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Force fields uniquely assign interatomic forces for a given set of atomic coordinates. The underlying assumption is that electrons are in their quantum-mechanical ground state or in thermal equilibrium. However, there is an abundance of…

Materials Science · Physics 2013-08-19 Wolf B. Dapp , Martin H. Müser

Charge transfer statistics of quantum particles is obtained by analysing the time evolution of the many-body wave function. Exploiting properly chosen gauge transformations, we construct the probabilities for transfers of a discrete number…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 A. Shelankov , J. Rammer

The conductance of a molecular junction is commonly determined by either charge-transfer-doping, where alignment of the Fermi energy to the molecular levels is achieved, or tunnelling through the tails of molecular resonances within the…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 R. Gutierrez , G. Fagas , K. Richter , F. Grossmann , R. Schmidt

The transmission of charge through an ultrasmall double junction is considered with Coulomb effects but at zero temperature. We construct an equation which describes the time development of the transmission probability of charges and solve…

Mesoscale and Nanoscale Physics · Physics 2016-08-15 Heinz-Olaf Müller

A new approach in the quantum theory of few-electron nanoelectronic devices -- the S-matrix approach -- is presented in a simple example: a single-electron transistor consisting of a single-level quantum dot connected with two metallic…

High Energy Physics - Phenomenology · Physics 2007-05-23 Nguyen Van Hieu , Nguyen Bich Ha

Transport through molecular contacts with a sluggish intramolecular vibrational mode strongly coupled to excess charges is studied far from equilibrium. A Born-Oppenheimer approximation in steady state reveals voltage dependent energy…

Mesoscale and Nanoscale Physics · Physics 2012-06-27 Lars Kecke , Joachim Ankerhold

An interaction of electromagnetic field with a nanostructure composed of two quantum dots is studied theoretically. An effect of a resonant electron transfer between the localized low-lying states of quantum dots is predicted. A necessary…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Leonid A. Openov

The conductance of single molecule junctions is calculated using a Landauer approach combined to many-body perturbation theory MBPT) to account for electron correlation. The mere correction of the density-functional theory eigenvalues,…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 T. Rangel , A. Ferretti , P. E. Trevisanutto , V. Olevano , G. -M. Rignanese

Evaluating the time-dependent dynamics of driven open quantum systems is relevant for a theoretical description of many systems, including molecular junctions, quantum dots, cavity-QED experiments, cold atoms experiments and more. Here, we…

Mesoscale and Nanoscale Physics · Physics 2017-08-23 Archak Purkayastha , Yonatan Dubi

Although Marcus theory is widely used to describe charge transfer in molecular systems, in its usual form it is restricted to transfer from one molecule to another. If a charge is delocalised across multiple donor molecules, this approach…

Chemical Physics · Physics 2019-11-28 Natasha B. Taylor , Ivan Kassal

We study a quantum teleportation scheme between two nanomechanical modes without local interaction. The nanomechanical modes are linearly coupled to and connected by the continuous variable modes of a superconducting circuit consisting of a…

Quantum Physics · Physics 2011-07-26 L. Tian , S. M. Carr

The paper presents cross sections for collisions of neutral atoms/molecules with a charged nanoparticle, which is the source of the dipole potential. The accuracy of the orbital limited motion (OLM) approximation is estimated. It is shown…

Plasma Physics · Physics 2016-12-19 M. N. Shneider

Single-electron circuits of the future, consisting of a network of quantum dots, will require a mechanism to transport electrons from one functional part to another. For example, in a quantum computer[1] decoherence and circuit complexity…

Mesoscale and Nanoscale Physics · Physics 2011-11-02 R. P. G. McNeil , M. Kataoka , C. J. B. Ford , C. H. W. Barnes , D. Anderson , G. A. C. Jones , I. Farrer , D. A. Ritchie

Quantum--Mechanical methods that are both computationally fast and accurate are not yet available for electronic excitations having charge transfer character. In this work, we present a significant step forward towards this goal for those…

Chemical Physics · Physics 2015-06-12 Michele Pavanello , Troy Van Voorhis , Lucas Visscher , Johannes Neugebauer

Quantum rate theory encompasses the electron-transfer rate constant concept of electrochemical reactions as a particular setting, besides demonstrating that the electrodynamics of these reactions obey relativistic quantum mechanical rules.…

We propose a simple scheme that describes accurately essential non-equilibrium effects in nanoscale electronics devices using equilibrium transport theory. The scheme, which is based on the alignment and dealignment of the junction…

Mesoscale and Nanoscale Physics · Physics 2012-10-01 V. M. García-Suárez , J. Ferrer

Molecular-scale diodes made from self-assembled monolayers (SAMs) could complement silicon-based technologies with smaller, cheaper, and more versatile devices. However, advancement of this emerging technology is limited by insufficient…

We study steady-state charge transfer across an interacting resonance-level model connected asymmetrically to two leads. For a linear energy dispersion relation of the leads, we calculate current-voltage characteristics of the model exactly…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Dibyendu Roy

The realization of molecular-based electronic devices depends to a large extent on the ability to mechanically stabilize the involved molecular bonds, while making use of efficient resonant charge transport through the device. Resonant…

Mesoscale and Nanoscale Physics · Physics 2018-09-11 David Gelbwaser-Klimovsky , Alán Aspuru-Guzik , Michael Thoss , Uri Peskin

We consider a two-level system coupled to contacts as a model for charge pump under external laser pulse. The model represents a charge-transfer molecule in a junction, and is a generalization of previously published results [B. D.…

Mesoscale and Nanoscale Physics · Physics 2011-05-31 Boris D. Fainberg , Maxim Sukharev , Tae-Ho Park , Michael Galperin