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Carbon nanostructures are ideal substrates for functionalization with molecules, since they consist of a single atomic layer giving rise to an extraordinary sensitivity to changes in their surrounding. The functionalization opens a new…

Mesoscale and Nanoscale Physics · Physics 2015-01-20 Ermin Malic , Heiko Appel , Oliver T. Hofmann , Angel Rubio

We report results of a multiscale simulation study of multilayer structures consisting of graphene sheets with embedded Pt nanoparticles. Density functional theory is used to understand the energetics of Pt-graphene interfaces and provide…

Applied Physics · Physics 2020-04-28 Samaneh Nasiri , Christian Greff , Kai Wang , Mingjun Yang , Qianqian Li , Paolo Moretti , Michael Zaiser

An application of quantum size carbon structures--graphenes as electrodes of supercapacitors is studied. A fundamental limit of energy and power density arising from quantum nature of objects due to singularity in graphene density of states…

We investigate the adsorption of graphene sheets on h-BN substrates by means of first-principles calculations in the framework of adiabatic connection fluctuation-dissipation theory in the random phase approximation. We obtain adhesion…

Mesoscale and Nanoscale Physics · Physics 2011-12-14 B. Sachs , T. O. Wehling , M. I. Katsnelson , A. I. Lichtenstein

We study the effects of metallic doping on the electronic properties of graphene using density functional theory in the local density approximation in the presence of a local charging energy (LDA+U). The electronic properties are sensitive…

Materials Science · Physics 2009-11-13 B. Uchoa , C. -Y. Lin , A. H. Castro Neto

We investigate the optical properties of edge-functionalized graphene nanosystems, focusing on the formation of junctions and charge transfer excitons. We consider a class of graphene structures which combine the main electronic features of…

Materials Science · Physics 2011-05-18 Caterina Cocchi , Deborah Prezzi , Alice Ruini , Marilia J. Caldas , Elisa Molinari

Low frequency 1/f noise is investigated in graphene, encapsulated between hexagonal boron nitride (hBN) substrate in dual gated geometry. The overall noise magnitude is smaller as compared to graphene on Si/SiO2 substrate. The noise…

Mesoscale and Nanoscale Physics · Physics 2021-12-15 Chandan Kumar , Anindya Das

We study the electronic structure of diluted F atoms chemisorbed on graphene using density functional theory calculations. We show that the nature of the chemical bonding of a F atom adsorbed on top of a C atom in graphene strongly depends…

Mesoscale and Nanoscale Physics · Physics 2015-03-18 J. O. Sofo , A. M. Suarez , Gonzalo Usaj , P. S. Cornaglia , A. D. Hernández-Nieves , C. A. Balseiro

Stability and electronic properties of atomic layers of GaN are investigated in the framework of the van der Waals-density functional theory. We find that the ground state of the layered GaN is a planar graphene-like configuration rather…

Mesoscale and Nanoscale Physics · Physics 2013-02-22 Dongwei Xu , Haiying He , Ravindra Pandey , Shashi P. Karna

Man-made artificial graphene has attracted significant attention in the past few years due to the possibilities to construct designer Dirac fermions with unexpected topological properties and applications in nanoelectronics. Here we use a…

Materials Science · Physics 2014-12-10 Matti Ropo , Sami Paavilainen , Jaakko Akola , Esa Räsänen

We report on the detection and charge distribution analysis for nitrogen substitutional dopants in single layer graphene membranes by aberration-corrected high-resolution transmission electron microscopy (HRTEM). Further, we show that the…

This article reviews the basic theoretical aspects of graphene, a one atom thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric…

Other Condensed Matter · Physics 2009-01-15 A. H. Castro Neto , F. Guinea , N. M. R. Peres , K. S. Novoselov , A. K. Geim

Nitrogen-doped epitaxial graphene grown on SiC(000?1) was prepared by exposing the surface to an atomic nitrogen flux. Using Scanning Tunneling Microscopy (STM) and Spectroscopy (STS), supported by Density Functional Theory (DFT)…

We study the electronic and structural properties of substitutional impurities of graphenelike nanoporous materials C$_2$N, $tg$-, and $hg$-C$_3$N$_4$ by means of density functional theory calculations. We consider four types of impurities;…

Materials Science · Physics 2020-10-21 Saif Ullah , Pablo A. Denis , Marcos G. Menezes , Fernando Sato , Rodrigo B. Capaz

Graphene nanoribbon folds with single and double closed edges are studied using density functional theory methods. Van der Waals dispersive interactions are included via semi-empirical pairwise optimized potential. The geometrical phases of…

Materials Science · Physics 2013-05-09 Nam B. Le , Lilia M. Woods

In this study, we investigate effects of boron substitution on the structural and electronic properties of small tungsten clusters using density functional theory (DFT). We construct a series of tungsten boride clusters by replacing…

Materials Science · Physics 2025-12-17 Akshata M. Waghmare , Sajeev S. Chacko , Balasaheb J. Nagare

Recently cycloarene has been experimentally obtained in a self-assembled structure, forming graphene-like monoatomic layered systems. Here, we establish the bandgap engineering/prediction in cycloarene assemblies within a combination of…

Materials Science · Physics 2021-06-09 F. Crasto de Lima , A. Fazzio

Boron (B) containing III-nitride materials, such as wurtzite (B,Ga)N alloys, have recently attracted significant interest to tailor the electronic and optical properties of optoelectronic devices operating in the visible and ultraviolet…

Materials Science · Physics 2023-08-16 Cara-Lena Nies , Thomas P. Sheerin , Stefan Schulz

In a Bernal graphene bilayer, carbon atoms belong to two inequivalent sublattices A and B, with atoms that are coupled to the other layer by $p_\sigma$ bonds belonging to sublattice A and the other atoms belonging to sublattice B. We…

Mesoscale and Nanoscale Physics · Physics 2018-09-05 Ahmed Missaoui , Jouda Jemaa Khabthani , Nejm-Eddine Jaidane , Didier Mayou , Guy Trambly de Laissardière

In this Letter, we derive an effective theory of graphene on a hexagonal Boron Nitride (h-BN) substrate. We show that the h-BN substrate generically opens a spectral gap in graphene despite the lattice mismatch. The origin of that gap is…

Mesoscale and Nanoscale Physics · Physics 2012-11-12 M. Kindermann , Bruno Uchoa , D. L. Miller