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The random phase approximation (RPA) for the electron correlation energy, combined with the exact-exchange energy, represents the state-of-the-art exchange-correlation functional within density-functional theory (DFT). However, the standard…

Other Condensed Matter · Physics 2015-05-20 Xinguo Ren , Patrick Rinke , Alexandre Tkatchenko , Matthias Scheffler

The random phase approximation (RPA) is exact for the exchange energy of a many-electron ground state, but RPA makes the correlation energy too negative by about 0.5 eV/electron. That large short-range error, which tends to cancel out of…

Computational Physics · Physics 2020-06-24 Tim Gould , Adrienn Ruzsinszky , John P. Perdew

The Random Phase Approximation (RPA) is a widely employed post Hartree-Fock or DFT method, capable of capturing van der Waal interactions and other dynamic correlation effects at relatively low costs of $\mathcal O(N^3)$ in time and…

Materials Science · Physics 2015-09-02 Felix Hummel

We report the first three-dimensional wavevector analysis of the jellium exchange-correlation (xc) surface energy in the random-phase approximation (RPA). The RPA accurately describes long-range xc effects which are challenging for…

Materials Science · Physics 2009-11-11 J. M. Pitarke , L. Constantin , J. P. Perdew

A fast method is developed for calculating the Random-Phase-Approximation (RPA) correlation energy for density functional theory. The correlation energy is given by a trace over a projected RPA response matrix and the trace is taken by a…

Chemical Physics · Physics 2013-01-01 Daniel Neuhauser , Eran Rabani , Roi Baer

The GW self-energy may become computationally challenging to evaluate because of frequency and momentum convolutions. These difficulties were recently addressed by the development of the multipole approximation (MPA) and the W-av methods:…

The direct random-phase approximation (dRPA) is used to calculate and compare atomization energies for the HEAT set and 10 selected molecules of the G2-1 set using both plane waves and Gaussian-type orbitals. We describe detailed procedures…

We address the puzzling weak-coupling perturbative behavior of graphene interaction effects as manifested experimentally, in spite of the effective fine structure constant being large, by calculating the effect of Coulomb interactions on…

Mesoscale and Nanoscale Physics · Physics 2014-09-11 Johannes Hofmann , Edwin Barnes , S. Das Sarma

We discuss a possible form for a theory akin to local density functional theory, but able to produce van der Waals energies in a natural fashion. The usual Local Density Approximation (LDA) for the exchange and correlation energy $E_{xc}$…

Soft Condensed Matter · Physics 2007-05-23 John F. Dobson

We develop the plasmon-pole approximation (PPA) theory for calculating the carrier self-energy of extrinsic graphene as a function of doping density within analytical approximations to the $GW$ random phase approximation ($GW$-RPA). Our…

Mesoscale and Nanoscale Physics · Physics 2018-12-05 E. H. Hwang , Robert E. Throckmorton , S. Das Sarma

Analytical forces have been derived in the Lagrangian framework for several random phase approximation (RPA) correlated total energy methods based on the range separated hybrid (RSH) approach, which combines a short-range density functional…

Chemical Physics · Physics 2016-03-16 Bastien Mussard , Peter G. Szalay , János G. Ángyán

Undoped graphene (Gr) sheets at low temperatures are known, via Random Phase Approximation (RPA) calculations, to exhibit unusual van der Waals (vdW) forces. Here we show that graphene is the first known system where effects beyond the RPA…

Strongly Correlated Electrons · Physics 2014-06-03 John F. Dobson , Tim Gould , Giovanni Vignale

The newly developed "strongly constrained and appropriately normed" (SCAN) meta-generalized-gradient approximation (meta-GGA) can generally improve over the non-empirical Perdew-Burke-Ernzerhof (PBE) GGA not only for strong chemical…

Materials Science · Physics 2016-10-19 Haowei Peng , Zeng-Hui Yang , Jianwei Sun , John P. Perdew

The random phase approximation (RPA) builds in correlations left out by mean-field theory. In full 0-hbar-omega shell-model spaces we calculate the Hartree-Fock + RPA binding energy, and compare it to exact diagonalization. We find that in…

Nuclear Theory · Physics 2009-11-07 Ionel Stetcu , Calvin W. Johnson

The Random Phase and Amplitude Formalism (RPA) has significantly extended the scope of weak turbulence studies. Because RPA does not assume any proximity to the Gaussianity in the wavenumber space, it can predict, for example, how the…

Chaotic Dynamics · Physics 2014-01-15 Mitsuhiro Tanaka , Naoto Yokoyama

Random Phase Approximation (RPA) provides a very convenient tool to study the ensembles of weakly interacting waves, commonly called Wave Turbulence. In its traditional formulation, RPA assumes that phases of interacting waves are random…

Mathematical Physics · Physics 2009-11-10 Yeontaek Choi , Yuri V. Lvov , Sergey Nazarenko

We calculate the single-particle spectral function for doped bilayer graphene in the low energy limit, described by two parabolic bands with zero band gap and long range Coulomb interaction. Calculations are done using thermal Green's…

Mesoscale and Nanoscale Physics · Physics 2014-04-18 Andro Sabashvili , Stellan Östlund , Mats Granath

The Gaussian expansion method (GEM) is extensively applied to the calculations in the random-phase approximation (RPA). We adopt the mass-independent basis-set that has been tested in the mean-field calculations. By comparing the RPA…

Nuclear Theory · Physics 2015-05-13 H. Nakada , K. Mizuyama , M. Yamagami , M. Matsuo

The properties of metallic systems with important and structured excitations at low energies, such as Cu, are challenging to describe with simple models like the plasmon pole approximation (PPA), and more accurate and sometimes prohibitive…

Materials Science · Physics 2023-04-26 Dario A. Leon , Andrea Ferretti , Daniele Varsano , Elisa Molinari , Claudia Cardoso

We discuss the validity (or not) of the ring-diagram approximation (i.e. RPA) in the calculation of graphene self-energy in the weak-coupling ($r_s \ll 1$) limit, showing that RPA is a controlled and valid approximation for…

Materials Science · Physics 2007-08-30 S. Das Sarma , Ben Yu-Kuang Hu , E. H. Hwang , Wang-Kong Tse