Related papers: On transition rates in surface hopping
A recent proposal by Hallam et al. suggested using the chaotic properties of the semiclassical equations of motion, obtained by the time dependent variational principle (TDVP), as a characterization of quantum chaos. In this paper, we…
A wide variety of physical systems ranging from the firing of neurons to eutrophication of lakes to the presence of Arctic summer sea ice exhibit a phenomenon known as tipping. In mathematical models, tipping can be caused by bifurcations,…
We study dissipative phase transitions in a system of two coupled fully-connected quantum Ising models interacting with an environment. The dynamics is governed by a Lindblad master equation combining coherent unitary evolution and…
Dynamical transitions, such as a change from bound to unbound motion, often occur as post-adiabatic crossings of a time-dependent separatrix. Whether or not any given orbit will include such a crossing transition typically depends…
We introduce an efficient method TTN-HEOM for exactly calculating the open quantum dynamics for driven quantum systems interacting with highly structured bosonic baths by combining the tree tensor network (TTN) decomposition scheme to the…
Adequate simulation of non-adiabatic dynamics through conical intersection requires account for a non-trivial geometric phase (GP) emerging in electronic and nuclear wave-functions in the adiabatic representation. Popular mixed…
The Landau--Zener (LZ) model describes a two-level quantum system that undergoes an avoided crossing. In the adiabatic limit, the transition probability vanishes. An auxiliary control field $H_\text{CD}$ can be reverse-engineered so that…
Nuclear quantum effects and non-Born--Oppenheimer effects play a vital role in many chemical and biological processes, motivating the incorporation of such effects into dynamical simulations. In real-time nuclear--electronic orbital…
Simple route of engineering topological phases for any desired value of winding and Chern numbers is found in the Su-Schrieffer-Heeger (SSH) model by adding a further neighbor hopping term of varying distances. It is known that the standard…
This work is a pedagogical survey about the hierarchical equations of motion and their implementation with the tensor-train format. These equations are a great standard in non-perturbative non-Markovian open quantum systems. They are exact…
We present statistics of quantum jumps in the two-level system with landau-Zener Hamiltonian that undergoes a Markovian process. For the Landau-Zener model, which is successful in simulating adiabatic/non-adiabatic evolution and quantum…
The hierarchical equations of motion technique has found widespread success as a tool to generate the numerically exact dynamics of non-Markovian open quantum systems. However, its application to low temperature environments remains a…
Non-adiabatic chemical reactions involving continuous circularly polarized light (cw CPL) have not attracted as much attention as dynamics in unpolarized/linearly polarized light. However, including circularly (in contrast to linearly)…
This paper is concerned with classes of models of stochastic reaction dynamics with time-scales separation. We demonstrate that the existence of the time-scale separation naturally leads to the application of the averaging principle and…
Chemical relaxation phenomena, including photochemistry and electron transfer processes, form a vigorous area of research in which nonadiabatic dynamics plays a fundamental role. Here, we show that for nonadiabatic dynamics with two…
In a quantum system with a smoothly and slowly varying Hamiltonian, which approaches a constant operator at times $t\to \pm \infty$, the transition probabilities between adiabatic states are exponentially small. They are characterized by an…
We develop a non-empirical scheme to search for the minimum-energy escape paths from the minima of the potential surface to unknown saddle points nearby. A stochastic algorithm is constructed to move the walkers up the surface through the…
It has been noticed that when the waiting time distribution exhibits a transition from an intermediate time power law decay to a long-time exponential decay in the continuous time random walk model, a transition from anomalous diffusion to…
A surface-hopping algorithm recently derived from the exact factorization approach, SHXF, [Ha, Lee, Min, J. Phys. Chem. Lett. 9, 1097 (2018)] introduces an additional term in the electronic equation of surface-hopping, which couples…
We examine the effect of nonlinearity at a level crossing on the probability for nonadiabatic transitions $P$. By using the Dykhne-Davis-Pechukas formula, we derive simple analytic estimates for $P$ for two types of nonlinear crossings. In…