic and Molecular Clusters · Physics 2009-11-11 Ali Sebetci

Electronic-structure theory is a strong pillar of materials science. Many different computer codes that employ different approaches are used by the community to solve various scientific problems. Still, the precision of different packages…

The work presents the electronic structure, spin state and optical properties of TM-dinuclear molecules (TM = Cr, Mn, Fe, Co, and Ni) which was modelled according to the recently reported Pt$^{II}$-dinuclear complex…

Materials Science · Physics 2019-12-19 Indukuru Ramesh Reddy , Kartick Tarafder

The structure, dynamics and stability of Fe-Pt nanoparticles have been investigated using DFT-based techniques: total energy calculations and DFT molecular dynamics. The investigated systems included multi-shell and disordered nanoparticles…

Mesoscale and Nanoscale Physics · Physics 2025-01-28 Paweł T. Jochym , Jan Łażewski , Małgorzata Sternik , Przemysław Piekarz

The theoretical formalism of the local density approximation (LDA) to density functional theory (DFT) has been used to study the electronic and geometric structures of SimCn (1<=m, n<=4;n<=m) clusters. An all electron 6-311++G** basis set…

Atomic and Molecular Clusters · Physics 2007-05-23 Prachi Pradhan , Asok K. Ray

The actinide elemental metals are scare, often toxic and radio active, causing challenges for both experiments and theory while offering fascinating physics. For practical purposes they are the prevalent building blocks for materials where…

Materials Science · Physics 2016-08-26 P. Soderlind

We study the structural and electronic properties of phase III of solid hydrogen using accurate many-electron theories and compare to state-of-the-art experimental findings. The atomic structures of phase III modelled by C2/c-24 crystals…

Materials Science · Physics 2021-02-24 Ke Liao , Tong Shen , Xin-Zheng Li , Ali Alavi , Andreas Grüneis

By investigating the crystalline structure of ground-state orthorhombic SrRuO$_3$, we present a benchmark study of some of the most popular density functional theory (DFT) approaches from the local density approximation (LDA),…

Materials Science · Physics 2016-08-03 Š. Masys , V. Jonauskas

A Gaussian approximation machine learning interatomic potential for platinum is presented. It has been trained on DFT data computed for bulk, surfaces and nanostructured platinum, in particular nanoparticles. Across the range of tested…

Materials Science · Physics 2023-04-06 Jan Kloppenburg , Livia B. Pártay , Hannes Jónsson , Miguel A. Caro
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