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Fluid polyamorphism, the existence of multiple amorphous fluid states in a single-component system, has been observed or predicted in a variety of substances. A remarkable example of this phenomenon is the fluid-fluid phase transition in…

Soft Condensed Matter · Physics 2022-09-21 Nathaniel R. Fried , Thomas J. Longo , Mikhail A. Anisimov

We have used a Hartree-type electron-helium potential together with a density functional description of liquid $^4$He and $^3$He to study the explosion of electron bubbles submitted to a negative pressure. The critical pressure at which…

Other Condensed Matter · Physics 2009-11-11 M. Pi , M. Barranco , R. Mayol , V. Grau

Solid helium (3He and 4He) in the hcp and fcc phases has been studied by path-integral Monte Carlo. Simulations were carried out in the isothermal-isobaric (NPT) ensemble at pressures up to 52 GPa. This allows one to study the temperature…

Statistical Mechanics · Physics 2015-06-25 Carlos P. Herrero

In recent years, metal hydride research has become one of the driving forces of the high-pressure community, as it is believed to hold the key to superconductivity close to ambient temperature. While numerous novel metal hydride compounds…

We report molecular dynamics simulations of a hydrophobic polymer-chain in aqueous solution between $260 {K}$ and $420 {K}$ at pressures of $1 {bar}$, $3000 {bar}$, and $4500 {bar}$. The simulations reveal a hydrophobically collapsed state…

Soft Condensed Matter · Physics 2017-09-13 Dietmar Paschek , Sascha Nonn , Alfons Geiger

We present a path-integral Monte Carlo study of dissociation in dense hydrogen ($1.75 \leq r_s \leq 2.2$, with $r_s$ the Wigner sphere radius). As temperature is lowered from $10^5$ to 5000 K, a molecular hydrogen gas forms spontaneously…

Condensed Matter · Physics 2009-10-28 W. R. Magro , D. M. Ceperley , C. Pierleoni , B. Bernu

Motivated by an experimental finding on the density of supercooled water at high pressure [O. Mishima, J. Chem. Phys. 133, 144503 (2010)] we performed atomistic molecular dynamics simulations study of bulk water in the isothermal-isobaric…

Soft Condensed Matter · Physics 2018-05-10 Solomon F. Duki , Mesfin Tsige

We employ quantum molecular dynamic simulations to investigate the behavior of benzene under shock conditions. The principal Hugoniot derived from the equation of state is determined. We compare our firs-principles results with available…

Materials Science · Physics 2015-05-14 Cong Wang , Ping Zhang

In their recent work Dias and Silvera (Science 2017) claim to have observed the Wigner-Huntington transition of hydrogen to a metallic state (MH) at a pressure of 495 GPa at low temperatures. The evidence for this transition is based on a…

Materials Science · Physics 2017-02-20 M. I. Eremets , A. P. Drozdov

Identifying the atomic structure and properties of solid hydrogen under high pressures is a long-standing problem of high-pressure physics with far-reaching significance in planetary and materials science. Determining the…

Materials Science · Physics 2020-04-16 Ke Liao , Xin-Zheng Li , Ali Alavi , Andreas Grüneis

By classical and path-integral molecular dynamics simulations, we study the pressure-temperature ($P$-$T$) phase diagram of LaH$_{10}$ to clarify the impact of temperature and atomic zero-point motions. We calculate the XRD pattern and…

Superconductivity · Physics 2022-05-31 Yuta Watanabe , Takuya Nomoto , Ryotaro Arita

The thermodynamic parameters of the superconducting state in Calcium under the pressure at 200 GPa have been determined. The numerical analysis by using the Eliashberg equations in the mixed representation has been conducted. It has been…

Superconductivity · Physics 2012-06-27 R. Szczęśniak , A. P. Durajski

The liquid-gas phase transition in finite nuclei is studied in a heated liquid-drop model where the nuclear drop is assumed to be in thermodynamic equilibrium with its own evaporated nucleonic vapor conserving the total baryon number and…

Nuclear Theory · Physics 2009-11-11 J. N. De , S. K. Samaddar , S. Shlomo , J. B. Natowitz

Diatomic nitrogen is an archetypal molecular system known for its exceptional stability and complex behavior at high pressures and temperatures, including rich solid polymorphism, formation of energetic states, and an insulator-to-metal…

Matter at low temperatures exhibits unusual properties such as superfluidity, superconductivity, Bose-Einstein condensation, and supersolidity. These states display quantum mechanical behaviours at scales much larger than atomic dimensions.…

Statistical Mechanics · Physics 2007-05-23 Gregory P. Bewley , Daniel P. Lathrop , Katepalli R. Sreenivasan

Black phosphorus (bP) is a crystalline material that can be seen as ordered stackings of two-dimensional layers, which lead to outstanding anisotropic physical properties. The knowledge of its pressure-temperature (P-T) phase diagram, and…

The paper presents an analysis of mechanical, structural, thermophysical and spectral properties of solid methane in temperature interval $0.5T_{tr} -T_{tr}$ ($T_{tr}$ is the triple point temperature) under equilibrium vapor pressure. It is…

Materials Science · Physics 2014-04-30 A. V. Leont'eva , A. Yu. Prokhorov , A. Yu. Zakharov , A. I. Erenburg

The transition of a warm dense fluid hydrogen from insulator to a conducting state at pressures of the order of 20-300 GPa and temperatures of 1000-5000 K has been the subject of active scientific research over the past few decades. The use…

Other Condensed Matter · Physics 2022-04-14 Ilya Fedorov , Vladimir Stegailov

We study the thermophysical properties of dense helium plasmas by using quantum molecular dynamics and orbital-free molecular dynamics simulations, where densities are considered from 400 to 800 g/cm$^{3}$ and temperatures up to 800 eV.…

Materials Science · Physics 2011-06-27 Cong Wang , Xian-Tu He , Ping Zhang

Adsorption of para-hydrogen films on Alkali metals substrates at low temperature is studied theoretically by means of Path Integral Monte Carlo simulations. Realistic potentials are utilized to model the interaction between two…

Statistical Mechanics · Physics 2009-11-11 M. Boninsegni