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We present a theory for the temperature-dependent nuclear magnetic shielding tensor of molecules with arbitrary electronic structure. The theory is a generalization of Ramsey's theory for closed-shell molecules. The shielding tensor is…

Chemical Physics · Physics 2014-03-12 Willem Van den Heuvel , Alessandro Soncini

We present a theory of nuclear magnetic resonance (NMR) shielding tensors for electronic states with arbitrary degeneracy. The shieldings are here expressed in terms of generalized Zeeman ($g^{(k)}$) and hyperfine ($A^{(k)}$) tensors, of…

Chemical Physics · Physics 2012-11-28 Willem Van den Heuvel , Alessandro Soncini

We present a simple derivation of the nuclear shielding in paramagnetic molecules, extendable to strong spin-orbit coupling cases of relevance to lanthanides and actinides, as well as encompassing contributions from excited multiplets.…

Chemical Physics · Physics 2019-05-01 Juha Vaara , Syed Awais Rouf , Jiří Mareš

Recently, Yu, Brown, and Chuang [Phys. Rev. A {\bf 71}, 032341 (2005)] investigated the entanglement attainable from unitary transformed thermal states in liquid-state nuclear magnetic resonance (NMR). Their research gave an insight into…

Quantum Physics · Physics 2007-11-10 Yukihiro Ota , Shuji Mikami , Motoyuki Yoshida , Ichiro Ohba

In this paper we use the Nuclear Magnetic Resonance (NMR) to write eletronic states of a ferromagnetic system into a high-temperature paramagnetic nuclear spins. Through the control of phase and duration of radiofrequency pulses we set the…

In high spin molecules metal ions are coupled by ferro or antiferromagnetic short range interactions so that their magnetic moments are parallel or antiparallel to each other at temperatures (T) much smaller than the coupling constant J.…

Condensed Matter · Physics 2009-09-25 A. Keren , P. Mendels , A. Kratzer , A. Scuiller , M. Verdaguer , Z. Slaman , C. Baines

The magnetic state of the single-component molecular compound, [Cu(tmdt)$_{2}$], is investigated by means of $^{1}$H-NMR. An abrupt spectral broadening below 13 K and a sharp peak in nuclear spin-lattice relaxation rate, $T_{1}^{-1}$, at 13…

Strongly Correlated Electrons · Physics 2012-05-31 Rina Takagi , Kazuya Miyagawa , Kazushi Kanoda , Biao Zhou , Akiko Kobayashi , Hayao Kobayashi

We study theoretically the formation of the nuclear-spin polaron state in semiconductor nanosystems within the Lindblad equation approach. To this end, we derive a general Lindblad equation for the density operator that complies with the…

Mesoscale and Nanoscale Physics · Physics 2022-06-01 Iris Kleinjohann , Andreas Fischer , Mikhail M. Glazov , Frithjof B. Anders

As a nuclear spin model of scalable quantum register, the one-dimensional chain of the magnetic atoms with nuclear spins 1/2 substituting the basic atoms in the plate of nuclear spin free easy-axis 3D antiferromagnet is considered. It is…

Quantum Physics · Physics 2008-12-02 A. A. Kokin , V. A. Kokin

We present theoretical studies of temperature dependent diamagnetic-paramagnetic transitions in thin quantum rings. Our studies show that the magnetic susceptibility of metal/semiconductor rings can exhibit multiple sign flips at…

Mesoscale and Nanoscale Physics · Physics 2021-01-04 Neal Blackman , Dentcho A. Genov

We use recent developments in the framework of time dependent matrix product state method (t-MPS) to compute the NMR relaxation rate $1/T_1$ for spin-1/2 chains under magnetic field and for different Hamiltonians (XXX, XXZ, isotropically…

Strongly Correlated Electrons · Physics 2016-11-08 E. Coira , P. Barmettler , T. Giamarchi , C. Kollath

We present the general theory of clean, two-dimensional, quantum Heisenberg antiferromagnets which are close to the zero-temperature quantum transition between ground states with and without long-range N\'{e}el order. For N\'{e}el-ordered…

Condensed Matter · Physics 2009-10-22 Andrey V. Chubukov , Subir Sachdev , Jinwu Ye

Nuclear Magnetic Resonance (NMR) is a powerful local quantum probe of the electronic structure of materials, but in the absence of reliable theory the interpretation of the NMR data can be challenging. This is true in particular for the…

Superconductivity · Physics 2021-12-21 Marija Avramovska , Jakob Nachtigal , Jürgen Haase

The NMR relaxation rate and the static spin susceptibility in graphene are studied within a tight-binding description. At half filling, the NMR relaxation rate follows a power law as $T^2$ on the particle-hole symmetric side, while with a…

Strongly Correlated Electrons · Physics 2008-02-19 Tianxing Ma , Balázs Dóra

We demonstrate ionization of a molecule with the bias voltage of a Scanning Tunnelling Microscope (STM) resulting in a coexistence of a neutral and ionic molecules, i.e. radical (paramagnetic) and non-radical (diamagnetic) states. This…

Mesoscale and Nanoscale Physics · Physics 2024-04-02 Yishay Manassen , Michael Averbukh , Zion Hazan , Yahel Tzuriel , Pino Boscolo , Alexsander Shnirman , Baruch Horovitz

We solve the $S=1/2$ infinite-range random Heisenberg Hamiltonian in the paramagnetic phase using quantum Monte Carlo and analytical techniques. We find that the spin-glass susceptibility diverges at a finite temperature $T_g$ which…

Disordered Systems and Neural Networks · Physics 2008-02-03 D. R. Grempel , M. J. Rozenberg

$^{75}$As NMR measurements were performed on a polycrystalline sample of spin-1/2 alternating-spin-chain Heisenberg antiferromagnet AgVOAsO$_4$. Temperature-dependent NMR shift $K(T)$, which is a direct measure of the intrinsic spin…

Materials Science · Physics 2017-12-27 N. Ahmed , P. Khuntia , H. Rosner , M. Baenitz , A. A. Tsirlin , R. Nath

This paper studies spin glass to paramagnetic transition in the Spherical Sherrington-Kirkpatrick model with ferromagnetic Curie-Weiss interaction with coupling constant $J$ and inverse temperature $\beta$. The disorder of the system is…

Probability · Mathematics 2024-08-26 Iain M. Johnstone , Yegor Klochkov , Alexei Onatski , Damian Pavlyshyn

Here we demonstrate how para-hydrogen can be used to prepare a two-spin system in an almost pure state which is suitable for implementing nuclear magnetic resonance (NMR) quantum computation. A 12ns laser pulse is used to initiate a…

Very recently, there has been significant progress with establishing a common phenomenology of the superconducting cuprates in terms of nuclear magnetic resonance (NMR) shift and relaxation. Different from the old interpretation, it was…

Superconductivity · Physics 2020-06-05 Marija Avramovska , Danica Pavićević , Jürgen Haase
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