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The adsorption of a collagen fragment on both a hydrophobic, hydrogen-terminated and a hydrophilic, natively oxidised Si surface is investigated using all-atom molecular dynamics. While favourable direct protein-surface interactions via…

Soft Condensed Matter · Physics 2019-03-27 Daniel J. Cole , Mike C. Payne , Lucio Colombi Ciacchi

Liquids under confinement differ in behavior from their bulk counterparts and can acquire properties that are specific to the confined phase and linked to the nature and structure of the host matrix. While confined liquid water is not a new…

Materials Science · Physics 2020-07-22 François-Xavier Coudert

Interactions between molecules and electrode surfaces play a key role in electrochemical processes and are a subject of extensive research, both experimental and theoretical. In this manuscript, we address the water dissociation reaction on…

Chemical Physics · Physics 2023-02-16 Karen Fidanyan , Guoyuan Liu , Mariana Rossi

Scalar-relativistic DFT-GGA has been used to study adsorption of water in molecular and dissociative configurations on delta-Plutonium (111) surface. In molecular state, water is physisorbed in an almost flat-lying orientation at a one-fold…

Materials Science · Physics 2009-11-13 Raymond Atta-Fynn , Asok K. Ray

The acoustic levitation of small particles provides a versatile platform to investigate the collective dynamical properties of self-assembled many-body systems in the presence of hydrodynamic coupling. However, acoustic scattering forces…

Soft Condensed Matter · Physics 2022-11-08 Brady Wu , Bryan VanSaders , Melody X. Lim , Heinrich M. Jaeger

Water's ability to autoionize into hydroxide and hydronium ions profoundly influences surface properties, rendering interfaces either basic or acidic. While it is well-established that protons show an affinity to the air-water interface, a…

Chemical Physics · Physics 2025-02-05 Xavier R. Advincula , Kara D. Fong , Angelos Michaelides , Christoph Schran

Photocatalytic water splitting reaction on TiO2 surface is one of the fundamental issues that bears significant implication in hydrogen energy technology and has been extensively studied. However, the existence of the very first reaction…

Chemical Physics · Physics 2011-11-15 Shijing Tan , Yongfei Ji , Yang Wang , Jin Zhao , Aidi Zhao , Bing Wang , Yi Luo , Jinlong Yang , J. G. Hou

Unstructured proteins can modulate cellular responses to environmental conditions by undergoing coil-globule transitions and phase separation. However, the molecular mechanisms of these phenomena still need to be fully understood. Here, we…

Soft Condensed Matter · Physics 2023-06-28 Bernat Durà Faulí , Valentino Bianco , Giancarlo Franzese

An analysis of water clustering is used to study the quasi-2D percolation transition of water adsorbed at planar hydrophilic surfaces. Above the critical temperature of the layering transition (quasi-2D liquid-vapor phase transition of…

Statistical Mechanics · Physics 2009-11-11 A. Oleinikova , I. Brovchenko , A. Geiger

Understanding the dynamic nature of the semiconductor-water interface is crucial for developing efficient photoelectrochemical water splitting catalysts, as it governs reactivity through charge and mass transport. In this study, we employ…

Chemical Physics · Physics 2024-05-03 Sagarmoy Mandal , Tushar Kanti Ghosh

The evaporation of a droplet induces variety of ordered patterns near the contact line between the droplet and a substrate. This pattern formation involves both the behavior of colloidal suspensions and interactions between a droplet and a…

Soft Condensed Matter · Physics 2024-08-05 Yusaku Abe , Yu Matsuda

We calculate the ion and composition distributions around colloid particles in an aqueous mixture, accounting for preferential adsorption, electrostatic interaction, selective solvation among ions and polar molecules, and…

Soft Condensed Matter · Physics 2011-11-04 Ryuichi Okamoto , Akira Onuki

Using molecular dynamics simulations, we reveal emergent properties of hydrated electrode interfaces that while molecular in origin are integral to the behavior of the system across long times scales and large length scales. Specifically,…

Materials Science · Physics 2015-05-20 David T. Limmer , Adam P. Willard

Colloidal spheres with a partial platinum surface coating perform auto-phoretic motion when suspended in hydrogen peroxide solution. We present a theoretical analysis of the self-propulsion velocity of these particles using a continuum…

Soft Condensed Matter · Physics 2015-02-12 Joost de Graaf , Georg Rempfer , Christian Holm

Reactions at solid-water interfaces play a foundational role in water treatment systems, catalysis, chemical separations, and in predicting chemical fate and transport in the environment. Over the last century, experimental measurements and…

Chemical Physics · Physics 2022-12-14 Anastasia G. Ilgen , Kevin Leung , Louise J. Criscenti , Jeffery A. Greathouse

The interface between liquid water and the Pt(111) metal surface is characterized structurally and thermodynamically via reactive molecular dynamics (MD) simulations within the ReaxFF framework. The formation of a distinct buckled adsorbate…

Chemical Physics · Physics 2021-03-19 Christoph Karsten Jung , Laura Braunwarth , Andrey Sinyavskiy , Timo Jacob

The distribution of ions at the air/water interface plays a decisive role in many natural processes. It is generally understood that polarizable ions with low charge density are surface-active, implying they sit on top of the water surface.…

Chemical Physics · Physics 2022-10-05 Yair Litman , Kuo-Yang Chiang , Takakazu Seki , Yuki Nagata , Mischa Bonn

Deformed droplets are ubiquitous in various industrial applications, such as inkjet printing, lab-on-a-chip devices, and spray cooling, and can fundamentally affect the involved applications both favorably and unfavorably. Here, we employ…

Due to the improvement of computer power and the development of efficient algorithms it is now possible to combine high-dimensional quantum dynamical calculations of the dissociative adsorption of molecular beams with reliable ab-initio…

mtrl-th · Physics 2009-10-30 Axel Gross

A novel pattern forming instability in a mixture of a granular material and water in a horizontal rotating drum is experimentally investigated. The particles accumulate in radial symmetric rings separated by pure water. The transition…

Soft Condensed Matter · Physics 2007-05-23 A. P. J. Breu , C. A. Kruelle , I. Rehberg