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Recent theoretical studies have suggested that transition metal perovskite oxide membranes can enable surface phonon polaritons in the infrared range with low loss and much stronger subwavelength confinement than bulk crystals. Such modes,…

We report a systematic investigation of orthorhombic perovskite-type RCrO3 powder samples by Raman scattering for nine different rare earth R3+ cations (R = Y, La, Pr, Sm, Gd, Dy, Ho, Yb, Lu). The room-temperature Raman spectra and the…

Materials Science · Physics 2012-02-13 M. Weber , J. Kreisel , P. A. Thomas , M. Newton , K. Sardar , R. I. Walton

Based on magnetization, specific heat, magnetostriction, and neutron diffraction studies on single-crystal TbCo2B2C, it is found out that the paramagnetic properties, down to liquid nitrogen temperatures, are well described by a Curie-Weiss…

Strongly Correlated Electrons · Physics 2008-12-24 M. ElMassalami , R. Moreno , R. M. Saeed , F. A. B. Chaves , C. M. Chaves , H. Takeya , B. Ouladdiaf , M. Amara

Barium zirconate (BaZrO$_3$) is one of the very few perovskites that is claimed to retain an average cubic structure down to \SI{0}{\K}, while being energetically very close to an antiferrodistortive phase obtained by condensation of a soft…

The structural phase diagram of the Pb-free ferroelectric (Na1/2Bi1/2)1-xBaxTiO3 (NBT-BT), x<0.1, has been explored by Raman spectroscopy at temperatures from 10 to 470 K. The data provide clear evidence for a proposed…

Materials Science · Physics 2015-05-18 Ben Wylie-van Eerd , Dragan Damjanovic , Naama Klein , Nava Setter , Joe Trodahl

We report a Raman scattering study of polycrystalline CaCu$_3$Ti$_4$O$_{12}$ (CCTO) under pressure up to 5.32 GPa. The pressure dependence of several Raman modes was investigated. No anomalies have been observed on the phonon spectra…

The spin degree of freedom of charge carriers in halide-perovskite semiconductors can be highly useful for information photonics applications. The Faraday effect is known to be the best indicator of paramagnetism of the material and of the…

A comparative analysis of the structural phase transitions of EuTiO3 and SrTiO3 (at TS = 282 and 105 K, respectively) is made on the basis of phonon-dispersion and density functional calculations. The phase transition of EuTiO3 is predicted…

Other Condensed Matter · Physics 2015-05-30 Jerry L. Bettis , Myung-Hwan Whangbo , Jürgen Köhler , Annette Bussmann-Holder , A. R. Bishop

We report on phonon properties and electronic transitions in CaCu3Ti4O12, a material which reveals a colossal dielectric constant at room temperature without any ferroelectric transition. The results of far- and mid-infrared measurements…

Strongly Correlated Electrons · Physics 2008-01-28 Ch. Kant , T. Rudolf , F. Mayr , S. Krohns , P. Lunkenheimer , S. G. Ebbinghaus , A. Loidl

Specific heat measurements and theoretical calculations reveal an intimate analogy between EuTiO3 and SrTiO3. For EuTiO3 a hitherto unknown specific heat anomaly is discovered at TA=282(1)K which is analogous to the well known specific heat…

Strongly Correlated Electrons · Physics 2015-05-28 A. Bussmann-Holder , J. Köhler , R. K. Kremer , J. M. Law

Complex electrical permittivity measurements in (1-x)[Pb(Mg1/3 Nb2/3)O3]-xPbTiO3 ceramics for 0.10 x 0.40 were performed in the frequency and temperature range from 1 kHz to 100 kHz and from 15 to 600 K, respectively. Unexpected dielectric…

Materials Science · Physics 2009-11-10 M. H. Lente , A. L. Zanin , E. R. M. Andreeta , I. A. Santos , D. Garcia , J. A. Eiras

The lattice dynamics of the $\rm YMnO_3$ magneto-electric compound has been investigated using density functional calculations, both in the ferroelectric and the paraelectric phases. The coherence between the computed and experimental data…

Materials Science · Physics 2012-03-09 Julien Varignon , Sébastien Petit , Marie-Bernadette Lepetit

We use density functional theory (DFT) calculations to study the lattice vibrations and electronic properties of the correlated metal LaNiO$_3$. To characterize the rhombohedral to cubic structural phase transition of perovskite LaNiO$_3$,…

Materials Science · Physics 2011-11-09 Gaoyang Gou , Ilya Grinberg , Andrew M. Rappe , James M. Rondinelli

Inelastic neutron-scattering experiments on the high-temperature superconductor La$_{1.855}$Sr$_{0.145}$CuO$_{4}$ reveal a magnetic excitation gap $\Delta$ that decreases continuously upon application of a magnetic field perpendicular to…

Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ is one of the simplest representatives of the class of lead relaxors and often serves as a model system for more complicated compounds. In this paper we analyse both polarized and depolarized Raman scattering…

Materials Science · Physics 2009-11-10 Oleksiy Svitelskiy , Jean Toulouse , Z. -G. Ye

Spectroscopic modes provide the most sensitive probe of the very weak interactions responsible for the properties of the long-wavelength cycloid in the multiferroic phase of \BF below $\TN \approx 640$ K. Three of the four modes measured by…

Materials Science · Physics 2015-06-15 Randy S. Fishman , Jason T. Haraldsen , Nobuo Furukawa , Shin Miyahara

The microstructure and phase transition in relaxor ferroelectric Pb(Mg1/3Nb2/3)O3 (PMN) and its solid solution with PbTiO3 (PT), PMN-xPT, remain to be one of the most puzzling issues of solid state science. In the present work we have…

Materials Science · Physics 2009-11-07 Z. -G. Ye , Y. Bing , J. Gao , A. A. Bokov , P. Stephens , B. Noheda , G. Shirane

We show with first-principles molecular dynamics the persistence of intrinsic $\langle111\rangle$ Ti off-centerings for BaTiO$_3$ in its cubic paraelectric phase. Intriguingly, these are inconsistent with the Pm$\bar 3$m space group often…

Materials Science · Physics 2022-04-01 Michele Kotiuga , Samed Halilov , Boris Kozinsky , Marco Fornari , Nicola Marzari , Giovanni Pizzi

We have studied niobium superconducting thin wires deposited onto a SrTiO$_{3}$ substrate. By measuring the reflection coefficient of the wires, resonances are observed in the superconducting state in the 130 MHz to 4 GHz range. They are…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 B. Camarota , F. Parage , F. Balestro , P. Delsing , O. Buisson

We investigate the magnetization dynamics of $TmFeO_3$ single crystals across the spin-reorientation phase transition using broadband microwave absorption spectroscopy up to 87.5 GHz. Temperature- and magnetic-field-dependent…

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