Related papers: Carbon Fractionation in PDRs
Carbon containing molecules in cold molecular clouds show various levels of isotopic fractionation through multiple observations. To understand such effects, we have developed a new gas-grain chemical model with updated 13C fractionation…
High levels of deuterium fractionation in gas-phase molecules are usually associated with cold regions, such as prestellar cores. Significant fractionation ratios are also observed in hot environments such as hot cores or hot corinos, where…
We modelled \HH\ and CO formation incorporating the fractionation and selective photodissociation affecting CO when \AV\ $\la2$mag. UV absorption measurements typically have N(\cotw)/N(\coth) $\approx 65$ that are reproduced with the…
We report the first detection of PDR molecular tracers, namely HOC+, and CO+, and confirm the detection of the also PDR tracer HCO towards the starburst galaxy NGC 253, claimed to be mainly dominated by shock heating and in an earlier stage…
The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the…
The ionization fraction plays a key role in the chemistry and dynamics of molecular clouds. We study the H13CO+, DCO+ and HOC+ line emission towards the Horsehead, from the shielded core to the UV irradiated cloud edge, i.e., the…
We present observations of HDCO and H2CO emission toward a sample of 15 Class 0 protostars in the Orion A and B clouds. Of these, eleven protostars are Herschel-identified PACS Bright Red Sources (PBRS) and four are previously identified…
Photon-dominated regions (PDRs) are expected to show a layered structure in molecular abundances and emerging line emission, which is sensitive to the physical structure of the region as well as the UV radiation illuminating it. We aim to…
Nowadays there are several observational studies about the 13CO/C18O abundance ratio (X) towards nearby molecular clouds. These works give observational support to the C18O selective photodissociation due to the interaction between the FUV…
We present a comprehensive study of the rho Ophiuchi molecular cloud that addresses aspects of the physical structure and condition of the molecular cloud and its photodissociation region (PDR) by combining far-infrared and…
We present a far-ultraviolet (PDR) and an X-ray dominated region (XDR) code. We include and discuss thermal and chemical processes that pertain to irradiated gas. An elaborate chemical network is used and a careful treatment of PAHs and H2…
We investigate the gas-phase and grain-surface chemistry in the inner 30 AU of a typical protoplanetary disk using a new model which calculates the gas temperature by solving the gas heating and cooling balance and which has an improved…
Our current understanding of interstellar carbon fractionation hinges on the interpretation of astrochemical kinetic models. Yet, the various reactions included carry large uncertainties in their (estimated) rate coefficients, notably those…
We examine 20 diffuse and translucent Galactic sight lines and extract the column densities of the ^12CO and ^13CO isotopologues from their ultraviolet A--X absorption bands detected in archival Space Telescope Imaging Spectrograph data…
Aims: Our aims are threefold: a) To compare the $uv$ and mm-wave results; b) to interpret 13CO and 12CO abundances in terms of the physical processes which separately and jointly determine them; c) to interpret observed J=1-0 rotational…
We present analytic theory for the total column density of singly ionized carbon (C+) in the optically thick photon dominated regions (PDRs) of far-UV irradiated (star-forming) molecular clouds. We derive a simple formula for the C+ column…
CH stars form a distinct class of objects with characteristic properties like iron deficiency, enrichment of carbon and overabundance in heavy elements. These properties can provide strong observational constraints for theoretical…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…
Small hydrocarbons, such as C2H, C3H and C3H2 are more abundant in photo-dissociation regions (PDRs) than expected based on gas-phase chemical models. To explore the hydrocarbon chemistry further, we observed a key intermediate species, the…
We apply photo-dissociation region (PDR) molecular line emission models, that have varying degrees of enhanced mechanical heating rates, to the gaseous component of simulations of star-forming galaxies taken from the literature. Snapshots…