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Materials with high dielectric constant are in great demand for the miniaturization of electronic devices. More specifically, high dielectric constant polymer-ceramic composites are useful for embedded capacitor applications. A composite…

Materials Science · Physics 2013-01-18 P. Thomas , R. S. Ernest Ravindran , K. B. R. Varma

The Poly(vinylidene fluoride)/CaCu3Ti4O12 (CCTO) nanocrystal composite films (85nm) with relatively high dielectric permittivity (90 at 100Hz) were prepared by the solution casting followed by spin coating technique. The structural, the…

Materials Science · Physics 2013-01-18 P. Thomas , S. Satapathy , K. Dwarakanath , K. B. R. Varma

Poly(Methyl Methacrylate) (PMMA) and CaCu3Ti4O12 (CCTO) composites were fabricated via melt mixing followed by hot pressing technique. These were characterized using X-ray diffraction (XRD), thermo gravimetric (TGA), Thermo Mechanical…

Materials Science · Physics 2013-01-21 P. Thomas , R. S. Ernest Ravindran , K. B. R. Varma

Composites comprising Poly(Methyl Methacrylate) (PMMA) and CaCu3Ti4O12 (CCTO) via melt mixing followed by hot pressing were fabricated. These were characterized using X-ray diffraction (XRD), thermo gravimetric (TGA), scanning electron…

Materials Science · Physics 2013-01-18 P. Thomas , R. S. Ernest Ravindran , K. B. R. Varma

We have measured dielectric properties of Ca$_{1+x}$Cu$_{3-x}$Ti$_4$O$_{12}$ ($x$ = 0, 0.1, 0.5, 1, 1.5, 2, 2.9 and 3), and have found that Ca$_2$Cu$_2$Ti$_4$O$_{12}$ (a composite of CaCu$_3$Ti$_4$O$_{12}$ and CaTiO$_3$) exhibits a high…

Materials Science · Physics 2009-11-11 W. Kobayashi , I. Terasaki

The origins of an ultrahigh dielectric constant in polycrystalline CaCu3Ti4O12 (CCTO) was studied using the combination of impedance spectroscopy, electron microscopy, and scanning probe microscopy (SPM). Impedance spectra indicate that the…

Materials Science · Physics 2009-11-10 S. V. Kalinin , J. Shin , G. M. Veith , A. P. Baddorf , M. V. Lobanov , H. Runge , M. Greenblatt

The glasses in the system (100-x)TeO2-xCaCu3Ti4O12, (x=0.25 to 3 mol %) were fabricated. The color varied from olive green to brown as the CaCu3Ti4O12 (CCTO) content increased in TeO2 matrix. The X-ray powder diffraction and differential…

Materials Science · Physics 2013-01-22 P. Thomas , K. B. R. Varma

High dielectric constant nano composite of Polyaniline (PANI) CaCu3Ti4O12 (CCTO) was synthesized using a simple procedure involving in-situ polymerization of aniline in dil. HCl. The PANI and the composite were subjected to X-ray…

Materials Science · Physics 2013-01-18 P. Thomas , K. Dwarakanath , K. B. R. Varma

The present work reports synthesis, as well as a detailed and careful characterization of structural, magnetic, and dielectric properties of differently tempered undoped and doped CaCu3Ti4O12 (CCTO) ceramics. For this purpose, neutron and…

Materials Science · Physics 2010-01-22 S. Krohns , J. Lu , P. Lunkenheimer , V. Brize , C. Autret-Lambert , M. Gervais , F. Gervais , F. Bouree , F. Porcher , A. Loidl

We observe the large enhancement in the dielectric response near the percolation threshold in a composite nanoparticle system consisting of metallic RuO$_2$ grains embedded into dielectric CaCu$_3$Ti$_4$O$_1$$_2$ (CCTO) matrix and annealed…

Materials Science · Physics 2015-06-19 Rupam Mukherjee , Gavin Lawes , Boris Nadgorny

For pyroelectric detector application materials should have low dielectric constant, high pyroelectric coefficient, large non volatile polarization at small applied electric field and low specific heat. Large field (greater than 1200kV/cm)…

Materials Science · Physics 2008-08-05 S. Satapathy , P. K. Gupta , K. B. R. Varma , Pragya Tiwari , V. Ganeshan

The structural, dielectric and ferroelectric properties of lead-free (Na0.5-xKxBi0.5-xLax)TiO3 powders synthesized by sol-gel self-combustion method were investigated. Rietveld refinement of Synchrotron x-ray diffraction data confirms pure…

Structural, vibrational, and lattice dielectric properties of CdCu{3}Ti{4}O{12} are studied using density-functional theory within the local spin-density approximation, and the results are compared with those computed previously for…

Materials Science · Physics 2009-11-07 Lixin He , J. B. Neaton , David Vanderbilt , Morrel H. Cohen

The cubic perovskite-related ceramic CaCu3Ti4O12 has a very high static dielectric constant ~10000 at room temperature (RT), which drops to about 100 below about 100 K. Substituting Cd for Ca reduces the RT value of the dielectric constant…

Strongly Correlated Electrons · Physics 2007-05-23 C. C. Homes , T. Vogt , S. M. Shapiro , W. Si , S. Wakimoto , M. A. Subramanian

In the present work the authors report results of broadband dielectric spectroscopy on various samples of CaCu3Ti4O12, including so far only rarely investigated single crystalline material. The measurements extend up to 1.3 GHz, covering…

Materials Science · Physics 2008-09-03 S. Krohns , P. Lunkenheimer , S. G. Ebbinghaus , A. Loidl

We present dielectric measurements of the colossal dielectric constant material CaCu3Ti4O12 extending up to 1.3 GHz also covering so far only rarely investigated single crystalline samples. Special emphasis is put on the second relaxation…

Materials Science · Physics 2007-07-19 S. Krohns , P. Lunkenheimer , S. G. Ebbinghaus , A. Loidl

A thorough investigation of the dielectric properties of Cu2Ta4O12, a material crystallizing in a pseudo-cubic, perovskite-derived structure is presented. We measured the dielectric constant and conductivity of single crystals in an…

Materials Science · Physics 2009-11-10 B. Renner , P. Lunkenheimer , M. Schetter , A. Loidl , A. Reller , S. G. Ebbinghaus

We report on linear and non-linear dielectric property measurements of BaTiO3 - CoFe2O4 (BTO-CFO) ferroelectro-magnetic nano-composites and pure BaTiO3 and CoFe2O4 samples with Scanning Near Field Microwave Microscopy. The permittivity…

Materials Science · Physics 2009-11-11 Yi Qi , H. Zheng , R. Ramesh , Steven M. Anlage

The dispersal of high dielectric constant ferroelectric ceramic material Ba(0.7)Sr(0.3)TiO(3) (Tc~30 C) and Ba(0.88)Sr(0.12)TiO(3) (Tc~90 C) in an ion conducting polymer electrolyte (PEO:NH4I) is reported to result in an increase in the…

Chemical Physics · Physics 2009-11-10 Pramod Kumar Singh , Amreesh Chandra

In the present work we demonstrate that in addition to the well-known colossal-dielectric-constant material CaCu3Ti4O12 also various members of the series Ln2/3Cu3Ti4O12 with Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er and Tm, exhibit…

Materials Science · Physics 2010-03-25 J. Sebald , S. Krohns , P. Lunkenheimer , S. G. Ebbinghaus , S. Riegg , A. Reller , A. Loidl
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