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Related papers: Norm-conserving pseudopotentials with chemical acc…

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Recently published Density Functional Theory results from Whaley-Baldwin et. al. [New J. Phys. 22 023020, Feb 2020] using the PBE functional suggest that elemental sulfur does not adopt the simple-cubic (SC) $Pm\bar{3}m$ phase at high…

Materials Science · Physics 2020-12-07 Jack A. J. Whaley-Baldwin

We give a detailed analysis of the origin of spurious divergences and finite steps that have been recently identified in particle-number restoration calculations within the nuclear energy density functional framework. We isolate two…

Nuclear Theory · Physics 2011-08-17 M. Bender , T. Duguet , D. Lacroix

We show that the energy of a perturbed system can be fully recovered from the unperturbed system's electron density. We derive an alchemical integral transform by parametrizing space in terms of transmutations, the chain rule and…

Chemical Physics · Physics 2022-10-28 Simon León Krug , Guido Falk von Rudorff , O. Anatole von Lilienfeld

A method is presented to evaluate the particle-phonon coupling (PC) corrections to the single-particle energies (SPEs) in semi-magic nuclei. In such nuclei always there is a collective low-lying $2^+$ phonon, and a strong mixture of…

Nuclear Theory · Physics 2017-12-12 E. E. Saperstein , M. Baldo , S. S. Pankratov , S. V. Tolokonnikov

Astrophysical models studying the origin of the p-nuclei require knowledge of the reaction rates of photodisintegrations and capture reactions. Since experimental data at astrophysically relevant energies are limited, reaction rate…

Nuclear Theory · Physics 2021-04-28 E. Vagena , M. Axiotis , P. Dimitriou

We study the performance of our previously proposed Projective Quantum Eigensolver (PQE) on IBM's quantum hardware in conjunction with error mitigation techniques. For a single qubit model of H$_2$, we find that we are able to obtain…

Quantum Physics · Physics 2023-10-10 Jonathon P. Misiewicz , Francesco A. Evangelista

Multiresolution analysis of electronic structure affords the opportunity to capture the full physics of atomic cores in a systematically improvable manner. Applying new techniques, we demonstrate for the first time that multiresolution…

Condensed Matter · Physics 2009-11-07 Torkel D. Engeness , T. A. Arias

We calculate groundstate total energies and single-particle excitation energies of seven pi conjugated molecules described with the semi-empirical Pariser-Parr-Pople (PPP) model using self-consistent many-body perturbation theory at the GW…

Mesoscale and Nanoscale Physics · Physics 2013-11-22 K. Kaasbjerg , K. S. Thygesen

We provide an integration of the universal, perturbative explicitly correlated [2]$_\text{R12}$-correction in the context of the Variational Quantum Eigensolver (VQE). This approach is able to increase the accuracy of the underlying…

Quantum Physics · Physics 2022-07-08 Philipp Schleich , Jakob S. Kottmann , Alán Aspuru-Guzik

Error estimates of finite element methods for reaction-diffusion problems are often realised in the related energy norm. In the singularly perturbed case, however, this norm is not adequate. A different scaling of the $H^m$ seminorm for…

Numerical Analysis · Mathematics 2021-03-15 Sebastian Franz , Hans-G. Roos

First principles calculations based on density functional theory are having an incerasing impact on our understanding of molecule-surface interactions. For example, calculations of the multi-dimensional potential energy surface have…

Materials Science · Physics 2007-05-23 O. Gulseren , D. M. Bird , S. E. Humphreys

The bulk properties (lattice constants, bulk moduli, and cohesive energies) of alkali, alkaline-earth, and transition metals are studied within the framework of the recently developed meta-GGA (meta-Generalized Gradient Approximation)…

Materials Science · Physics 2018-11-14 Subrata Jana , Kedar Sharma , Prasanjit Samal

Analytic approximations to the ground-state energy of closed-shell quantum dots (number of electrons from 2 to 210) are presented in the form of two-point Pade approximants. These Pade approximants are constructed from the small- and…

Condensed Matter · Physics 2009-10-30 A. Gonzalez , B. Partoens , F. M. Peeters

We present a simple linear model to estimate the basis set incompleteness errors (BSIE) of (vertex-corrected) $GW$ QP energies based on the kinetic energy of the corresponding orbital only. We parametrise the model for $G_0W_0$,…

Chemical Physics · Physics 2025-12-01 Dario Baum , Lucas Visscher , Arno Förster

We use fully self-consistent GW calculations on diamond and silicon carbide to reparametrize the Heyd-Scuseria-Ernzerhof exact exchange density functional for use in band structure calculations of semiconductors and insulators. We show that…

Mesoscale and Nanoscale Physics · Physics 2015-08-05 V. Zólyomi , J. Kürti

The excitation energies and ionization potentials of the atoms in the first transition series are notoriously difficult to compute accurately. Errors in calculated excitation energies can range from 1--4 eV at the Hartree-Fock level, and…

chem-ph · Physics 2009-10-22 Thomas V. Russo , Richard L. Martin , P. Jeffrey Hay

The parameters of many-body potentials for Co, Nb and Zr metals, based on the embedded-atom method, have been systematically derived. The analytical potential scheme allows us to reproduce correctly the cohesive energies and structural…

Materials Science · Physics 2014-05-02 Pascal Thibaudeau , Julian Gale

By assuming the existence of a pseudopotential smooth enough to do Hartree-Fock variations and good enough to describe nuclear structure, we construct mass formulae that rely on general scaling arguments and on a schematic reading of shell…

Nuclear Theory · Physics 2015-06-26 J. Duflo , A. P. Zuker

The pseudospectral method is a powerful tool for finding highly precise solutions of Schr\"{o}dinger's equation for few-electron problems. We extend the method's scope to wave functions with non-zero angular momentum and test it on several…

Atomic Physics · Physics 2013-05-29 Paul E. Grabowski , David F. Chernoff

Using supersymmetry techniques analytical expressions for the average of the fidelity amplitude f_epsilon(tau)=< psi(0)| exp(2 pi i H_epsilon tau) exp(-2 pi i H_0 tau)| psi(0) > are obtained, where H_epsilon=H_0+(sqrt{epsilon}/(2 pi) )*V,…

Mathematical Physics · Physics 2009-11-10 H. -J. Stoeckmann , R. Schaefer
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