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The mode-coupling theory of the glass transition (MCT) has been at the forefront of fundamental glass research for decades, yet the theory's underlying approximations remain obscure. Here we quantify and critically assess the effect of each…

Statistical Mechanics · Physics 2023-11-29 I. Pihlajamaa , V. E. Debets , C. C. L. Laudicina , L. M. C. Janssen

We have performed molecular dynamics simulations for a model two-dimensional soft-core mixture in a supercooled state. The mixture exhibits a slow structural relaxation in a quiescent state, however, the relaxation is much enhanced in…

Soft Condensed Matter · Physics 2009-11-10 Ryoichi Yamamoto , Kunimasa Miyazaki , David R. Reichman

Mode-coupling theory for uniformly sheared underdamped systems with an isothermal condition is presented. As a result of the isothermal condition, it is shown that the shear stress exhibits significant relaxation at the alpha-relaxation…

Statistical Mechanics · Physics 2013-02-27 Koshiro Suzuki , Hisao Hayakawa

The interplay between the structural relaxation and the rheological response of a binary LJ glass former is studied via MD simulations. In the quiescent state, the model is well known for its sluggish dynamics and a two step relaxation of…

Soft Condensed Matter · Physics 2015-05-14 Fathollah Varnik

We discuss some generic features of the dynamics of glass-forming liquids close to the glass transition singularity of the idealized mode-coupling theory (MCT). The analysis is based on a recent model by one of the authors for the…

Statistical Mechanics · Physics 2015-10-07 Tommaso Rizzo , Thomas Voigtmann

A relation between equilibrium, steady-state, and waiting-time dependent dynamical two-time correlation functions in dense glass-forming liquids subject to homogeneous steady shear flow is discussed. The systems under study show pronounced…

Soft Condensed Matter · Physics 2015-05-18 Matthias Krüger , Fabian Weysser , Thomas Voigtmann

We report on quantitative comparisons between simulation results of a bead-spring model and mode-coupling theory calculations for the structural and conformational dynamics of a supercooled, unentangled polymer melt. We find…

Soft Condensed Matter · Physics 2009-11-13 Song-Ho Chong , Martin Aichele , Hendrik Meyer , Matthias Fuchs , Jörg Baschnagel

The high-pressure dynamics of a computer-modeled silica melt is studied in the framework of the mode-coupling theory of the glass transition (MCT) using static-structure input from molecular-dynamics (MD) computer simulation. The theory…

Materials Science · Physics 2009-11-13 Th. Voigtmann , J. Horbach

The history dependence of the glasses formed from flow-melted steady states by a sudden cessation of the shear rate $\dot\gamma$ is studied in colloidal suspensions, by molecular dynamics simulations, and mode-coupling theory. In an ideal…

Using molecular dynamics simulations, we study dynamics of a model polymer melt composed of short chains with bead number N=10 in supercooled states. In quiescent conditions, the stress relaxation function $G(t)$ is calculated, which…

Soft Condensed Matter · Physics 2009-11-07 Ryoichi Yamamoto , Akira Onuki

The influence of thermal processing on the potential energy, atomic structure, and mechanical properties of metallic glasses is examined using molecular dynamics simulations. We study the three-dimensional binary mixture, which was first…

Soft Condensed Matter · Physics 2019-12-23 Nikolai V. Priezjev

Mode coupling theory (MCT) has had notable successes in addressing the rheology of hard-sphere colloidal glasses, and also soft colloidal glasses such as star-polymers. Here, we explore the properties of a recently developed MCT-based…

Soft Condensed Matter · Physics 2012-03-30 Th. Voigtmann , J. M. Brader , M. Fuchs , M. E. Cates

We extend our earlier shear-transformation-zone (STZ) theory of amorphous plasticity to include the effects of thermally assisted molecular rearrangements. This version of our theory is a substantial revision and generalization of…

Materials Science · Physics 2009-11-10 M. L. Falk , J. S. Langer , L. Pechenik

Shear localization in slowly-driven bulk metallic glasses (BMGs) is typically accompanied by a sharp drop in the bulk stress response as a signature of the plastic yielding transition. It is also observed that the sharpness of this…

Soft Condensed Matter · Physics 2023-09-22 Kamran Karimi , Stefanos Papanikolaou

Brownian dynamics simulations of bidisperse hard discs moving in two dimensions in a given steady and homogeneous shear flow are presented close to and above the glasstransition density. The stationary structure functions and stresses of…

Soft Condensed Matter · Physics 2010-01-20 O. Henrich , F. Weysser , M. E. Cates , M. Fuchs

Dense supercooled colloidal melt in forward shear from a quiescent state shows overshoot in shear stress at 10% strain with an unchanged fluid structure at equal stress before and after overshoot. In addition, we find overshoot in normal…

Soft Condensed Matter · Physics 2015-06-17 Amit Kumar Bhattacharjee

We report results of molecular-dynamics simulations of a model polymer melt consisting of short non-entangled chains in the supercooled state above the critical temperature of mode-coupling theory (MCT). To analyse the dynamics of the…

Soft Condensed Matter · Physics 2007-05-23 M. Aichele , J. Baschnagel

The re-solidification of amorphous solids after mechanically driven yielding from a nonequilibrium state is a fundamental soft matter science problem of broad relevance in materials science, with implications for material strength,…

Soft Condensed Matter · Physics 2026-04-16 Anoop Mutneja , Kenneth S. Schweizer

We study theoretically the non-linear response properties of glass formers. We establish several general results which, together with the assumption of Time-Temperature Superposition, lead to a relation between the non-linear response and…

Statistical Mechanics · Physics 2009-12-19 Marco Tarzia , Giulio Biroli , Jean-Philippe Bouchaud , Alexandre Lefèvre

The process of crystal nucleation can be accelerated or retarded by ultrasonic vibration, which is particularly attractive for the addictive manufacture and thermoplastic forming of metallic glasses, however, the effect and mechanism of…

Materials Science · Physics 2022-12-06 Baoshuang Shang , Noel Jakse , Pengfei Guan , Weihua Wang , Jean-louis Barrat