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In proposals for quantum computers using arrays of trapped ultracold polar molecules as qubits, a strong external field with appreciable gradient is imposed in order to prevent quenching of the dipole moments by rotation and to distinguish…

Quantum Physics · Physics 2015-05-27 Qi Wei , Sabre Kais , Bretislav Friedrich , Dudley Herschbach

We propose high-spin $\Sigma$-state polar molecules assembled from ultracold atoms to probe charge-parity violating physics beyond the Standard Model. We identify YbCr as a prime candidate to search for the electric dipole moment of the…

Quantum Gases · Physics 2026-03-16 Alessio Ciamei , Adam Koza , Marcin Gronowski , Michał Tomza

Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the…

We have studied the effects of loading $^{87}$Rb into a far off resonant trap (FORT) in the presence of an ultracold cloud of $^{85}$Rb. The presence of the $^{85}$Rb resulted in a marked decrease of the $^{87}$Rb load rate. This decrease…

Atomic Physics · Physics 2009-07-20 Anthony R. Gorges , Mathew S. Hamilton , Jacob L. Roberts

We consider collisions of electric and magnetic polar molecules, taking the OH radical as an example, subject to combined electric and magnetic static fields. We show that the relative orientation of the fields has an important effect on…

Atomic Physics · Physics 2013-07-16 Goulven Quéméner , John L. Bohn

We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…

Quantum Physics · Physics 2024-09-24 Felipe Isaule , Robert Bennett , Jörg B. Götte

We demonstrate coherent control of both the rotational and hyperfine state of ultracold, chemically stable $^{87}$Rb$^{133}$Cs molecules with external microwave fields. We create a sample of ~2000 molecules in the lowest hyperfine level of…

Quantum Gases · Physics 2016-11-02 Philip D. Gregory , Jesus Aldegunde , Jeremy M. Hutson , Simon L. Cornish

We show that a ferro-electric quantum phase transition can be driven by the dipolar interaction of polar molecules in the presence a micro-wave field. The obtained ferro-electricity crucially depends on the harmonic confinement potential,…

Quantum Gases · Physics 2015-05-13 Chien-Hung Lin , Yi-Ting Hsu , Hao Li , Daw-Wei Wang

We explore the uses of ultracold molecules as a platform for future experiments in the field of quantum simulation, focusing on two molecular species, $^{40}$Ca$^{19}$F and $^{87}$Rb$^{133}$Cs. We report the development of coherent quantum…

The collisions between linear polar molecules, trapped in a microwave field with circular polarization, are theoretically analyzed. The microwave trap suggested by DeMille \cite{DeMille} seems to be rather advantageous in comparison with…

Atomic Physics · Physics 2015-05-13 Alexander V. Avdeenkov

We investigate the effect of far-off-resonant trapping light on ultracold bosonic RbCs molecules. We use kHz-precision microwave spectroscopy to measure the differential AC Stark shifts between the ground and first excited rotational levels…

The observation of significant dipolar effects in gases of ultra-cold polar molecules typically demands a strong external electric field to polarize the molecules. We show that even in the absence of a significant polarization, dipolar…

Quantum Gases · Physics 2011-12-20 A. Pikovski , M. Klawunn , A. Recati , L. Santos

We investigate theoretically the interaction of polar molecules with optical lattices and microwave fields. We demonstrate the existence of frequency windows in the optical domain where the complex internal structure of the molecule does…

Quantum Physics · Physics 2009-11-13 S. Kotochigova , E. Tiesinga

We present expressions demonstrating that collisional decoherence of ultracold atoms or molecules in a coherent superposition of non-degenerate quantum states is suppressed when both the real and imaginary parts of the scattering lengths…

Quantum Physics · Physics 2012-07-26 Jie Cui , Roman V. Krems

We probe resonant dipolar interactions between ultracold $^{40}$K$^{87}$Rb molecules and Rydberg $^{87}$Rb atoms in an optically trapped ensemble. Through state-selective ionization detection of the KRb molecules, we observe resonant energy…

Atomic Physics · Physics 2025-04-10 Lingbang Zhu , Jeshurun Luke , Roy Shaham , Yi-Xiang Liu , Kang-Kuen Ni

Ultracold ground state dipolar 40K-87Rb molecules have recently been produced in a loose harmonic trap by employing a magnetic field sweep across a Feshbach resonance followed by stimulated Raman adiabatic passage [K.-K. Ni et al., Science…

Progress on researches in the field of molecules at cold and ultracold temperatures is reported in this review. It covers extensively the experimental methods to produce, detect and characterize cold and ultracold molecules including…

Quantum Physics · Physics 2015-05-13 Olivier Dulieu , Carlo Gabbanini

Full control of molecular interactions, including reactive losses, would open new frontiers in quantum science. Here, we demonstrate extreme tunability of chemical reaction rates by using an external electric field to shift excited…

Ultracold atoms confined in a dipole trap are submitted to a potential whose depth is proportional to the real part of their dynamic dipole polarizability. The atoms also experience photon scattering whose rate is proportional to the…

Atomic Physics · Physics 2017-04-11 Maxence Lepers , Jean-François Wyart , Olivier Dulieu , --

Measurements of interactions between cold molecules and ultracold atoms can allow for a detailed understanding of fundamental collision processes. These measurements can be done using various experimental geometries including where both…

Atomic Physics · Physics 2020-03-25 N. J. Fitch , L. P. Parazzoli , H. J. Lewandowski