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Electron energy loss spectroscopy is consolidating as a powerful tool to explore electronic (as well as vibrational) excitations of matter, including molecules. Performed in a scanning transmission electron microscope, this technique is…

Chemical Physics · Physics 2021-03-05 Ciro A. Guido , Enzo Rotunno , Matteo Zanfrognini , Stefano Corni , Vincenzo Grillo

A periodic arrangement of 2D conducting planes is known to host a (bulk) plasmon dispersion that interpolates between the typical, gapped behavior of 3D metals and a gapless, acoustic regime as a function of the out-of-plane wavevector. The…

Strongly Correlated Electrons · Physics 2022-11-09 Christian Boyd , Luke Yeo , Philip W. Phillips

We calculate electron energy loss spectra (EELS) for composite plasmonic structures based on silicene and germanene. A continued-fraction expression for the effective dielectric function is used to perform multiscale calculations of EELS…

Materials Science · Physics 2013-11-05 L. Rast , V. K. Tewary

A consistent theory of electron energy-loss spectroscopy (EELS) includes two indispensable elements: (i) electronic response of the target system and (ii) quantum kinematics of probing electrons. While for the bulk materials and their…

Mesoscale and Nanoscale Physics · Physics 2017-12-12 Vladimir U. Nazarov , Vyacheslav M. Silkin , Eugene E. Krasovskii

Time-resolved and ultrafast electron energy-loss spectroscopy (EELS) is an emerging technique for measuring photoexcited carriers, lattice dynamics, and near-fields across femtosecond to microsecond timescales. When performed in either a…

Materials Science · Physics 2025-11-03 Wonseok Lee , Levi D. Palmer , Thomas E. Gage , Scott K. Cushing

High-resolution electron energy loss spectroscopy (HREELS) is one of the most powerful methods to detect the dispersion of plasmons. However, we find that in the HREELS measurement, the scattering geometric configuration will seriously…

Mesoscale and Nanoscale Physics · Physics 2022-03-18 Jiade Li , Zijian Lin , Guangyao Miao , Weiliang Zhong , Siwei Xue , Yi Li , Zhiyu Tao , Weihua Wang , Jiandong Guo , Xuetao Zhu

Cathodoluminescence spectroscopy has been performed on silver nanoparticles in a scanning electron microscopy setup. Peaks appearing in the visible range for particles fabricated on silicon substrate are shown to arrive from excitation of…

Optics · Physics 2009-06-08 Pratik Chaturvedi , Keng Hsu , Anil Kumar , James C. Mabon , Nicholas Fang

Surface plasmons on metals can concentrate light into sub-nanometric volumes and on these near atomic length scales the electronic response at the metal interface is smeared out over a Thomas-Fermi screening length. This nonlocality is a…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Yu Luo , A. I. Fernandez-Dominguez , Aeneas Wiener , S. A. Maier , J. B. Pendry

Surface and volume plasmons excited in a metal cluster by moving electron and corresponding inelastic scattering spectra are studied based on the hydrodynamic approach. Along with the bulk losses traditionally taken into account, the…

Plasma Physics · Physics 2016-04-20 V. B. Gildenburg , V. A. Kostin , I. A. Pavlichenko

Spatially resolved electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM) has been used to investigate as fluidic phase in nanoubbles embedded in a metallic Pd90Pt10 matrix. Using the 1s->2p…

Materials Science · Physics 2016-08-14 D. Taverna , M. Kociak , O. Stéphan , A. Fabre , E. Finot , B. Décamps , C. Colliex

The electronic properties of two-dimensional (2D) materials depend sensitively on the underlying atomic arrangement down to the monolayer level. Here we present a novel strategy for the determination of the band gap and complex dielectric…

The dynamical response of metallic clusters up to $10^3$ atoms is investigated using the restricted molecular dynamics simulations scheme. Exemplarily, sodium like material is considered. Correlation functions are evaluated to investigate…

Atomic and Molecular Clusters · Physics 2015-05-28 Thomas Raitza , Heidi Reinholz , Igor Morozov , Gerd Röpke

We demonstrate spatially-resolved measurements of spontaneous and stimulated electron-photon interactions in nanoscale optical near fields using electron energy-loss spectroscopy (EELS), cathodoluminescence spectroscopy (CL), and…

Recent developments in experiments with vibrational electron energy loss spectroscopy (EELS) have revealed spectral shape variations at spatial resolutions down to sub-atomic scale. Interpretation in terms of local phonon density of states…

Materials Science · Physics 2021-09-15 Paul M. Zeiger , Ján Rusz

Plasmonics, the science and technology of the interaction of light with metallic objects, is fundamentally changing the way we can detect, generate and manipulate light. Although the field is progressing swiftly, thanks to the availability…

Swift electrons passing near or through metallic structures have proven to be an excellent tool for studying plasmons and other types of confined optical modes involving collective charge oscillations in the materials hybridized with…

A theoretical study of the surface energy-loss function of freestanding Pb(111) thin films is presented, starting from the single monolayer case. The calculations are carried applying the linear response theory, with inclusion of the…

Materials Science · Physics 2013-04-11 X. Zubizarreta , E. V. Chulkov , V. M. Silkin

Versatile quantum modes emerge for plasmon describing the collective oscillations of free electrons in metallic nanoparticles when the particle sizes are greatly reduced. Rather than traditional nanoscale study, the understanding of quantum…

The performance of electron energy-loss spectrometers can often be limited by their electron-optical aberrations. Due to recent developments in high energy-resolution and momentum-resolved electron energy loss spectroscopy (EELS), there is…

Materials Science · Physics 2023-02-28 Yueming Guo , Andrew R. Lupini

High energy electron beams can now be routinely focused to 1-2 {\AA} and offer the ability to obtain vibrational information from materials using monochromated electron energy-loss spectroscopy (EELS) in a scanning transmission electron…

Materials Science · Physics 2021-07-13 Kartik Venkatraman , Peter A. Crozier