Related papers: Rubidium Rydberg linear macrotrimers
Conical intersections between electronic potential energy surfaces are paradigmatic for the study of non-adiabatic processes in the excited states of large molecules. However, since the corresponding dynamics occurs on a femtosecond…
Since their first experimental observation, ultralong-range Rydberg molecules consisting of a highly excited Rydberg atom and a ground state atom have attracted the interest in the field of ultracold chemistry. Especially the intriguing…
We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…
Matter-wave interferometry has been performed with helium atoms in high Rydberg states. In the experiments the atoms were prepared in coherent superpositions of Rydberg states with different electric dipole moments. Upon the application of…
We present evidence for Rydberg-Rydberg interaction in a gas of rubidium atoms above room temperature. Rabi oscillations on the nanosecond timescale to different Rydberg states are investigated in a vapor cell experiment. Analyzing the…
We report the observation of cold Cs Rydberg atom molecules bound at internuclear separations of R~3-9 um. The bound states result from avoided crossings between Rydberg atom pair interaction potentials in an applied electric field. The…
We investigate the impact of combined electric and magnetic fields on the structure of ultralong-range polar Rydberg molecules. Our focus is hereby on the parallel as well as the crossed field configuration taking into account both the…
We investigate the formation of trimers in an infinite one-dimensional lattice model of hard-core particles with single-particle hopping $t$ and and nearest-neighbour two-body $U$ and three-body $V$ interactions of relevance to Rydberg…
We investigate triatomic molecules that consist of two ground state atoms and a highly excited Rydberg atom, bound at large internuclear distances of thousands of \AA ngstroms. In the molecular state the Rydberg electron is in a…
We explore the possibility to trap Rydberg atoms in tightly confining magnetic microtraps. The trapping frequencies for Rydberg atoms are expected to be influenced strongly by magnetic field gradients. We show that there are regimes where…
Ultralong-range Rydberg molecules provide an exciting testbed for molecular physics at exaggerated scales. In the so-called trilobite and butterfly Rydberg molecules, the Born-Oppenheimer approximation can fail due to strong non-adiabatic…
We examine topological phases and symmetry-protected electronic edge states in the context of a Rydberg composite: a Rydberg atom interfaced with a structured arrangement of ground-state atoms. The electronic Hamiltonian of such a composite…
We study ultracold long-range collisions of heteronuclear alkali-metal dimers with a reservoir gas of alkali-metal Rydberg atoms in a two-photon laser excitation scheme. In a low density regime where molecules remain outside the Rydberg…
Quantum reflection is a pure wave phenomena that predicts reflection of a particle at a changing potential for cases where complete transmission occurs classically. For a chemical bond, we find that this effect can lead to non-classical…
Optically trapped Rydberg atoms are a suitable platform to explore quantum many-body physics mediated by long-range atom--atom interactions that can be engineered through externally applied light fields. However, this approach is limited to…
Three-body F\"orster resonances controlled by a dc electric field are of interest for the implementation of three-qubit quantum gates with single atoms captured in optical traps and laser-excited into strongly interacting Rydberg states. In…
We investigate the impact of an electric field on the structure of ultralong-range polar diatomic Rydberg molecules. Both the s-wave and p-wave interactions of the Rydberg electron and the neutral ground state atom are taken into account.…
We present experiments on two-photon excitation of ${\rm ^{87}}$Rb atoms to Rydberg states. For this purpose, two continuous-wave (cw)-laser systems for both 780 nm and 480 nm have been set up. These systems are optimized to a small…
We review ultralong-range Rydberg molecules (ULRM), which are bound states between a Rydberg atom and one or more ground-state atoms with bond lengths on the order of thousands of Bohr radii. The binding originates from multiple…
Experiments in dense, ultracold gases of rubidium Rydberg atoms show a considerable decrease of the radiative excited state lifetimes compared to dilute gases. This accelerated decay is explained by collective and cooperative effects,…