Related papers: Carbon Fractionation in PDRs
Deuterium fractionation can constrain the physical and chemical conditions at the early stage of brown dwarf formation. We present IRAM 30m observations over a wide frequency range of 213-279 GHz of singly and doubly deuterated species of…
Nitrogen-bearing molecules in cold molecular clouds exhibit a range of isotopic fractionation ratios and these molecules may be the precursors of $^{15}$N enrichments found in comets and meteorites. Chemical model calculations indicate that…
We study the chemistry of small hydrocarbons in the photon-dominated regions (PDRs) associated with the ultra-compact HII region Mon R2. Our goal is to determine the variations of the abundance of small hydrocarbons in a high-UV irradiated…
Aims. We measure the deuterium fraction, RD, and the CO-depletion factor, fd, toward a number of starless and protostellar cores in the L1688 region of the Ophiuchus molecular cloud complex and search for variations based upon environmental…
The aim of this study is to investigate systematic chemical differentiation of molecules in regions of high mass star formation. We observed five prominent sites of high mass star formation in HCN, HNC, HCO+, their isotopes, C18O, C34S and…
Various studies have emphasized variations of the charge state and composition of the interstellar polycyclic aromatic hydrocarbon (PAH) population in photodissociation regions (PDRs). We aim to model the spatial evolution of the charge and…
CO is thought to be the main reservoir of volatile carbon in protoplanetary disks, and thus the primary initial source of carbon in the atmospheres of forming giant planets. However, recent observations of protoplanetary disks point towards…
We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…
We have used archival far-ultraviolet spectra from observations made by HST/STIS and FUSE to determine the column densities and rotational excitation temperatures for CO and H2, respectively, along the lines of sight to 23 Galactic O and B…
We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model…
In this work, we study deuterium fractionation in four starless cores in the low-mass star-forming region L1688 in the Ophiuchus molecular cloud. We study how the deuterium fraction ($R_D$) changes with environment, compare deuteration of…
We have measured fragmentation branching ratios of neutral CnH and CnH+ cations produced in high velocity (4.5 a.u) collisions between incident CnH+ cations and helium atoms. Electron capture gives rise to excited neutral species CnH and…
We analyze $^{12}$CO($J$=2-1), $^{13}$CO($J$=2-1), C$^{18}$O ($J$=2-1), and 1.3 mm continuum maps of the $\rho$ Ophiuchi A photo-dissociation region (PDR) obtained with ALMA. Layered structures of the three CO isotopologues with an angular…
Elemental abundances, which are often depleted with respect to the solar values, are important input parameters for kinetic models of interstellar chemistry. In particular, the amount of carbon relative to oxygen is known to have a strong…
We have carried out an in-depth study of the peripheral region of the molecular cloud L1204/S140, where the far ultraviolet radiation and the density are relatively low. Our observations test theories of photon-dominated regions (PDRs) in a…
We present 5--14~$\mu$m spectra at two different positions across the Orion Bar photodissociation region (PDR) obtained with the Infrared Spectrograph onboard the Spitzer Space Telescope and 3.3~$\mu$m PAH observations obtained with the…
The radiation from stars and active galactic nuclei (AGN) creates photodissociation regions (PDRs) and X-ray dominated regions (XDRs), where the chemistry or heating are dominated by far-ultraviolet (FUV) radiation or X-ray radiation,…
We present maps at high spatial and spectral resolution in emission lines of C2H, c-C3H2, C4H, 12CO and C18O of the edge of the Horsehead nebula obtained with the Plateau de Bure Interferometer (PdBI). The edge of the Horsehead nebula is a…
We present a study of small carbon chains and rings in Photon Dominated Regions (PDRs) performed at millimetre wavelengths. Our sample consists of the Horsehead nebula (B33), the rho,Oph L1688 cloud interface, and the cometary-shaped cloud…
We have carried out observations of CCH ($N=1-0$), CH$_{3}$CN ($J=5-4$), and three $^{13}$C isotopologues of HC$_{3}$N ($J=10-9$) toward three massive young stellar objects (MYSOs), G12.89+0.49, G16.86--2.16, and G28.28--0.36, with the…