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Partial atomic charges are a useful and intuitive concept for understanding molecular properties and chemical reaction mechanisms, showing how changes in molecular geometry can affect the flow of electronic charge within a molecule.…

Chemical Physics · Physics 2022-01-14 Ryan J. MacDonell , Serguei Patchkovskii , Michael S. Schuurman

Nanoscale molecular-electronic devices and machines are emerging as promising functional elements, naturally flexible and efficient, for next generation technologies. A deeper understanding of carrier dynamics in molecular junctions is…

Mesoscale and Nanoscale Physics · Physics 2018-04-04 K. Beltako , F. Michelini , N. Cavassilas , L. Raymond

Using time-dependent current-density functional theory, we derive analytically the dynamical exchange-correlation correction to the DC conductance of nanoscale junctions. The correction pertains to the conductance calculated in the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Na Sai , Michael Zwolak , Giovanni Vignale , Massimiliano Di Ventra

Previous study of properties of the first-order phase transition in a set of plasma mod-els with common feature - absence of individual correlations between charges of opposite sign, was continued. Predicted discontinuities in equilibrium…

Plasma Physics · Physics 2009-02-16 I. L. Iosilevski , A. Yu. Chigvintsev

Foerster and modified Redfield theories play one of the central roles in the description of excitation energy transfer in molecular systems. However, in the present state, these theories describe only the dynamics of populations of local…

Chemical Physics · Physics 2020-01-29 Anton Trushechkin

The effect of quantum fluctuations on the current-voltage characteristics of Josephson junctions and superconducting nanowires is studied in the underdamped limit. Quantum fluctuations induce transitions between a Coulomb--blockade and a…

Mesoscale and Nanoscale Physics · Physics 2008-08-21 A. Zazunov , N. Didier , F. W. J. Hekking

We analyze the interplay between vibrational and electronic degrees of freedom in charge transport across a molecular single-electron transistor. We focus on the wide class of molecules which possess quasi-degenerate vibrational…

Soft Condensed Matter · Physics 2007-05-23 Andrea Donarini , Milena Grifoni , Klaus Richter

We show, using a tight-binding model and time-dependent density-functional theory, that a quasi-steady state current can be established dynamically in a finite nanoscale junction without any inelastic effects. This is simply due to the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Neil Bushong , Na Sai , Massimiliano Di Ventra

We study the dynamics of quantum excitations inside macromolecules which can undergo conformational transitions. In the first part of the paper, we use the path integral formalism to rigorously derive a set of coupled equations of motion…

Soft Condensed Matter · Physics 2015-06-04 L. Boninsegna , P. Faccioli

We theoretically study electronic transport through a layer of quantum dots connecting two metallic leads. By the inclusion of an inductor in series with the junction, we show that steady electronic transport in such a system may be…

Mesoscale and Nanoscale Physics · Physics 2015-03-14 Danko Radic , Anatoly M. Kadigrobov , Leonid Y. Gorelik , Robert I. Shekhter , Mats Jonson

Quantum dots are nanoscopic systems, where carriers are confined in all three spatial directions. Such nanoscopic systems are suitable for fundamental studies of quantum mechanics and are candidates for applications such as quantum…

Mesoscale and Nanoscale Physics · Physics 2016-03-16 Bahareh Goldozian , Fikeraddis A. Damtie , Gediminas Kiršanskas , Andreas Wacker

The charge transfer in low energy (0.25 to 150 eV/amu) H($nl$) + He$^+(1s)$ collisions is investigated using a quasi-molecular approach for the $n=2,3$ as well as the first two $n=4$ singlet states. The diabatic potential energy curves of…

Quantum Physics · Physics 2015-05-19 J. Loreau , K. Sodoga , D. Lauvergnat , M. Desouter-Lecomte , N. Vaeck

A theory for light-induced current by strong optical pulses in molecular-tunneling junctions is described. We consider a molecular bridge represented by its highest occupied and lowest unoccupied levels, HOMO and LUMO, respectively. We take…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 B. D. Fainberg , M. Jouravlev , A. Nitzan

Charge dynamics in an ultra-cold setup involving a laser dressed atom and an ion is studied here. This transfer of charge is enabled through molecular Rydberg states that are accessed via a laser. The character of the charge exchange…

Atomic Physics · Physics 2019-07-17 Rick Mukherjee

A transport methodology to study the electron transport between quantum dots arrays based in Transfer Hamiltonian approach is presented. The interactions between the quantum dots and between the quantum dots and the electrodes are…

Mesoscale and Nanoscale Physics · Physics 2012-05-10 S. Illera , N. Garcia-Castello , J. D. Prades , A. Cirera

Controlling the transmission of electrical current using a quantum point contact constriction paved a way to a large variety of experiments in mesoscopic physics. The increasing interest in heat transfer in such systems fosters questions…

Mesoscale and Nanoscale Physics · Physics 2017-12-25 Amir Rosenblatt , Fabien Lafont , Ivan Levkivskyi , Ron Sabo , Itamar Gurman , Daniel Banitt , Moty Heiblum , Vladimir Umansky

A quantum shuttle is an archetypical nanoelectromechanical device, where the mechanical degree of freedom is quantized. Using a full-scale numerical solution of the generalized master equation describing the shuttle, we have recently shown…

Mesoscale and Nanoscale Physics · Physics 2016-08-16 A. Donarini , T. Novotný , A. -P. Jauho

Preparing and observing quantum states of nanoscale particles is a challenging task with great relevance for quantum technologies and tests of fundamental physics. In contrast to atomic systems with discrete transitions, nanoparticles…

Quantum Physics · Physics 2020-12-23 Lukas Martinetz , Klaus Hornberger , James Millen , M. S. Kim , Benjamin A. Stickler

Transport of ions in molecular-scale confined spaces is central to all aspects of life and technology: into a crack, it may break steel within days; through a membrane separator, it determines the efficiency of electrochemical energy…

Soft Condensed Matter · Physics 2021-04-05 H. -W. Cheng , J. Dziadkowiec , V. Wieser , A. M. Imre , M. Valtiner

The thermoelectric transport through a molecular bridge is discussed, with an emphasis on the effects of inelastic processes of the transport electrons caused by the coupling to the vibrational modes of the molecule. In particular it is…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 O. Entin-Wohlman , Y. Imry , A. Aharony