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Monolayer lateral heterostructure of graphene and hexagonal boron nitride (h-BNC) has attracted a growing attention mainly due to its tunable band-gap character and unique physical properties at interface. Hereby, we reported the first-time…

We present theoretical studies of morphology, stability, and electronic structure of monolayer hexagonal CBN alloys with rich content of h-BN and carbon concentration not exceeding 50 %. Our studies are based on the bond order type of the…

Materials Science · Physics 2019-06-26 Agnieszka Jamróz , Jacek A. Majewski

We investigate the electronic properties of heterostructures based on ultrathin hexagonal boron nitride (h-BN) crystalline layers sandwiched between two layers of graphene as well as other conducting materials (graphite, gold). The tunnel…

The widely used crystal structures for both heptazine-based and triazine-based two-dimensional (2D) graphitic carbon nitride (g-C$_3$N$_4$) are the flat P-6m2 configurations. However, the experimentally synthesized 2D g-C$_3$N$_4$ possess…

Materials Science · Physics 2021-02-03 Luneng zhao , Xizhi Shi , Jin Li , Tao Ouyang , Chunxiao Zhang , Chao Tang , Chaoyu He , Jianxin Zhong

Rhombohedral dense forms of carbon, rh-C2 (or hexagonal h-C6), and boron nitride, rh-BN (or hexagonal h-B3N3), are derived from rhombohedral 3R graphite based on original crystal chemistry scheme backed with full cell geometry optimization…

Materials Science · Physics 2021-09-29 Samir F. Matar , Vladimir L. Solozhenko

New classes 2D carbon-based materials beyond graphene have been intensively studied for their promising applications in nano-/opto-/spin-electronics, catalysis, sensors, clean energy, etc. Very recently, the controllable large-scale…

Materials Science · Physics 2019-04-02 Guangzhao Qin , Zhenzhen Qin , Huimin Wang , Jianjun Hu , Ming Hu

Hexagonal boron nitride (h-BN) is a promising two-dimensional insulator with a large band gap and low density of charged impurities that is isostructural and isoelectronic with graphene. Here we report the chemical and atomic-scale…

Three new novel phases of carbon nitride (CN) bilayer, which are named as \alpha-C$_{2}$N$_{2}$, \beta-C$_{2}$N$_{2}$ and \gamma-C$_{4}$N$_{4}$, respectively, have been predicted in this paper. All of them are consisted of two CN sheets…

Materials Science · Physics 2019-02-01 Wanxing Lin , Shi-Dong Liang , Chunshan He , Wucheng Xie , Haiying He , Quanxiang Mai , Jiesen Li , D. X. Yao

A new set of lattice-models based on the hexagonal $\sqrt{N}\times\sqrt{N}$ super-cells of the well-known honeycomb lattice with single-hole defect (HL-D-1/2N) are proposed to realize the nontrivial isolated flat-bands. Through performing…

Materials Science · Physics 2022-08-15 Chaoyu He , Yujie Liao , Tao Ouyang , Huimin Zhang , Hongjun Xiang , Jianxin Zhong

Graphene is known as a two-dimensional Dirac semimetal, in which electron states are described by the Dirac equation of relativistic quantum mechanics. Three-dimensional analogues of graphene are characterized by Dirac points or lines in…

Mesoscale and Nanoscale Physics · Physics 2017-08-16 Ha-Jun Sung , Sunghyun Kim , In-Ho Lee , K. J. Chang

Graphite and hexagonal boron nitride (h-BN) are two prominent members of the family of layered materials possessing a hexagonal lattice. While graphite has non-polar homo-nuclear C-C intra-layer bonds, h-BN presents highly polar B-N bonds…

Materials Science · Physics 2012-04-16 Oded Hod

In 2015, a new two dimensional (2D) carbon allotrope, called phagraphene, was theoretically proposed. Based on this structure, we propose here a new boron nitride structure called phaBN. It is composed by three types of rings: pentagons,…

Materials Science · Physics 2020-12-09 J. M. Pontes , N. F. Frazão , David L. Azevedo , Jonas R. F. Lima

Hexagonal boron nitride (BN), one of the very few layered insulators, plays a crucial role in 2D materials research. In particular, BN grown with a high pressure technique has proven to be an excellent substrate material for graphene and…

Mesoscale and Nanoscale Physics · Physics 2020-06-19 J. Sonntag , J. Li , A. Plaud , A. Loiseau , J. Barjon , J. H. Edgar , C. Stampfer

In heterostructures consisting of atomically thin crystals layered on top of one another, lattice mismatch or rotation between the layers results in long-wavelength moir\'e superlattices. These moir\'e patterns can drive significant band…

Mesoscale and Nanoscale Physics · Physics 2019-10-01 Nathan R. Finney , Matthew Yankowitz , Lithurshanaa Muraleetharan , K. Watanabe , T. Taniguchi , Cory R. Dean , James Hone

Finding an effective and controllable way to create a sizable energy gap in graphene-based systems has been a challenging topic of intensive research. We propose that the hybrid of boron nitride and graphene (h-BNC) at low BN doping serves…

Mesoscale and Nanoscale Physics · Physics 2023-12-01 Chih-Piao Chuu , Wei-En Tseng , Kuan-Hung Liu , Ching-Ming Wei , Mei-Yin Chou

Single layer core/shell structures consisting of graphene as core and hexagonal boron nitride as shell are studied using first-principles plane wave method within density functional theory. Electronic energy level structure is analysed as a…

Mesoscale and Nanoscale Physics · Physics 2014-08-05 S. Cahangirov , S. Ciraci

We theoretically investigate the electronic structures of moir\'{e} superlattices arising in monolayer / bilayer graphene stacked on hexagonal boron nitride (hBN) in presence and absence of magnetic field. We develop an effective continuum…

Mesoscale and Nanoscale Physics · Physics 2014-10-10 Pilkyung Moon , Mikito Koshino

We use density functional theory based first-principles method to investigate the bandstructure and phase stability in the laterally grown hexagonal C$_x$(BN)$_{1-x}$, two-dimensional Graphene and $h$-BN hybrid nanomaterials, which were…

Mesoscale and Nanoscale Physics · Physics 2016-03-21 Ransell D'Souza , Sugata Mukherjee

Layer-dependent electronic and structural properties of emerging graphitic carbon boron compound C3B are investigated using both density functional theory and the GW approximation. We discover that, in contrast to a moderate quasiparticle…

Materials Science · Physics 2020-07-29 Yabei Wu , Weiyi Xia , Yubo Zhang , Wenguang Zhu , Wenqing Zhang , Peihong Zhang

Nanoscrolls (papyrus-like nanostructures) are very attractive structures for a variety of applications, due to their tunable diameter values and large accessible surface area. They have been successfully synthesized from different…

Materials Science · Physics 2019-06-05 Eric Perim , Douglas S. Galvao