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We have evaluated the successes and failures of the Hubbard-corrected density functional theory (DFT+U) approach to study Mg doping of LiCoO$_2$. We computed the effect of the U parameter on the energetic, geometric and electronic…

Materials Science · Physics 2014-11-07 Juan A. Santana , Jeongnim Kim , P. R. C. Kent , Fernando A. Reboredo

Metal/superconductor/semiconductor (Ag/HgBaCaCuO/CdSe) heterostructures have been successfully fabricated using pulse-electrodeposition technique. The electrochemical parameters are optimized and diffusion free growth of CdSe onto…

Superconductivity · Physics 2009-11-10 D. D. Shivagan , P. M. Shirage , S. H. Pawar

The utility of a continuous beam of He droplets for the assembly and surface deposition of Ag clusters, <N(Ag)> ~ 300 - 6 000, is studied with transmission electron microscopy. Images of the clusters on amorphous carbon substrates obtained…

Atomic and Molecular Clusters · Physics 2016-09-28 Evgeny Loginov , Luis F. Gomez , Andrey F. Vilesov

It is noteworthy that chemical substitution of BaFe2As2 (122) with the noble elements Cu and Au gives superconductivity with a maximum Tc=3 K, while Ag substitution (Ag-122) stays antiferromagnetic. For Ba(Fe1-xTMx)2As2, TM= Cu, Au, or Ag,…

Superconductivity · Physics 2020-06-24 L. Li , D. S. Parker , Z. Gai , H. B. Cao , A. S. Sefat

A simplified density functional theory (DFT) method for charged adsorbates on an ultrathin, insulating film supported by a metal substrate is developed and presented. This new method is based on a previous DFT development that uses a…

Materials Science · Physics 2017-03-27 Ivan Scivetti , Mats Persson

The dynamics of phase field crystal (PFC) modeling is derived from dynamical density functional theory (DDFT), for both single-component and binary systems. The derivation is based on a truncation up to the three-point direct correlation…

Materials Science · Physics 2015-05-19 Zhi-Feng Huang , K. R. Elder , Nikolas Provatas

We apply the density functional theory for superconductors (SCDFT) based on the local-density approximation (LDA) to alkali-doped fullerides A3C60 with the face-centered cubic structure. We evaluate the superconducting transition…

Superconductivity · Physics 2013-08-23 Ryosuke Akashi , Ryotaro Arita

We predict the structures of neutral gas-phase gold clusters ($Au_n$, $n$ = 5$-$13) at finite temperatures based on free-energy calculations obtained by replica-exchange ab initio molecular dynamics. The structures of neutral…

La0.7Ba0.3MnO3 (LBMO):Agx (x = 0.0, 0.1, 0.2, 0.3, and 0.4) composites are synthesized by solid-state reaction route, the final sintering temperatures are varied from 1300 (LBMO1300Ag) to 1400 0C (LBMO1400Ag), and their physical properties…

Strongly Correlated Electrons · Physics 2008-01-09 Rahul Tripathi , V. P. S. Awana , H. Kishan , S. Balamurugan , G. L. Bhalla

In this work, the vibrational and electronic properties of Al$_{12}$M (Zn, Cu) clusters are investigated using density functional theory (DFT) calculations. The results indicate that the clusters favor low-spin states when evaluated with…

Materials Science · Physics 2024-08-30 Peter Ludwig Rodríguez-Kessler

Electron holography in a transmission electron microscope was applied to measure the phase shift induced by Au clusters as a function of the cluster size. Large phase shifts Df observed for small Au clusters cannot be described by the…

Materials Science · Physics 2009-11-13 R. Popescu , E. Mueller , M. Wanner , D. Gerthsen , M. Scowalter , A. Rosenauer , A. Boettcher , D. Loeffler , P. Weis

Density-functional theory calculations are used to verify the atomic structure of the $\sqrt{3}$$\times$$\sqrt{3}$ silicene phase grown on the Ag(111) surface. Recent experimental studies strongly suggested that the previous double-layer…

Materials Science · Physics 2016-02-29 Se Gab Kwon , Myung Ho Kang

Ab initio description of point defects in semiconductors, characterized by in-gap states of significant multideterminant character, presents a longstanding theoretical challenge for density functional theory (DFT) methods. In this study, we…

Materials Science · Physics 2024-11-27 Zsolt Benedek , Ádám Ganyecz , Anton Pershin , Viktor Ivády , Gergely Barcza

Three new phases of ternary transitional metal carbides, namely MAX phases, Nb4SiC3, Nb4GeC3 and Nb4GaC3 were proposed by means of density functional theory, and they were all predicted to be mechanically stable. It was figured out that the…

Materials Science · Physics 2015-09-15 Teng Yue , Baochang Wang , Weiwei Sun , Zhu Xiao-shuo , Feng Xiao-xue , Yan Mu-fu , Fu Yu-dong

We extend the phase field crystal (PFC) framework to quantitative modeling of polycrystalline graphene. PFC modeling is a powerful multiscale method for finding the ground state configurations of large realistic samples that can be further…

Molecular dynamics simulation is employed to understand the thermodynamic behavior of cuboctahedron (cub) and icosahedron (ico) nanoparticles with 2-20 number of shells (55-28741 atoms). The embedded atom method was used to describe the…

Materials Science · Physics 2019-08-13 Maryam Azadeh , Movaffaq Kateb , Pirooz Marashi

Non-equilibrium molecular dynamics (NEMD) techniques are widely used for investigating lattice thermal conductivity. Recently, machine learning force fields (MLFFs) have emerged as a promising approach to enhance the precision in NEMD…

Materials Science · Physics 2023-09-21 Takumi Araki , Shinnosuke Hattori , Toshio Nishi , Yoshihiro Kudo

For its potential as a catalyst, nanoporous gold (NPG) prepared through dealloying of bulk Ag-Au alloys has been extensively investigated. NPG thin films can offer ease of handling, better tunability of the chemistry and microstructure of…

We develop an effective potential approach for assessing the flow of charge within a two-dimensional donor-acceptor/metal network based on core-level shifts. To do so, we perform both density functional theory (DFT) calculations and x-ray…

The structural, electronic, and magnetic properties of bulk GdCu (CsCl-type) are investigated using spin density functional theory, where highly localized $4f$ orbitals are treated within LDA+$U$ and GGA+$U$ methods. The calculated magnetic…

Strongly Correlated Electrons · Physics 2020-05-29 Vikas Kashid , Ersoy Şaşıoğlu , Gustav Bihlmayer , Alexander B. Shick , Stefan Blügel