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By applying a circularly polarized and slightly blue-detuned microwave field with respect to the first excited rotational state of a dipolar molecule, one can engineer a long-range, shallow potential well in the entrance channel of the two…

Quantum Gases · Physics 2018-10-24 Lucas Lassablière , Goulven Quéméner

We have investigated the angle-resolved ATI spectrum of oriented molecules in the IR+XUV co-rotating circular laser fields. According to the different roles of IR and XUV laser in the ionization process, we purposefully adjust the photon…

Atomic Physics · Physics 2024-01-15 Yu-Hong Li , Facheng Jin , Yujun Yang , Fei Li , Ying-Chun Guo , Zhi-Yi Wei , Jing Chen , Xiaojun Liu , Bingbing Wang

We present a theoretical study of the time-dependent laser alignment of molecules taking into account the hyperfine coupling due to nuclear-quadrupole interactions. The coupling of nuclear spins to the overall angular momentum of molecules…

Chemical Physics · Physics 2020-06-18 Linda V. Thesing , Andrey Yachmenev , Rosario González-Férez , Jochen Küpper

We report experiments on field-free molecular alignment performed at FLASH, the free electron laser (FEL) in Hamburg. The impulsive alignment induced by a 100 fs near-infrared laser pulse in a rotationally cold CO_2 sample is characterized…

We present a new analytical solution for the equation of motion of relativistic electrons in the focus of a high-intensity laser pulse. We approximate the electron's transverse dynamics in the averaged field of a long laser pulse focused to…

We present experimental evidence for spin-orbit interaction of an electron as it scatters from a neutral atom. The scattering process takes place within a Rb$_2$ ultralong-range Rydberg molecule, consisting of a Rydberg atomic core, a…

The impulsive limit (the "sudden approximation") has been widely employed to describe the interaction between molecules and short, far-off-resonant laser pulses. This approximation assumes that the timescale of the laser--molecule…

Chemical Physics · Physics 2023-08-14 Volker Karle , Mikhail Lemeshko

The rotational echo response of molecules is found to strongly depend on the delay between the two ultrashort laser pulses, as opposed to two-level systems. We study this dependence experimentally and theoretically and show that by…

Quantum Physics · Physics 2018-12-12 Dina Rosenberg , Ran Damari , Sharly Fleischer

We report on a new phenomenon of molecular nuclear spin isomers conversion in the field of resonant laser radiation. It is based on the isomer-selective optical excitation and the difference of conversion rates for excited and unexcited…

Chemical Physics · Physics 2009-10-31 A. M. Shalagin , L. V. Il'ichov

Photoelectron angular distributions (PADs) of oriented polar molecules in response to different polarized lasers are systematically investigated. It is found that the PADs of polar CO molecules show three distinct styles excited by…

Chemical Physics · Physics 2013-03-05 Xiaosong Zhu , Qingbin Zhang , Weiyi Hong , Peixiang Lu , Zhizhan Xu

We find exact conditions for the enhancement or suppression of internal and/or scattered fields and the determination of their spatial distribution or angular momentum through the combination of simple fields. The incident fields can be…

Optics · Physics 2015-06-16 Benjamin Hourahine , Francesco Papoff

Ultrashort laser pulses are widely used for transient field-free molecular orientation -- a phenomenon important in chemical reaction dynamics, ultrafast molecular imaging, high harmonics generation, and attosecond science. However,…

Chemical Physics · Physics 2022-12-21 Ilia Tutunnikov , Long Xu , Yehiam Prior , Ilya Sh. Averbukh

A new mode of effective interaction of molecular rotational degrees of freedom with an intense, nonresonant, ultrashort laser pulse is explored. Transient nonadiabatic charge redistribution (TNCR) in larger molecules or molecular ions…

Optics · Physics 2020-01-01 D. A. Romanov , R. J. Levis

We demonstrate experimentally a method of all-optical selective rotational control in gas mixtures. Using an optical centrifuge - an intense laser pulse whose linear polarization rotates at an accelerated rate, we simultaneously excite two…

Chemical Physics · Physics 2024-06-19 P. Amani , A. A. Milner , V. Milner

When hydrogen molecules collide with a surface, they can either scatter away from the surface or stick to the surface through a dissociation reaction which leaves two H atoms adsorbed on the surface. The relative probabilities of these two…

Chemical Physics · Physics 2024-10-03 H. Chadwick , G. Zhang , C. J. Baker , P. L. Smith , G. Alexandrowicz

Exploration of a new ultrafast-ultrasmall frontier in atomic and molecular physics has begun. Not only is is possible to control outer-shell electron dynamics with intense ultrafast optical lasers, but now control of inner-shell processes…

The optical binding of many particles has great potential to achieve the wide-area formation of a "crystal" of small materials. Unlike conventional optical binding, where the whole assembly of targeted particles is irradiated with light, if…

Optics · Physics 2023-02-28 Yukihiro Tao , Tomohiro Yokoyama , Hajime Ishihara

Molecular rotational spectroscopy based on strong-field-ionization-induced nitrogen laser is employed to investigate the time evolution of the rotational wave packet composed by a coherent superposition of quantum rotational states created…

A theoretical study of the rotational dynamics of a linear polar molecule in a two-color non-resonant cw laser field is presented. By systematically considering the interactions of this field with the electric dipole moment, polarizability…

Quantum Physics · Physics 2020-08-26 David Mellado-Alcedo , Niurka R. Quintero , Rosario González-Férez

We propose a general impulsive model for scattering of molecules from a flat solid surface. It is assumed within the framework of this model that an encounter of an atom (or ion) with the surface is a series of elastic (in the direction…

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