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Pyroelectric current and magnetoelectric coupling measurements on polycrystalline samples of the quadruple perovskite (LaMn$_{3}$)Mn$_{4}$O$_{12}$ give evidence of ferroelectricity driven by the antiferromagnetic ordering of the $B$-site…

Electric polarization in ErCrO3 single crystals has been investigated in the temperature range of 5_370 K. Ferroelectric ordering has not been found in any of the directions. However, electric polarization induced by restricted polar…

Materials Science · Physics 2019-05-03 V. A. Sanina , B. Kh. Khannanov , E. I. Golovenchits , M. P. Shcheglov

An unresolved issue in the commonly used Pb(Zr1-xTix)O3 (PZT) ceramics is understanding the intrinsic piezoelectric behaviors of its crystal around the morphotropic phase boundary (MPB). Here, we demonstrate a novel approach to grow c-axis…

Materials Science · Physics 2024-08-26 Desheng Fu , Seiji Sogen , Hisao Suzuki

Relaxor ferroelectric perovskites are highly polarizable and can exhibit giant coupling between elastic strain and an applied electric field. Here, we report an in situ extended X-ray absorption fine structure (EXAFS) study of a…

Recent structural studies of ferroelectric PbZr(1-x)TixO3 (PZT) with x= 0.48, have revealed a new monoclinic phase in the vicinity of the morphotropic phase boundary (MPB), previously regarded as the the boundary separating the rhombohedral…

Materials Science · Physics 2019-08-17 B. Noheda , D. E. Cox , G. Shirane , R. Guo , B. Jones , L. E. Cross

We report electric polarization and magnetization measurements in single crystals of double perovskite Lu2MnCoO6 using pulsed magnetic fields and optical second harmonic generation (SHG) in DC magnetic fields. we observe well-resolved…

Materials Science · Physics 2016-06-22 S. Chikara , J. Singleton , J. Bowlan , D. A. Yarotski , N. Lee , H. Y. Choi , Y. J. Choi , V. S. Zapf

Ferroelectric and dielectric properties of polydomain (twinned) single-crystal Pb(Zr1-xTix)O3 thin films are described with the aid of a nonlinear thermodynamic theory, which has been developed recently for epitaxial ferroelectric films…

Materials Science · Physics 2009-11-10 V. G. Kukhar , N. A. Pertsev , H. Kohlstedt , R. Waser

We have synthesized single crystals of Na$_3$Co$_2$SbO$_6$ and characterized the structure and magnetic order by measuring anisotropic magnetic properties, heat capacity, x-ray and neutron single crystal diffraction. Magnetic properties and…

Strongly Correlated Electrons · Physics 2019-07-17 J. -Q. Yan , S. Okamoto , Y. Wu , Q. Zheng , H. D. Zhou , H. B. Cao , M. A. McGuire

We have grown single crystals of multiferroic double-perovskite Lu2CoMnO6 and studied the directional dependence of their magnetic and dielectric properties. The ferromagnetic order emerges below TC ~ 48K along the crystallographic c axis.…

Strongly Correlated Electrons · Physics 2014-03-26 N. Lee , H. Y. Choi , Y. J. Jo , M. S. Seo , S. Y. Park , Y. J. Choi

The domain structure in K2Cd2xMn2(1-x)(SO4)3 (x=0.5, 0.7 and 0.9) langbeinite crystals is studied with the aid of optical polarization microscopy. It is shown that the domain walls in ferro-elastic langbeinites separate enantiomorphous…

Materials Science · Physics 2007-09-04 R. Vlokh , I. Girnyk , O. V. Vlokh , I. Skab , A. Say , Y. Uesu

A comparative study of the dielectric properties and electric polarization of multiferroics GdMn2O5 and Gd0.8Ce0.2Mn2O5 has been carried out in the temperature range from 5 up to 300 K. The polarization properties in the ferroelectric state…

Materials Science · Physics 2018-04-18 V. A. Sanina , B. Kh. Khannanov , E. I. Golovenchits , M. P. Shcheglov

Ceramic solid solutions of PbZr(1-x)TixO3 (PZT) with compositions of about x= 0.50 are well-known for their extraordinarily large piezoelectric responses. The latter are highly anisotropic, and it was recently shown that, for the…

Materials Science · Physics 2007-05-23 B. Noheda , D. E. Cox

The strain dependence of electric and magnetic properties has been widely investigated, both from a fundamental science perspective and an applications point of view. Electromechanical coupling through field-induced polarization rotation…

Materials Science · Physics 2015-06-22 Zhiguang Wang , Yaojin Wang , Haosu Luo , Jiefang Li , D. Viehland

Conductive ferroelectric domain walls (DWs) represent a promising topical system for the development of nanoelectronic components and devices. DWs show very different properties as compared to their bulk counterparts. Of central interest…

High-energy x-ray diffraction experiments peformed on rhombohedral (1-x)Pb(Zn1/3Nb2/3)O3-xPbTiO3(PZN-xPT) crystals with x= 4.5 and 8% show that an electric field applied along the [001] direction induces the tetragonal phase, as proposed by…

Materials Science · Physics 2009-11-07 B. Noheda , Z. Zhong , D. E. Cox , G. Shirane , S-E. Park , P. Rehring

For decades it has been a well-known fact that among the few ferroelectric compounds in the perovskite family namely BaTiO3, KNbO3, PbTiO3 Na1/2Bi1/2TiO3 the dielectric and piezoelectric properties of BaTiO3 is considerably higher than the…

A ferroelectric monoclinic phase of space group $Cm$ ($M_A$ type) has been discovered in 0.65Pb(Mg$_{1/3}$Nb$_{2/3})O_3$-0.35PbTiO$_3$ by means of high resolution synchrotron X-ray diffraction. It appears at room temperature in a single…

Materials Science · Physics 2009-11-07 Z. -G. Ye , B. Noheda , M. Dong , D. Cox , G. Shirane

We report a systematic study of the structure, electric and magnetic properties of Ca$_3$Co$_{2-x}$Mn$_x$O$_6$ single crystals with $x =$ 0.72 and 0.26. The DC and AC magnetic susceptibilities display anomalies with characteristic of the…

Materials Science · Physics 2017-09-08 J. Shi , J. D. Song , J. C. Wu , X. Rao , H. L. Che , Z. Y. Zhao , H. D. Zhou , J. Ma , R. R. Zhang , L. Zhang , X. G. Liu , X. Zhao , X. F. Sun

The 5d pyrochlore oxide Cd2Re2O7 exhibits successive phase transitions from a cubic pyrochlore structure (phase I) to a tetragonal structure without inversion symmetry below Ts1 of ~200 K (phase II) and further to another noncentrosymmetric…

It is known that ferroelectric single crystals can be turned from a polydomain to a monodomain state by the application of an electric field. Here we report an unexpected opposite effect: the formation of through-the-crystal polydomain…

Materials Science · Physics 2026-01-07 Petr S. Bednyakov , Petr V. Yudin , Alexander K. Tagantsev , Jiří Hlinka